兼具抗菌及抗紫外線高透濕防水濕式膜之研究

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٥ܿמೌᏢଣ!

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ᠼᆢᆶ׷਑ᔈҔౢ཰ࣴวᅺγ஑੤

ᅺγፕЎ!

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ঋڀל๵Ϸל๋Ѧጕଯ೸ᔸٛН!

ᔸԄጢϐࣴز

The study of Anti-Bacterial and Anti-Ultraviolet

Ray of Highly Breathable Waterproof Membrane

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!!ࣴ!ز!ғǺጰࣿ໢!

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!!ࡰᏤ௲௤Ǻ໳पӄ!!!!!!!!!!!!

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I

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΋૓ԶقଞᙃނޑౢࠔڀԖၨ٫ޑቸ܄کጲ᚞܄Ǵ໺಍ᔸԄ༡թуπ໻ ૈ༡թӧఖᙃނǴόૈᔈҔܭଞᙃނޑ༡թౢࠔǴѲᅿڙज़ஒ཮٬ѱ൑ޑሡ ؃ໆคݤᘉεǴයఈёว৖፾ӝܭӚԄѲᅿϐ೸ᔸٛНౢࠔǶӢԜҁࣴزό ӕܭа۳ᔸԄ೸ᔸٛНуπמೌޑБԄуπǴׯҔᚆࠠѲౢғᔸԄጢޑБ ݤǴᙖҗόӕჴᡍచҹӵѲᅿǵPU ᐋિᅿᜪǵל๋ѦጕᏊǵל๵Ꮚషӝӧ PU ᐋિύǵ༡թуπచҹϷຠӝᇙำፓ᏾฻Ƕ่݀ᡉҢǴԜࣴزޑ೸ᔸࡋ ёၲډ 8000g/m2/day а΢ǴКҞ߻ଳԄ༡թޑ 2000~3000 g/m2/day ܈ࢂځ дᔸԄ೸ᔸౢࠔϐ 4000~5000g/m2/day ଯрࣗӭǴ׎ԋଯ೸ᔸࡋ/ל๋Ѧጕ/ ל๵ӭфૈતᙃࠔǶ٠ஒࣴวрԋ݀ၨ٫ޑଛБϷуπచҹ຾ՉᚉໆғౢǴ ё଺ࣁғౢᇙ೷ϐᛙۓୖԵచҹǴ٬҂ٰ೸ᔸٛНౢࠔӧଯᐒૈޑᓬ༈࡭ុ ߥ࡭ᝡݾᓬ༈Ƕ ᜢᗖӷǺᔸԄ೸ᔸٛНуπǴל๋ѦጕᏊǴל๵ᏊǴPU ᐋિǴ ༡թуπǴຠӝ

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II

Abstract

Generally speaking the knitted fabrics have better flexibility and bulking properties. Since the traditional wet coating processing can be only used in the woven fabrics, cannot apply in the knitted ones, the limitation of fabric would narrow the market.

The major purpose of this research is to use the antibacterial agents and anti-ultraviolet ray agents within PU resin to prepare the antibacterial / anti-ultraviolet ray breathable fabrics by using the moisture response reactive-hot melt adhesive laminating technology. The experimental

conditions includes the fabric typesȐNylon and PETȑ, the PU resin types, the

kind of antibacterial agents, the kind of anti-ultraviolet ray agents, and the coating conditions and so on. These results show that the humidity can reach to 8000g/m2/day which is higher than 2000~3000 g/m2/day of dry coating type or 4000~5000 g/m2/day of other wet coating types. We hope that we can get the high-quality breathable fabrics of antibacterial and anti-ultraviolet ray using the laminating technology. With these research results, we can make the better recipes and working conditions for the small amount production and the stable reference conditions for manufacturing. Moreover, these high

performances of antibacterial and anti-ultraviolet ray breathable fabrics maintain the competitive advantage in high class of textiles.

Key words: antibacterial agents, anti-ultraviolet ray agents, breathable

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III

ठᖴ

ӧԜҗ૱གᖴৱৣ໳पӄ௲௤தਔ໔ࡰᏤᆶ௲ᇧǴ٬ךૈ໩ճֹԋ ፕЎǴᡣךӧࣴزޑၸำύёаעᅪൽᆶᜤᚒǴࣣૈ๏ϒᔅշှ،Ǵჹ ࣴزޑሦୱԖӄཥޑᡏᇡǴ٬ךӧᏢಞޑၡ೼΢ڙ੻ؼӭǶӧԜ߄ၲന ੿၈ޑགৱϷᖴཀǶ ፕЎα၂ǴགᖴЎϯεᏢٔЎ㗄௲௤ǵ٥ܿמೌᏢଣܴ݅ۘ௲௤а Ϸ໳पӄ௲௤฻ΟՏہ঩ޑ஼ЈࡰᏤᆶࡰ҅Ǵ٠གᖴ٥ܿמೌᏢଣ݅ۘ ܴ௲௤ᆶ٥ܿמೌᏢଣמӝೀಔ঩ླྀ໡൛ӧፕЎᇙբ΢य़ޑᅿᅿڐշǴ ໻Ԝ߄ၲคज़ϐགᐟǶ ӧᏢයࣴزය໔གᖴسշ౛Ϸ׷ᠼ܌؂ՏԴৣޑ௲ᏤᆶႴᓰǶӧᏢ ಞၸำ๏ϒӭБय़ޑڐշϷჴᡍ࠻ޑᏢ׌ॺڐշᆶᔅԆǴ٬೭ٿԃޑࣴ زғғࢲкᅈऍӳӣᏫǶ നࡕा੝ձགᖴৎΓکܻ϶ޑႴᓰᆶЍ࡭Ƕҗ૱གᐟ܌Ԗම࿶ᔅշ ךǵЍ࡭ךǵ࣬ߞךޑΓǴ٬ךёа໩ճ౥཰ǴոΚ߆ӛ҂ޕޑࡷᏯᆶ य़ჹΓғќѦ΋ঁٚำ࿞ᗌ຾Ƕ!

