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[PDF] Top 20 Temperature dependence of rate coefficients of reactions of NO2 with CH3S and C2H5S

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Temperature dependence of rate coefficients of reactions of NO2 with CH3S and C2H5S

Temperature dependence of rate coefficients of reactions of NO2 with CH3S and C2H5S

... positive temperature dependence contributes more to the apparent rate coefficient than in cases of HS and CH 3 ...basis of present kinetic data, reaction 1 is ... See full document

5

Experimental and theoretical studies of rate coefficients for the reaction O(P-3) plus C2H5OH at high temperatures

Experimental and theoretical studies of rate coefficients for the reaction O(P-3) plus C2H5OH at high temperatures

... predicted with CVT/SCT are in satisfactory agreement with experimental values, indicating the SCT method treats tunneling effects ...temperatures, rate coefficients predicted with ... See full document

11

Experimental and theoretical investigations of rate coefficients of the reaction S(P-3)+O-2 in the temperature range 298-878 K

Experimental and theoretical investigations of rate coefficients of the reaction S(P-3)+O-2 in the temperature range 298-878 K

... ⫺2 s ⫺1 reported by Grillo, Reed, and ...profiles ofS兴 t with re- actions 共1a兲, 共1b兲, and 共4兲–共12兲 with a commercial kinetic modeling program FACSIMILE ; 41 ... See full document

9

Study on the Reaction of CH2 with H-2 at High Temperature

Study on the Reaction of CH2 with H-2 at High Temperature

... conclusion of this study, in agreement with Friedrichs and Wagner, 25 is that the importance of 1 CH 2 in the reaction of CH 2 + H 2 has been ... See full document

6

Experimental and theoretical investigation of rate coefficients of the reaction S(P-3)+OCS in the temperature range of 298-985 K

Experimental and theoretical investigation of rate coefficients of the reaction S(P-3)+OCS in the temperature range of 298-985 K

... population of energy level E in well i at time t, ␻ is the collisional frequencies, E 0i is the ground- state energy of well i, P i 共E,E ⬘ 兲 is the transition probability for a molecule in well i ... See full document

11

Production of H and O(P-3) Atoms in the Reaction of CH2 with O-2

Production of H and O(P-3) Atoms in the Reaction of CH2 with O-2

... treatment of the reaction systems increases the di fficulty in estimating the branching fractions of the ...ozonolysis of alkenes and structures of carbonyl oxides and their ... See full document

10

Ab Initio Chemical Kinetics for SiH2 + Si2H6 and SiH3 + Si2H5 Reactions and the Related Uninnolecular Decomposition of Si3H8 under a-Si/H CVD Conditions

Ab Initio Chemical Kinetics for SiH2 + Si2H6 and SiH3 + Si2H5 Reactions and the Related Uninnolecular Decomposition of Si3H8 under a-Si/H CVD Conditions

... The rate constants for the bimolecular reactions SiH 2 + Si 2 H 6 and SiH 3 + Si 2 H 5 and the related unimolecular decomposition processes can ... See full document

13

RATES OF THE REACTIONS CN+H2CO AND NCO+H2CO IN THE TEMPERATURE-RANGE 294-769 K

RATES OF THE REACTIONS CN+H2CO AND NCO+H2CO IN THE TEMPERATURE-RANGE 294-769 K

... Our values are in reasonable agreement with the only reported measurement of kl; the rate coefficients for reaction (2) have not been previously reported.. [6] investi[r] ... See full document

7

Computational study on the mechanisms and energetics of trimethylindium reactions with H2O and H2S

Computational study on the mechanisms and energetics of trimethylindium reactions with H2O and H2S

... characterization of thin semiconducting indium oxide films due to their obvious application as transparent conductive electrodes in optoelectronic devices, such as solar ...InN/TiO 2 nanoparticle solar cell ... See full document

8

Catalytic incineration of C2H5SH and its mixture with CH3SH over a Pt/Al2O3 catalyst

Catalytic incineration of C2H5SH and its mixture with CH3SH over a Pt/Al2O3 catalyst

... NCINERATION OF C 2 H 5 SH AND I TS M IXTURE WITH CH 3 SH OVER A Pt/Al 2 O 3 C ATALYST By Hsin Chu, 1 Yiing-Yuan Chiou, 2 Kuen-How ... See full document

5

Effect of solvent on reactions of Cp2Zr{(μ-H)2BHR}2 and Cp2ZrH{(μ-H)2BHR} (R = CH3, Ph) with B(C6F5)3

Effect of solvent on reactions of Cp2Zr{(μ-H)2BHR}2 and Cp2ZrH{(μ-H)2BHR} (R = CH3, Ph) with B(C6F5)3

... structures of cations of compounds 35 are shown in ...Figs. 2–4. The corresponding crystallographic data, selected bond distances and bond angles are given in Tables ... See full document

10

Reactions of ether-phosphine ruthenium hydride complexes with carbon disulfide and phenylacetylene: crystal structures of Ru(CO) Cl(P?O)3(η2-S2CH and Ru(CO) Cl(P?O)2(η2-S2CH)

Reactions of ether-phosphine ruthenium hydride complexes with carbon disulfide and phenylacetylene: crystal structures of Ru(CO) Cl(P?O)3(η2-S2CH and Ru(CO) Cl(P?O)2(η2-S2CH)

