1. Introduction
• Semiconductor devices
• Semiconductor technology
It should be completely understood that anything with the possibility of violating the law of copyright should not be cited in this lecture note. All the illustrative figures and/or numerical examples must be referred to the assigned textbook.
For academic use in the lectures of Prof. KC Hsu at FJU only.
All other rights are preserved. Any unauthorized copying, editing, exhibition, renting, exchanging, posting, publication, performance, diffusion and/or broadcast of this slide notes or any part thereof is strictly prohibited. And any such action establishes liability for a civil action and may rise to criminal prosecution.
What is Semiconductor?
Conductivity between conductor and insulator Conductivity can be controlled by dopant
Si and Ge
Compound semiconductors
– SiGe, SiC
– GaAs, InP, GaAsxP1-x, GaxIn1-xAsyP1-y, etc.
Why is Si?
Sand?
Thermal stability
SiO2 is easy to form
SiO2 can be used as diffusion mask
Dopant and Resistivity
Higher concentration, more carriers Higher conductivity, lower resistivity Electrons move faster than holes
N-Si has lower resistivity than p-Si
Basic Devices:
Resistor Capacitor Inductor Diode
Bipolar Transistor MOS Transistor
Major issues:
First transistor, 1947 by Bardeen & Brattain First single crystal Ge, 1950
First single crystal Si, 1952 First IC device, TI, 1958
First IC product, Fairchild Camera, 1961 a 4-transistor IC sold for $150
Basic Circuits
Bipolar PMOS NMOS CMOS BiCMOS
Devices with Different Substrates
Bipolar MOSFET BiCMOS Si
GaAs: up to 20 GHz device LED
Compound
Bipolar: high speed devices Ge
Dominate IC industry
Bipolar IC:
Earliest IC chip
1961, four bipolar transistors, $150.00 Market share reducing rapidly
Still used for analog and power devices TV, VCR, Cellar phone, etc.
PMOS
First MOS field effect transistor, 1960
Used for digital logic devices in the 1960s Replaced by NMOS after the mid-1970s
NMOS
Faster than PMOS
Used for digital logic devices in 1970s and 1980s
Electronic watches and hand-hold calculators Replaced by CMOS after the 1980s
CMOS
Most commonly used circuit in IC chip since 1980s
Low power consumption High temperature stability High noise immunity
Symmetric design
BiCMOS:
Combination of CMOS and bipolar circuits Mainly in 1990s
CMOS as logic circuit Bipolar for input/output Faster than CMOS
Higher power consumption
Likely will have problem when power supply voltage dropping below one volt
IC Chips:
Memory
Microprocessor
Application specific IC (ASIC)
Memory Chips:
Devices store data in the form of electric charge Volatile memory
– Dynamic random access memory (DRAM) – Static random access memory (SRAM)
Non-volatile memory
– Erasable programmable read only memory (EPROM) – FLASH (EEPROM-electrically EPROM)
DRAM
Major component of computer and other electronic instruments for data storage
Main driving force of IC processing development One transistor, one capacitor (one bit)
Refreshing ckt is needed
SRAM:
Fast memory application such as computer cache memory to store commonly used instructions
Unit memory cell consists of six transistors (6T) or 4T with resistors
Much faster than DRAM
More complicated processing, more expensive
EPROM:
Non-volatile memory
Keeping data ever without power supply
Computer bios memory which keeps boot up instructions
Floating gate
UV light memory erase
Moore’s Law:
Number of transistors doubled every 12 months while price unchanged
Limit of the IC device
Atom size:
Need some atoms to form a device
Likely the final limit is around 100 Å About 30 silicon atoms
Theoretical limit: at least 20 atoms
Basic Bipolar Process Steps
Buried layer doping
Epitaxial silicon growth
Isolation and transistor doping Interconnection
Passivation
The 1970s
Bipolar dominant NMOS
Main driving force: electronic watches and calculators
The 1980s
MOSFET surpassed bipolar CMOS
Multi-level interconnections
Main driving force: personal computer
1980’s CMOS Technology
LOCOS
PSG and reflow Evaporator
Positive PR
Projection printer Plasma /wet etch
New Materials: Cu
New Materials: Low-k New Materials: High-k
Next Generation Lithography
The 2000s
Chap 2 Atoms and electrons in Crystals
• semiconductor materials
• basic crystal structure
• Bohr model for H-atom
It should be completely understood that anything with the possibility of violating the law of copyright should not be cited in this lecture note. All the illustrative figures and/or numerical examples must be referred to the assigned textbook.