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IV

Ҟᒵ

ᄔ ाǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ ˧ AbstractǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ ˨ ठ ᖴ... ˩ Ҟ ᒵǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ ˪ კ Ҟ ᒵ ǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ ˬ ߄ Ҟ ᒵ ǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ ˭ ಃ΋ക ᆣፕǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 1 1-1 ߻قǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 3 1-2 ࣴزҞޑǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 3 ಃΒക Ў᝘ӣ៝ǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 5 2-1 ೸ᔸٛН౛ፕϟಏǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 5 2-2 ೸ᔸٛНᙃނϐϩᜪǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 8 2-3 ༡թуπמೌϟಏǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 11 2-4 ๋ѦጕޑቹៜǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 17 2-5 ל๵ೀ౛уπǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 23

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V 3-2 ୷ҁނ܄ෳ၂БݤǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 29 3-3 ჴᡍࢬำǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 37 ಃѤക ่݀ᆶ૸ፕǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 39 4-1 ଯ೸ᔸٛНᖓጢǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 39 4-2 ଯ೸ᔸٛНતᙃࠔǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 41 4-3 όӕѲᅿϐଯ೸ᔸٛНતᙃࠔǾǾǾǾǾǾǾǾǾǾǾǾǾ 44 4-4 ଯ೸ᔸٛН/ל๋ѦጕતᙃࠔǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 46 4-5 ଯ೸ᔸٛН/ל๋Ѧጕ/ל๵તᙃࠔǾǾǾǾǾǾǾǾǾǾǾǾ 48 4-6 ᚉໆғౢଯ೸ᔸٛНӭфૈ܄તᙃࠔǾǾǾǾǾǾǾǾǾǾ 51 ಃϖക ่ፕǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 54 ୖԵЎ᝘ǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 55

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VI

კҞᒵ

კ 1 ೸ᔸٛНޑ਻ϾᆶНᇃ਻Ϸߘᅀελޑᜢ߯ǾǾǾǾǾǾǾ 7 კ 2 ל๵բҔᐒڋǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 26 კ 3 ೸ᔸࡋෳ၂ᐒѠǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 30 კ 4 ٛН܄၂ᡍᐒѠǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 32 კ 5 ೸਻܄၂ᡍᐒѠǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 34 კ 6 ᙃނНࢱҔࢱՊᐒǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 34 კ 8!ל๋Ѧጕ၂ᡍᐒѠǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 36

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VII

߄Ҟᒵ

߄ 2!ӚᅿߘᅀமࡋޑКၨǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 5 ߄ 2 ೸ᔸٛНуπמೌϩ݋ǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 10 ߄ 3 όӕԋጢБԄ܌׎ԋᖓጢᄬ೷ޑ੝܄КၨǾǾǾǾǾǾǾǾ 12 ߄ 4 Ьा๋Ѧጕ֎ԏᏊǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 22 ߄ 5 ל๵уπતᙃࠔ܌٬Ҕϐל๵ٛᡖᏊ(ఠ๵Ꮚǵל๵Ꮚ) ǾǾǾ 26 ߄ 6 ኘНᏊКٯჹᚆࠠѲຑ՗ෳ၂ǾǾǾǾǾǾǾǾǾǾǾǾǾ 40 ߄ 7 ଯ೸ᔸٛНጢ׷ނ܄ຑ՗ǾǾǾǾǾǾǾǾǾǾǾǾǾǾǾ 40 ߄ 8 ӚᅿΒనࠠௗ๱ᏊᗺຠᔸԄጢނ܄ຑ՗ǾǾǾǾǾǾǾǾǾ 42 ߄ 9 Ӛᅿᔸ਻ϸᔈࠠ዗ᅙጤᗺຠᔸԄጢނ܄ຑ՗ǾǾǾǾǾǾǾ 43 ߄ 10 όӕѲᅿϐଯ೸ᔸٛНતᙃࠔނ܄ຑ՗ǾǾǾǾǾǾǾǾǾ 45 ߄ 11 όӕל๋ѦጕᏊϐଯ೸ᔸٛНતᙃࠔނ܄ຑ՗ǾǾǾǾǾǾ 46 ߄ 12 ଯ೸ᔸٛН/ל๋Ѧጕ/ל๵܄તᙃࠔނ܄ຑ՗ǾǾǾǾǾǾ 49 ߄ 24!ᚉໆғౢଯ೸ᔸٛНӭфૈ܄તᙃࠔނ܄ຑ՗ǾǾǾǾǾǾ 52