對於希望定量分析氣體流量，必須要製作精確的檢量線圖，首先要先決定動 相氣體，動相氣體必須是高純度氣體，這樣才能確保在熱傳導偵檢器(Thermal Conductivity. Detector；TCD)進行分析時能夠準確判斷樣品造成的影響。其次，
由於實驗設計上常會遇到必須同時檢測兩種氣體流量的狀況，此時必須選擇兩種 (Bubble Flow Meter)較為合適，只是由於皂泡流量計需以人工計時進行流量換算，
誤差較大。
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因此在計算積分面積時必須要以穩定之後的峰值做計算。
圖 6.3：He 氣 2 mol%之原始數據。
圖 6.4：He 氣 30 mol%之原始數據。
如同在 4.4.1 提到的，利用混合不同濃度的氣體分別做氣相層析儀測試，可 以得到不同濃度下的不同積分面積，將積分面積與濃度做圖，就可以得出不同濃 度下應有的積分面積值之檢量線，如同圖 4.11，此檢量線必須經過原點，求得回 歸曲線方程式。
利用回歸曲線方程式，在實際測量的時候，將測得的積分面積代入回歸曲線 方程式，藉此反推該氣體濃度，以此判斷該氣體穿透薄膜或是漏氣量為多少。
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第7章 參考文獻
[1] J. A. Ratafia-Brown, et al., "An environmental assessment of IGCC power systems," pp. 23 – 27, 2002.
[2] S. P. Kaldis, et al., "Energy and capital cost analysis of CO2 capture in coal IGCC processes via gas separation membranes," Fuel Processing Technology, vol. 85, pp. 337-346, 2004.
[3] U. Balachandran, et al., "Hydrogen separation by dense cermet membranes,"
Fuel, vol. 85, pp. 150-155, 2006.
[4] W. Chen, et al., "On the assembling of Pd/ceramic composite membranes for hydrogen separation," Separation and Purification Technology, vol. 72, pp.
92-97, 2010.
[5] S.-Y. Jeon, et al., "Hydrogen separation by Pd–CaZr0.9Y0.1O3-x cermet composite membranes," Separation and Purification Technology, vol. 79, pp.
337-341, 2011.
[6] X. Meng, et al., "Ni–BaCe0.95Tb0.05O3-x cermet membranes for hydrogen permeation," Journal of Membrane Science, vol. 401-402, pp. 300-305, 2012.
[7] S. Adhikari and S. Fernando, "Hydrogen Membrane Separation Techniques,"
Industrial & Engineering Chemistry Research, vol. 45, pp. 875-881, 2006.
[8] K. SCA, "Status review on membrane systems for hydrogen separation,"
Energy Center of Netherlands: Petten, The Netherlands, 2004.
[9] 胡蒨傑 and 魏大欽, "21 世紀的新森林—氣體分離薄膜," 薄膜科技, vol.
429, pp. 29-37, 2008.
[10] V. Dembovský, "Thermodynamics of dissolution and liberation of gases in the atomization of molten metals by plasma-induced expansion," Journal of Materials Processing Technology, vol. 64, pp. 65-74, 1997.
[11] J. Okazaki, et al., "An investigation of thermal stability of thin palladium–silver alloy membranes for high temperature hydrogen separation,"
86
Journal of Membrane Science, vol. 366, pp. 212-219, 2011.
[12] S. Yun and S. Ted Oyama, "Correlations in palladium membranes for hydrogen separation: A review," Journal of Membrane Science, vol. 375, pp.
28-45, 2011.
[13] G. L. Holleck, "Diffusion and solubility of hydrogen in palladium and palladium--silver alloys," The Journal of Physical Chemistry, vol. 74, pp.
503-511, 1970.
[14] A. Holt, et al., "The Diffusion of Hydrogen through Palladium," Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, vol. 91, pp. 148-155, 1915.
[15] S. Ilias, et al., "Application of Electroless Deposited Thin-Film Palladium Composite Membrane in Hydrogen Separation," Separation Science and Technology, vol. 32, pp. 487-504, 1997/01/01 1997.
[16] S. K. Lilov, "Determination of the Effective Kinetic Diameter of the Complex Molecules," Crystal Research and Technology, vol. 21, pp. 1299-1302, 1986.
[17] M. Shah, et al., "Current Status of Metal–Organic Framework Membranes for Gas Separations: Promises and Challenges," Industrial & Engineering Chemistry Research, vol. 51, pp. 2179-2199, 2011.
[18] Y. H. Ma, et al., "Characterization of Intermetallic Diffusion Barrier and Alloy Formation for Pd/Cu and Pd/Ag Porous Stainless Steel Composite Membranes," Industrial & Engineering Chemistry Research, vol. 43, pp.
2936-2945, 2003.
[19] Y. J. Ou, et al., "Nanostructures of Pd–Ni alloy deposited on carbon fibers for sensing hydrogen," Journal of Alloys and Compounds, vol. 569, pp. 130-135, 2013.
[20] S.-Y. Cho, et al., "Microstructural changes in grain interior and grain boundary by formation of metastable and stable phases related to age-hardening in an Au-Cu-Ag-Pd alloy," Journal of Materials Research, vol. 28, pp. 1211-1217, 2013.
[21] Ö. N. Doğan, et al., "Ordered bcc phases in a Cu–Pd–Mg hydrogen separation
87
membrane alloy," Journal of Alloys and Compounds, vol. 528, pp. 10-15, 2012.
[22] S.-K. Ryi, et al., "Pd-Cu alloy membrane deposited on alumina modified porous nickel support (PNS) for hydrogen separation at high pressure,"
Korean Journal of Chemical Engineering, vol. 29, pp. 59-63, 2012.