For academic use in the lectures of Prof. KC Hsu at FJU only.
All other rights are preserved. Any unauthorized copying, editing, exhibition, renting, exchanging, posting, publication, performance, diffusion and/or broadcast of this slide notes or any part thereof is strictly prohibited. And any such action establishes liability for a civil action and may rise to criminal prosecution.
Applications: Si: rectifiers, transistors, ICs
compounds: high speed devices and photonic devices Binary: GaN, GaP, GaAs in LED; GaAs, InP in microwave devices
Ternary: AlGaAs in lasers Quarternary: InGaAsP in lasers ZnS: fluorescent materials
InS, CdSe, PbTe, HgCdTe: light detectors
Si,Ge: infrared and nuclear radiation detectors
Energy gap (Eg in eV) determines the wavelength of absorbed/emitted light by the semiconductor
Lattice: periodic arrangement of atoms in a crystal
A unit cell: repeated throughout the crystal Primitive cell: the smallest repeated cell R= ma + nb +pc
Miller indices: h, k, l
From sand to wafer:
Sand
Sand to MGS
React MGS with HCl to form TCS Purify TCS
React TCS to H2 to form EGS Pull single crystal ingot
Defects in Epitaxy LayerLine dislocation
Stacking Fault Impurity Particle
Hillock
The photoelectric effect: (a) electrons are ejected from the surface of a metal when exposed to light of frequency n in a vacuum; (b) plot of the maximum kinetic energy of ejected electrons vs. frequency of the incoming light.
Photoelectric effect: Em= hν – qΦ
Bohr model for H-atom
1. Electrons exist in certain stable, circular orbits about the nucleus.
2. Electron may shift to an orbit of higher/lower energy, thereby
gaining/losing energy equal to the difference in the energy levels.
3. The angular momentum Pθ of the electron in an orbit is an integral multiple of h/2π, or ħ=h/2π.
c=3x108m/sec R=109678/cm (Rydberg constant)
E2 hν E1
+ -
r -q
n > m-1
§ Schrödinger wave eq 1
2
2 2
−
∂ = Ψ
= ∂ Ψ + Ψ
∇
− j
j t
m V h
h
m: mass V: potential Ψ: wave function of (x, y, z, t)
classic: K.E. + P.E.=total quantum:
j t x V
m
E m V
p
∂ Ψ
= ∂ Ψ
∂ + Ψ
− ∂
= +
h h
2 2 2
2
2 2
) E ( e F
1 ) 1
E (
F (E E )/kT n
F =
= + −
2 Ei Ev Ec
Nc ln Nv 2
kT 2
Ev
EF= Ec + + ≈ + =
k=1.38x10-23 J/°K, EF: Fermi level; T: temperature in °K
1.F(E) denotes the probability of an available energy state at E being occupied by an electron at absolute temp T
2.if E=EF, the occupation probability is ½
3.at 0°K, the energy states below EF are all filled, above EF are all empty 4.the Fermi function is symmetrical about EF
5.in intrinsic materials, Ef must lie above the middle of Eg, i.e.,
6.For n-Si, Fermi level is close to the conduction band; for p-Si, Fermi level is close to the valence band
7.F(E) only denotes the occupation probability at E if there are available states, i.e., no state available at E, it’s impossible to find an electron ther
Fermi Dirac distribution:
Intrinsic semiconductor: E- f=Ei and n=p=ni
i2 o
o p n
n =
Mass action law:
Æ Temp dependent
Chap 3 Carrier transport phenomena
○ Carrier drift, diffusion
○ Generation and recombination processes
○ Continuity equation
○ Thermionic emission process
○ Tunneling process
○ High-field effects
It should be completely understood that anything with the possibility of violating the law of copyright should not be cited in this lecture note. All the illustrative figures and/or numerical examples must be referred to the assigned textbook.
For academic use in the lectures of Prof. KC Hsu at FJU only.
All other rights are preserved. Any unauthorized copying, editing, exhibition, renting, exchanging, posting, publication, performance, diffusion and/or broadcast of this slide notes or any part thereof is strictly prohibited. And any such action establishes liability for a civil action and may rise to criminal prosecution.
