5.3 生物陽極材料分析
5.3.2 生物陽極循環伏安法測試
將生物陽極做為工作電極做循環伏安法掃描，可以看出生物陽極上附著的微生 物種類，並比較微生物附著上石墨氈表面後，對整個陽極的電化學特性的影響。每 個陽極材料在 20mV/s 的掃描速率，進行 15 圈的循環掃描至電壓-電流圖趨於穩定，
其圖於 Figure 5-15 所示。在 Figure 5-15 (A)可以看出微生物附著後，與 Figure 5-3 相比，生物陽極材料在電位-0.15V 至-0.3V 有額外的氧化峰出現，而電位-0.35V 至
(A)
(B)
Figure 5-15 (A) Cyclic voltammograms of various biofilm anode materials in 65mM phosphate solution at scan rate of 20 mV/s, from V= -0.6V to 0.6V vs Ag/AgCl/KCl (3.5M) ,(B)Comparation between anode materials before and after inoculation .
結論
6
生物燃料電池是一種新型綠色能源技術，不僅擁有理論高能源轉換率、對環 境無危害，主要應用於廢水處理的領域，將原本需要被處理、降解的廢棄有機物 用於生產電能，達到碳足跡中無碳排放的環保能源。生物燃料電池的理論發電量 為 3.3-4.2kWh/kg-COD，若使用台灣的工業廢水發電，每年將可獲超過 20 億度 的電力。但目前的技術瓶頸在於陽極材料無法容納大量微生物，使功率密度太低、
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