... 5a and 5b are obtained in high yields as yellow air-stable products which are soluble in dichloromethane but insoluble in nonpolar solvents.. The phenyl groups are o[r] ... See full document

10

Cyclopentadienyl chromium complexes with halide, methyl, isothiocyanate and isoselenocyanate ligands: Structures of [η5-(C5H4-COOCH3)]Cr(NO)2(Br) and [η5-(C5H4-COOCH3)]Cr(NO)2(N=C=S)

Cyclopentadienyl chromium complexes with halide, methyl, isothiocyanate and isoselenocyanate ligands: Structures of [η5-(C5H4-COOCH3)]Cr(NO)2(Br) and [η5-(C5H4-COOCH3)]Cr(NO)2(N=C=S)

... gen with Merck Kiesel-gel 60. The silica gel was heated with a heat gun during mixing in a rotary evaporator attached to a vacuum pump for 1 h to remove water and ...[9] and 18, were ... See full document

11

Experimental and quantum-chemical studies on dissociative photoionization of c-C2H4S

Experimental and quantum-chemical studies on dissociative photoionization of c-C2H4S

... photoionization of thiirane (c-C 2 H 4 S) in a region ∼9–20 eV was investigated with photoionization mass spectroscopy and calculations of molecular energies ... See full document

4

Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)5PPh2]2(?-C5H2S3)

Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)5PPh2]2(?-C5H2S3)

... The metal carbonyl fragment is crucial for the formation of 2, since treatment of the analogous organic species Et2NC(S)SCH2C-CH with Et3N or PhCH2NH2 resulted in no re[r] ... See full document

2

Synthesis, spectra and crystal structure of (E)-(CO)2(NO)Cr[(η5-C5H4)–CH=CH(η5-C5H4)]Cr(CO)2(NO)

Synthesis, spectra and crystal structure of (E)-(CO)2(NO)Cr[(η5-C5H4)–CH=CH(η5-C5H4)]Cr(CO)2(NO)

... consistent with the X-ray structure of 13, a compound with its Cp rings bearing an elec- tron-withdrawing ...angle of 13 is 177.2° (Fig. 5, Table ...isomer of 13i is ... See full document

10

Syntheses, spectra and crystal structure of (CO)2(NO)Cr(η5-C5H4)CH2(η5-C5H4)Fe[vinyl-(η5-C5H4)]

Syntheses, spectra and crystal structure of (CO)2(NO)Cr(η5-C5H4)CH2(η5-C5H4)Fe[vinyl-(η5-C5H4)]

... Volume Formula units/cell Formula weight Density (talc.) Absorption coefficient WOO) Diffractometer used Radiation Temperature Monochromator 28 range Scan type Scan speed [r] ... See full document

13

Photochemistry of the Dinitrosyl Iron Complex [S5Fe(NO)2]- Leading to Reversible Formation of [S5Fe(μ-S)2FeS5]2-:  Spectroscopic Characterization of Species Relevant to the Nitric Oxide Modification and Repair of [2Fe?2S] Ferredoxins

Photochemistry of the Dinitrosyl Iron Complex [S5Fe(NO)2]- Leading to Reversible Formation of [S5Fe(μ-S)2FeS5]2-: Spectroscopic Characterization of Species Relevant to the Nitric Oxide Modification and Repair of [2Fe?2S] Ferredoxins

... data of complex 1 are sum- marized in Table 2 and in Supporting ...crystal of 1 chosen for the X-ray diffraction study is 0.25 × 0.20 × 0.20 mm 3 in size and was mounted on a ... See full document

9

Syntheses, spectroscopy and fluxional behavior of the η3-crotyl, C3H4(CH3), pyrolidinyldithiocarbamate molybdenum complexes: crystal structure of exo-[Mo{η3-C3H4(CH3)}(η2-S2CNC4H8)(CO)(η2-dppm)]

Syntheses, spectroscopy and fluxional behavior of the η3-crotyl, C3H4(CH3), pyrolidinyldithiocarbamate molybdenum complexes: crystal structure of exo-[Mo{η3-C3H4(CH3)}(η2-S2CNC4H8)(CO)(η2-dppm)]

... instrument and referenced to polystyrene standard, using cells equipped with calcium fluoride ...dried and deoxygenated by reflux- ing over the appropriate reagents before ...THF and benzene ... See full document

8

Cyclopentadienyl chromium and tungsten complexes with halide, methyl and σ-phenylethynyl ligands: Structures of (η5-C5H5)Cr(NO)2(–C≡C–C6H5), (η5-C5H5)Cr(NO)2I and [(η5-C5H4)-COOCH3]W(CO)3Cl

Cyclopentadienyl chromium and tungsten complexes with halide, methyl and σ-phenylethynyl ligands: Structures of (η5-C5H5)Cr(NO)2(–C≡C–C6H5), (η5-C5H5)Cr(NO)2I and [(η5-C5H4)-COOCH3]W(CO)3Cl

... electrons of tungsten atom are much more shielded from the nucleus by the extra shell of electrons, d and f electrons, therefore much easier to be pushed about and more ba- sic, than those ... See full document

9

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