Electron mobility is greater than hole mobility due to smaller effective mass.
Lattice scattering: carrier scattered by a vibration of lattice resulting from temperature
Impurity scattering: scattering arisen form crystal defect
c c
o d
c o
d
c o
, v
, v
/ 1
ε ε
ε μ
ε ε
ε μ
ε ε
μ μ
>>
≈
<<
≈
= +
µ
عc ع
wt L wt
R L
ρ
=σ
1=
Ohmic contact: contact surface is a perfect source/sink of both type carriers and has no tendency to
inject/collect either electrons or holes, i.e., an electron leaves the left end and another electron enters the right end. A hole reaches the right end to combine with an electron, and a hole appears at the left end to maintain the charge neutrality.
p n
conduction
p p
p
n n
n
p p n
n
p p
J J
J
dx qD dp
p q
J
dx qD dn
n q
J
q D kT
D
q D kT
+
=
−
=
+
=
=
=
=
ε μ
ε μ
μ μ
μ
Einstein relation
Current density equation
Drift and diffusion directions for electrons and holes in a carrier gradient and an electric field. Particle flow directions are indicated by dashed arrows, and the resulting currents are indicated by solid arrows.
p n
cond
p p
p n
n n
J J
J
dx qD dp
p q
dx J qD dn
n q
J
+
=
−
= +
= μ ε μ ε
0
0 <
< dx
dp dx
dn
J(diff.) of minority carriers contributes the current, J(drift) of minority carriers is neglected.
Experimental arrangement for photoconductive decay measurements, and a typical oscilloscope trace.
The photoconductive decay measurement can measure the effects of recombination and trapping.
σ(t) = q [ n(t)µn + p(t)µp ]
The time dependence of carrier concentration can be
monitored by recording the sample resistance as a function of time.
For extrinsic materials, the carrier concentrations are given as
where EF is the Fermi level and Ei is the intrinsic Fermi level.
However, the above eqs. are only meaning when no excess carriers exist. Here we define quasi Fermi level EFn and EFp for electrons and holes, respectively, to denote the steady state carrier concentrations in similar forms
Quasi Fermi-level
kT E
i E kT o
E i E
o n e F i p n e i F
n = ( − )/ = ( − )/
kT E
E kT i
E
ie EFn i p n e i Fp
n
n = ( − )/ = ( − )/
The above expressions can be seen as defining the quasi Fermi level relations of steady state carrier concentrations under
nonequilibrium conditions with excess carriers generated. When excess carriers are present, the deviations of EFn and EFp from EF indicate how far the electron and hole concentration are from the equilibrium values no and po.
The above U is the indirect recombination rate under low injection in n type Si. Under injection pn>ni²,
recombination restore to equilibrium pn=ni². Under carrier extraction pn<ni² (reverse bias), carriers must be generated by the center.
In steady state, the electrons entering and leaving the conduction band; and the holes entering and leaving the valence band must be equal.
The continuity equations for minority carriers under low injection
p
no p n
p n p n
p n n
n
po p
n p
n p
n n
p p
p G p
x D p
x p p x
t p
n G n
x D n
x n n x
t n
ε τ ε μ
μ
ε τ ε μ
μ
− −
∂ + + ∂
∂
− ∂
∂
− ∂
∂ =
∂
− −
∂ + + ∂
∂ + ∂
∂
= ∂
∂
∂
2 2 2 2
np: minority carriers in p-type Si pn: minority carriers in n-type Si
under steady state: ∂⁄∂t=0
Drift and diffusion of a hole pulse in an n-type bar: (a) sample geometry; (b) position and shape of the pulse for several times during its drift down the bar.
⎟⎟
⎠
⎞
⎜⎜
⎝
⎛ − +
+ −
=
=
∂
= ∂
∂ −
− ∂
∂
∂
p p
p 2 t
t D 4
) t x
(
p no
n
n
n p
n p n
2 n 2
p
t e D 4
p N )
t , x ( p
) x ( N )
0 , x ( p .
C . B
t p p
x p x
D p
τ ε
μ
δ π
δ δ
δ τ
δ ε δ
δ μ
Chap 4 P-N junction, metal junction.
