• 沒有找到結果。

綜合此實驗,以含微量鋯(0.1wt%Zr)或釩(0.1wt%V)之兩種 A201 鑄造用鋁合金銲 料,經型鍛機擠型成銲條,再以此兩種銲條,用氬銲機(TIG)銲補 A201 鑄造用鋁合金 鑄件後,此兩種鑄件,經人工時效熱處理後之常溫(25℃)及高溫(230℃)機械性質,可 得到下列重要結論:

1. 含 微 量 鋯 (0.1wt%Zr) 或 釩 (0.1wt%V) 之 A201 鑄 造 用 鋁 合 金 , 於 凝 固 時 會 晶 出 Al3(Ti,Zr)相及 Al3(Ti,V)相,使鑄件晶粒明顯細化。

2.以微量鋯(0.1wt%Zr)或釩(0.1wt%V)之 A201 鑄造用鋁合金當銲條,用氬銲機(TIG) 銲補 A201 鑄造用鋁合金鑄件後,其銲道組織皆為等軸細小晶粒,經目視檢查、螢 光檢驗,皆無熱裂(Hot Cracking)發生。

3.以 A201 鑄造用鋁合金中添加(0.1wt%Zr)鋯及 A201 鑄造用鋁合金中添加 0.1wt%

V(釩)當銲條,銲補 A201 鑄造用鋁合金鑄件,此兩種銲件,經人工時效熱處理後之 常溫(25℃)抗拉強度分別為 A201 鑄造用鋁合金的 90%(372MPa/415MPa)及 88%(365 MPa /415MPa),延展性些微優於母材 A201 鑄造用鋁合金。

4.以 A201 鑄造用鋁合金中添加 0.1wt%Zr(鋯)及 A201 鑄造用鋁合金中添加 0.1wt%

V(釩)之兩種銲料當銲條,銲補 A201 鑄造用鋁合金鑄件,此兩種銲件,經人工時效 熱處理後之高溫(230℃)之抗拉強度分別為 A201 鑄造用鋁合金的 91%(284MPa/313 MPa)及 84%(262MPa/313MPa),延展性些微優於母材 A201 鑄造用鋁合金。

5.鑄件銲補前預熱,可大幅去除鑄件內所附著之水氣,使銲補後銲道不產生大量的 大、小氣孔,而獲得良好的機機械性質。

6.以此兩種銲料合金(含 0.1wt%Zr 及 0.1wt%V 之 A201 鑄造用鋁合金)當銲條,銲補 A201 鑄造用鋁合金之鑄造缺陷(如氣孔、縮孔、裂縫等),可藉銲補提高鑄件品質 二次合格率。

53

參考文獻

1.R. E. Reed-Hill and R. Abbaschian, “Physical Metallurgy Principles”, 3rd ed., PWS Publishing Company, 1991, pp.697-698

2.J. Raffin, US Patent No. 3475166, Oct. 26, 1969

3.J. R. Davis, “Aluminum and Aluminum alloys”, ASM Specialty Handbook, ASM International, 1994, pp.706-707

4.I. J. Polmear, G. Pons, Y. Barbaux, H. Octor, C. Sanchez, A. J. Morton, W. E. Borbidge and S. Rogers, “After Concorde:Evaluation of creep resistant Al-Cu-Mg-Ag Alloys”, Materials Science and Technology, 1999, Vol.15, pp.861-868

5.鄭嘉仁, “Mn 含量對 A201 鋁合金晶粒成長之影響”, 國立中央大學機械工程研究所 碩士論文, 1993

6.N. J. Davidson, “Review of the Mechanical Properties, Reliability and Usage of Ultra High Strength Aluminum and Application”, AFS, 1988, pp.232-247

7.B. C. Muddle and I. J. Polmear, “The Precipitate Ω Phase in Al-Cu-Mg-Ag Alloys”, Acta Metall., 1989, Vol.37, pp.777-789

8.R. J. Chester and I. J. Polmear, “TEM Investigation of Precipitates in Al-Cu-Mg-Ag and Al-Cu-Mg Alloys”, Micron, 1980, Vol.11, pp.311-312

9.K. M. Knowles and W. M. Stobbs, “The Structure of {100} Age-hardening Precipitates in Al-Cu-Mg-Ag Alloys”, Acta Cryst., 1988, B44, pp.207-227

10.J. R. Davis, “Aluminum and Aluminum alloys”, ASM Specialty Handbook, ASM International, 1994, pp.25

11.S. P. Ringer, W. Yeung, B. C. Muddle and I. J. Polmear, “Precipitate Stability in Al-Cu-Mg-Ag Alloys Aged at High Temperatures”, Acta Metall. Mater., 1994, Vol.42, pp.1715-1725

12.I. J. Polmear and M. J. Couper, “Design and Development of an Experimental Wrought

54

Aluminum Alloy for Use at Elevated Temperature”, Metallurgical Transaction A, 1988, Vol.19A, pp.1027- 1035

13.I. J. Polmear, G. Pons, Y. Barbaux, H. Octor, C. Sanchez, A. J. Morton, W. E. Borbidge and S. Rogers, “After Concorde: Evaluation of Creep Resistant Al- Cu-Mg-Ag Alloys”, Materials Science and Technology, 1999, Vol.15, pp.861-868

14.K. Hono, N. Sano, S. S. Babu, R. Okano and T. Sakurai, “Atom Probe Stuty of the Precipitation Process in Al-Cu-Mg-Ag Alloys”, Acta Metall. Mater., 1993, vol.41, pp.829-838

15.R. K. Wyss and R. E. Sanders, “Microstructure-Property Relationship in a 2xxx Aluminum Alloy with addition”, Metallurgical Transaction A, 1988, Vol.19A, pp.2523-2530