[23] B. AC, "Inorganic Membranes for Energy and Environmental Applications,"
springer verlag, 2008.
[24] L. Huang, et al., "Palladium membranes supported on porous ceramics prepared by chemical vapor deposition," Thin Solid Films, vol. 302, pp.
98-101, 1997.
[25] V. Jayaraman, et al., "Fabrication of ultrathin metallic membranes on ceramic supports by sputter deposition," Journal of Membrane Science, vol. 99, pp.
89-100, 1995.
[26] L. L. Hench and J. K. West, "The sol-gel process," Chemical Reviews, vol. 90, pp. 33-72, 1990.
[27] S.-E. Nam, et al., "Preparation of a palladium alloy composite membrane supported in a porous stainless steel by vacuum electrodeposition," Journal of Membrane Science, vol. 153, pp. 163-173, 1999.
[28] M. Cherry, et al., "Computational Studies of Protons in Perovskite-Structured Oxides," The Journal of Physical Chemistry, vol. 99, pp. 14614-14618, 1995.
[29] W. J, "Defect Chemistry and Proton Conductivity in Ba-based Perovskites,"
California Institute of Technology, 2005.
[30] W. G, et al., "Spectroscopy of the O-H and O-D stretching vibrations in SrTiO3 under applied electric field and uniaxial stress," Physical Review B, vol. 34, pp. 8406-8417, 1986.
[31] H. Uchida, et al., "Formation of protons in SrCeO3-based proton conducting oxides. Part II. Evaluation of proton concentration and mobility in Yb-doped SrCeO3," Solid State Ionics, vol. 36, pp. 89-95, 1989.
[32] C. Zuo, et al., "Effect of Zr-Doping on the Chemical Stability and Hydrogen Permeation of the Ni−BaCe0.8Y0.2O3-α Mixed Protonic−Electronic Conductor,"
88
Chemistry of Materials, vol. 18, pp. 4647-4650, 2006.
[33] S. Fang, et al., "CO2-Resistant Hydrogen Permeation Membranes Based on Doped Ceria and Nickel," The Journal of Physical Chemistry C, vol. 114, pp.
10986-10991, 2010.
[34] K. H. Ryu and S. M. Haile, "Chemical stability and proton conductivity of doped BaCeO3–BaZrO3 solid solutions," Solid State Ionics, vol. 125, pp.
355-367, 1999.
[35] H. Iwahara, "Proton conducting ceramics and their applications," Solid State Ionics, vol. 86–88, Part 1, pp. 9-15, 1996.
[36] N. Bonanos, "Oxide-based protonic conductors: point defects and transport properties," Solid State Ionics, vol. 145, pp. 265-274, 2001.
[37] W. B. Wang, et al., "Microstructures and proton conduction behaviors of Dy-doped BaCeO3 ceramics at intermediate temperature," Solid State Ionics, vol. 181, pp. 667-671, 2010.
[38] X.-J. Luo, et al., "Comparison of Aqueous and Non-Aqueous Tape Casting of Aluminum Nitride Substrates," Journal of the American Ceramic Society, vol.
88, pp. 497-499, 2005.
[39] S. A. Steward and L. L. N. Laboratory, Review of Hydrogen Isotope Permeability Through Materials: Lawrence Livermore National Laboratory, 1983.
[40] S. Samingprai, et al., "Chromium oxide intermetallic diffusion barrier for palladium membrane supported on porous stainless steel," Journal of Membrane Science, vol. 347, pp. 8-16, 2010.
[41] E. Fabbri, et al., "Does the increase in Y-dopant concentration improve the proton conductivity of BaZr1−xYxO3−δ fuel cell electrolytes," Solid State Ionics, vol. 181, pp. 1043-1051, 2010.
[42] Y. MASAHITO, et al., "Local Electronic Structure and Protonic Conductivity in Perovskite-Type Oxide, SrZrO3," Mater Trans, vol. 46, pp. 1131-1139, 2005.
[43] K. Shiratani, et al., "Synthesis and electrical conductivity of La-Sr-X-Mg-O
89
(X=Ti, Zr, Al) perovskite solid solution," Cer Int, vol. 37, pp. 7-7, 2011.
[44] K. D. Kreuer, "Aspects of the formation and mobility of protonic charge carriers and the stability of perovskite-type oxides," Solid State Ionics, vol.
125, pp. 285-302, 1999.
[45] T. Ishihara, Perovskite Oxide for Solid Oxide Fuel Cells: Springer London, Limited, 2009.
[46] D. Pergolesi, et al., "High proton conduction in grain-boundary-free yttrium-doped barium zirconate films grown by pulsed laser deposition,"
nature materials, 2010.
[47] S. B. C. Duval, et al., "Electrical conductivity of the proton conductor BaZr0.9Y0.1O3−δ obtained by high temperature annealing," Solid State Ionics, vol. 178, pp. 1437-1441, 2007.
[48] C. Kjølseth, et al., "Space–charge theory applied to the grain boundary impedance of proton conducting BaZr0.9Y0.1O3-δ," Solid State Ionics, vol. 181, pp. 268-275, 2010.
[49] T. Norby and R. Haugsrud, "Dense Ceramic Membranes for Hydrogen Separation," in Membranes for Energy Conversion, ed: Wiley-VCH Verlag GmbH & Co. KGaA, 2008, pp. 169-216.
[50] X. Guo and R. Waser, "Electrical properties of the grain boundaries of oxygen ion conductors: Acceptor-doped zirconia and ceria," Progress in Materials Science, vol. 51, pp. 151-210, 2006.
[51] 邱尊偉. 溶膠凝膠法製備質導陶瓷薄膜與粉體之特性研究. 國立交通大學, 碩士論文, 2012