• thermal equilibrium
• depletion region
• I-V characteristics
• charge storage and transient behavior
• Si/metal junction
It should be completely understood that anything with the possibility of violating the law of copyright should not be cited in this lecture note. All the illustrative figures and/or numerical examples must be referred to the assigned textbook.
For academic use in the lectures of Prof. KC Hsu at FJU only.
All other rights are preserved. Any unauthorized copying, editing, exhibition, renting, exchanging, posting, publication, performance, diffusion and/or broadcast of this slide notes or any part thereof is strictly prohibited. And any such action establishes liability for a civil action and may rise to criminal prosecution.
In thermal equilibrium, for the condition of zero net electron and hole currents, the Fermi level must be constant throughout the whole sample.
Equilibrium: no external excitation and no net current flowing
bi p
n kT / ) E E ( i
n n
n
bi n
p kT / ) E E ( i
p p
p
dx V d
e n n
dx qD dn
n q
J
dx V d e n p
dx qD dp
p q
J
i F
F i
=
⇒ −
−
=
=
+
=
−
=
⇒ −
−
=
=
−
=
−
−
ψ ψ ψ
ε
ε μ
ψ ψ ψ
ε
ε μ
C W
2
W V qN
qN
) V V
( W 2
N W N
N N
2 V q
N 1 N
1 N
1
s 2 bi B
B bi s
2 D
A
D A
s bi
D A
B
ε
ξ ξ ξ
=
=
= −
= +
+
=
po po
p
no no
n
n n
n
p p
p
−
≈
−
−
≈
−
Reverse bias depleting minority carriers is
“extraction of minority” forward bias is
“injection of majority.” The reverse
saturation current depends on the minority diffusion from the neutral region to the
depletion edge. Quasi Fermi levels in reverse bias can go inside the band.
[ ]
t t
t
t t
V / V rec
diff F
V 2 / V r
rec i
V 2 / i V
t o max th
p n
i t
i n
n
V / V 2
i t o th
V / 2 V i n
n
e J
J J
2 e J qWn
2 e
n N U v
) kT (
/ ) E E
( cosh n
2 n
p
) 1 e
( n N U v
e n n
p
η
τ σ
σ σ σ
≈ +
=
=
≈
− = +
+
= −
=
Under forward bias, the holes/electrons exceed their equilibrium values and attempt to return equilibrium by recombination: capture in depletion region.
t s
t
V / no V
p 2
p d
V ) I
J J
V ( A dV
A dJ G
kT e p L
Aq
dV A dQ
C
t
≈ +
=
=
=
=
(
/− 1 )
= AJ
se
V Vtdx ) t , x ( p qA
) t ( Q
0 t
e I
) t ( Q
I )
0 ( Q
; 0 t
0 )
t ( i If
t ) t ( Q )
t ( ) Q
t ( i
q p t
q p x
J
p x
J q 1 t
p
p 0
/ t p p
p p
p
p p
p p
p p
p p
p
∫
∞−
⇒ =
>
⇒ =
=
>
=
∂ +∂
=
∂ +
= ∂
∂
−∂
⇒
∂ −
− ∂
∂ =
∂
δ τ
τ τ
τ δ δ
τ δ δ
τ
) I
/ I
1 ln(
t
qAL ) t ( ) Q
t ( p
t ,
) t ( Q )
t ( ) Q
t ( i
R F
p sd
p p
p p
p p
+
=
=
∂ + ∂
=
τ δ
τ
2
1( )⎥
⎦
⎢ ⎤
⎣
⎡
= − +
R F
p F
sd I I
erf I
t τ (too length to be derived)
Semiconductor/metal contact
1. Work function qΦ 2. Affinity qχ
3. Fermi level energy EF electron with probability=½ to jump to EC
4. Schottky contact: a contact with rectifying Ohmic contact: a contact without blocking 5. flatband voltage: VFB=Φms
Φm > Φs for a p-type semiconductor,
Ohmic contacts b.t. metal–semiconductor Φm < Φs for an n-type semiconductor,
Schottky contacts b.t. metal–semiconductor
Φm < Φs for a p-type semiconductor, Φm > Φs for an n-type semiconductor,
Under forward bias: transport of electron/hole
‘ EF
Ec
Ev
qV 1
2 3
4
metal semiconductor
Tunneling effect
EF
EF
Ec
Ec Ev
Ev
δ
δ’
‘
Contact resistance:
Vt
e Bn
T qA
k V cm R J
V c
/
*
2 1
0
= φ
⋅ Ω
⎟⎠
⎜ ⎞
⎝
⎛
∂
= ∂
−
=
Chap 6 Metal/Oxide/Semiconductor (MOS)
1. MOS diode:
2. MOSFET:
3. Device scaling:
4. CMOS:
It should be completely understood that anything with the possibility of violating the law of copyright should not be cited in this lecture note. All the illustrative figures and/or numerical examples must be referred to the assigned textbook.
For academic use in the lectures of Prof. KC Hsu at FJU only.
All other rights are preserved. Any unauthorized copying, editing, exhibition, renting, exchanging, posting, publication, performance, diffusion and/or broadcast of this slide notes or any part thereof is strictly prohibited. And any such action establishes liability for a civil action and may rise to criminal prosecution.
2 s
s 2
2
kT / q po p
kT / q po p
W 1 x
) x ( dx
d
e p p
e n n
⎥⎦⎤
⎢⎣⎡ −
⇒ =
−
=
=
= −
ψ ξ ψ
ρ ψ
ψ ψ
m A
sc
A B s
m
B )
inv ( s
kT / q
i s
W qN
Q
qN 2 W 2
2 e n
n B
−
=
=
=
=
ψ ξ
ψ ψ
strong inversion: ψ
) inv ( s o
m T A
1
2 A s
2 ox o
j s
s o
s 2 s A
o s o
C W V qN
d N
q
V 1 2
C C C W
V V
2
W qN
C V Q
ψ ξ
ξ ξ
ψ ψ ξ
+
=
⎟⎟
⎠
⎞
⎜⎜
⎝
⎛ +
=
=
+
=
=
=
−
j o
j o
C C
C C C
= +
In practice, work function difference is function of impurity concentration and there are charges in Si/SiO2 and within oxide. We need apply a negative voltage to the gate to obtain flat-band.
s m
ms
V
FB= φ = φ − φ
Flat-band voltage
Qit is orientation dependent:
<100> < <110> < <111>;
Qf is positive dependent on
oxidation/annealing/orientation Æ <100> preferred for MOS;
Qot is defect in oxide removed by low T annealing;
Qm is mobile in oxide under high V/high T
W d
x W d
d 1 x
Q dx Q
x x
Q 0 dx
d
s
m x o
0 s
s
o ox
m s
+
<
<
⎟⎠
⎜ ⎞
⎝
⎛ − −
= −
=
<
<
−
=
= ⇒
∫ ξρ ξ
ε ξ
ξ ρ ε
o
ot m
ms f FB
d
0 m
m
d
0 ot
ot
d o 0
FB
ox
o o
o ox
s
C
Q Q
V Q
dx )
x ( d x
Q 1
dx )
x ( d x
Q 1
dx )
x ( d x
1 C
V 1
) x x
( Q
) x ( Q
dx d
+
− +
=
=
=
⎥⎦⎤
⎢⎣⎡
−
=
− +
= −
=
∫
∫
∫
φ
ρ ρ
ρ
ξ
δ δ
ξ ρ ε
• Without applied bias: n+-p-n+ back-to- back p-n junctions Æ only reverse
leakage current
• VGS>VT: surface inversion forms channel, once VDS>0 Æ current conducts
• further increase of VDS, IDS goes up with slow rate and finally saturated.
Assumptions for the I-V characteristics of a MOSFET
1. Gate structure corresponds to an ideal MOS diode, i.e., VFB=0, Φms=0, no trap/interface charges.
2. Drift current is under consideration, diffusion current is neglected.
3. Inversion carriers are with constant mobility.
4. Uniform substrate doping
5. Reverse current leakage is ignored.
6. Gradual channel approximation, i.e., transverse electrical field >> longitudinal electrical field.
[ ]
⎪⎭
⎪⎬
− ⎫ +
−
⎩⎨
⎧ ⎟
⎠
⎜ ⎞
⎝
⎛ − −
=
= ⇒
=
−
=
+
=
∫
2 3 B 2
3 D B
o
A s
D D
B G
o n
D
D
x n 0
A sc
B s
) 2
( )
V 2
C ( qN 2
3 2
2 V 2 V
L V I ZC
dR I
dV
dx ) x ( qn )
y ( Q
) y ( W qN
Q
) y ( V 2
) y (
i
ψ ξ ψ
μ ψ
ψ ψ
[ ]
( )
( G T) D
o n
D
o D n
G m D
2 T G
o n
Dsat
2 2 G
B G
Dsat n
2 3 B 2
3 D B
o A s
D D
B G
o n
D
V V L V
I ZC
L V ZC V
g I
V L V
2 I ZC
K V 1 2
1 K 2
V V
0 ) L ( Q
) 2 ( )
V 2
C ( qN 2
3 V 2
2 2 V
L V I ZC
−
=
∂ =
= ∂
−
≈
⎟⎟⎠
⎞
⎜⎜⎝
⎛ − + +
−
=
=
⎪⎭
⎪⎬
− ⎫ +
⎩ −
⎨⎧
⎟⎠
⎜ ⎞
⎝
⎛ − −
=
μ
μ μ
ψ
ψ ξ ψ
μ ψ
in saturation
transconductance VD<VG-VT (linear) VD≥VG-VT (saturation)
Subthreshold characteristics of a MOSFET. VG<VT: surface
weakly invertedÆ diffusion is dominated in the lateral npn BJT (SBD).
( )
t T
G
t D
t B
s
V / ) V V
( D
T G
s
V / V V
/ ) i (
D n
e I
V V
e 1
L e
n I qAD
−
−
−
⇒ ∝
−
≈
−
=
ψ
ψ ψ
o
BS B
A B s
o f ms
T C
V qN
C
V Q 2 (2 )
2 +
+ +
−
= ξ ψ
ψ φ
Threshold voltage control:
1. ion-implantation: adjust NA at Si-SiO2 surface:
NA VT
2. Gate oxide thickness: d VT
3. Substrate bias: (reverse bias) |VBS| VT 4. Gate material due to Φms
Threshold voltage adjustment using substrate bias.
o
BS B
A B s
o f ms
T C
V qN
C
V Q 2 (2 )
2 +
+ +
−
= ξ ψ
ψ φ
Δ
− Δ
−
=
+ +
=
' L
' L
Z Z L
L C
2 Q V
V eff eff
o B sc
FB
T ψ
L VT
1. Shorter channel: punch-through becomes easily occursÆ breakdown voltage is
lowered
2. Shorter channel: longitudinal field
increasesÆ mobility reduced due to surface scattering
3. Channel length modulation will reduce gD in saturation
I-V characteristics of a short channel MOSFET.
[ ]
( G T )2 oDsat
o n
Dsat
2 3 B 2
3 D B
o A s
D D
B G
o n
D
I V
L V 2 I ZC
) 2 ( )
V 2
C ( qN 2
3 V 2
2 2 V
L V I ZC
=
−
=
⎪⎭
⎪⎬
− ⎫ +
⎩ −
⎨⎧
⎟⎠
⎜ ⎞
⎝
⎛ − −
=
μ
ψ ξ ψ
μ ψ
in saturation
Long channel
Short channel Leff ↘ I ↗
Scaling rules: constant ع-field scaling
old parameter L, new parameter L’=L/κ,
scaling factor κ>1 Æ d’=d/κ, Z’=Z/κ, A’=A/κ², ع’=V’/L’=V/L=ع Æ V’=V/κ,
dع/dx=qND/ξÆ ع=qND(x-W)/ξ= qND’(x’- W’)/ξ=ع’ÆND’=κND
Co’=ξox/d’=κ ξox/d =κCo Æ Cox=ACo ÆCox’=A’Co’=Cox/κ
Considerations of limits of IC
Intrinsic device limitations:
quantum limit:
gate oxide thickness:
critical electric field
saturation velocity (vs):
thermal limit of switching energy
Considerations of limits of IC
wiring limitations
electromigration limit interconnections:
wire resistance
power limitations. The max allowable temp rise
The max. power dissipation
technology limits: lithography/ min size
new materials?
RC delay
Prevention of latch-up with a heavily doped substrate.
1. β reduction
2. resistive shunting 3. epi-wafer
4. twin-well process
5. Trench isolation.
6. Si-on-insulator