16.張志鴻, “銀含量對於 A201 鑄造鋁合金 Ω 相析出影響”, 國立中央大學機械工程研 究所碩士論文, 2000

17.A. Grag, Y. C. Chang and J. M. Howe, “Precipitation of the Ω Phase in an Al-4.0Cu-0.5Mg alloy”, Scripta Metallurgica et Materialia, 1990, Vol.24, pp.677-680 18.J. A. Taylor, B. A. Parker and I. J. Polmear, “Precipitation in Al-Cu-Mg-Ag Casting

Alloy”, Metal Science, 1978, Vol.12, No.10, pp.478-482

19.K. Hono, T. Sakurai and I. J. Polmear, “Pre-Precipitate Clustering in an Al-Cu-Mg-Ag Alloy”, Scripta Metallurgica et Materialia, 1994, Vol.30, No.6, pp.695-700

20.S. P. Ringer, K. Hono, I. J. Polmear and T. Sakurai, “Nucleation of Precipitates in Aged Al-Cu-Mg-(Ag) Alloys with High Cu:Mg Ratios”, Acta Materialia, 1996, Vol.44, No.5, pp.1883-1898

21.L. Reich, M. Murayama and K. Hono, “Evolution of Ω Phase in an Al-Cu-Mg-Ag Alloy – A Three-Dimensional Atom Probe Study”, Acta Materialia, 1998, Vol.46, No.17, pp.6053-6062

55

22.O. Beffort, C. Solenthaler, P. J. Uggowitzer and M. O. Speidel, “High toughtness and high strength spray-deposited AlCuMgAg-base alloys for use at moderately elevated temperatures”, Materials Science and Engineering A, 1995, Vol.191A, pp.121-134 23.R. E. Reed-Hill and R. Abbaschian, “Physical Metallurgy Principles”, 3rd ed., PWS

Publishing Company, 1991, pp.534-535

24.T. D. Burleigh, “The Postulated Mechanisms for Stress Corrosion Cracking of Aluminum Alloys”, Corrosion, 1991, Vol.47, pp.89-98

25.M. S. Misra and K. J. Oswalt, “Corrosion Behavior of Al-Cu-Ag (A201) Alloy”, Metals Engineering Quarterly, 1976, pp.39-44

26.“Aerospace Material Specification”, AMS, 1987, 4235A, AMS4236

27.劉偉隆,林淳杰,曾春風 ,陳文照編譯 “ 物理冶金第三版 ”, 全華科技圖書股份有 限公司, 2004, pp.14-45

28.B. Hemsworth, T. Boniszewski and N. F. Eaton, “Classification and Definition of High Temperature Welding Cracks in Alloys”, Metal Construction & Brit. Welding Journal, 1969, Vol.1, pp.5-16

29.F.Matsuda: Hot Crack Susceptibility of Metal , Advances in welding Metallurgy,JWS,1990,pp.26-58.

30.J. Koziarski, “Some Considerations On Weldability Of Aluminum Alloys”, Welding Journal, 1953, pp.970-986

31.J. R. Davis, “Aluminum and Aluminum alloys”, ASM Specialty Handbook, ASM International, 1994, pp.376-419

32.J. C. Borland, “Generalized Theory of Super-Solidus Cracking in Weld and Casting”, Brit. Welding Journal, 1960, Vol.7, No.8, pp. 508-512

33.Steeubergen and Thornton, “A Quantitative Determination of the condition for Hot Cracking During Welding for Aluminum Alloys”, Welding Journal, 1970, Vol.2,

56

pp.61-68

34.J. B. Arthur, “Fusion Welding of 24S-T3 Aluminum Alloy”, Welding Journal, 1955, pp.558-569

35.S. Kou, “Welding Metallurgy”, John Wiley And Sons NY, 1987, pp.129-295 36.R. P. Meister and D. C. Martin, “Welding of Aluminum and Alum

37.W. I. Pumphrey and D. C. Moore, “Cracking during and after Solidification in some Aluminum-Copper-Magnesium Alloys of High Purity”, J. Inst. Metals, 1948, Vol.73, pp.428-438

38.W. I. Pumphrey and J. V. Lyons, “Cracking during the Casting and Welding of the More Common Binary Aluminum Alloys of Commercial Quality”, J. Inst. Metals, 1948, Vol.74, pp.439-455

39.H. T. Kim, S. W. Nam and S. H. Hwang, “Study On the Solidification Cracking Behaviour of High Strength Aluminum Alloy Welds—Effect of Alloying Elements and Solidification Behaviours”, J. Mater. Sci., 1996, Vol.31, No.3, pp.2859-2864

40.A. F. Norman, V. Drazhner and P. B. Prangnell, “Effect of Welding Parameters on the Solidification Microstructure of Autogenous TIG Welds in an Al-Cu-Mg-Mn Alloy”, Materials Science & Engineering A, 1999, Vol.259A, pp.53-64

41.V. G. Davydov, T. D. Rostova, V. V. Zakharov, Yu. A. Filatov and V. I. Telagin,

“Scientific Principles of Making an Alloying Addition of Scandium to Aluminum Alloys”, Materials Science & Engineering A, 2000, Vol.280A, pp.30-36

42.A. F. Norman, P. B. Prangnell and R. S. McEwen, “The Solidification Behaviour of Dilute aluminum-Scandium Alloys”, Acta Materialia, 1999, Vol.46, pp.5715-5732 43.聶若光、洪炎輝、伍員鵬、鄭榮瑞、葉建宏, “添加 Sc 對 A201 高強度鑄造用鋁合

金 機 械 性 質 影 響 之 研 究 ”, 中 華 民 國 鑄 造 工 程 學 刊 , 第 二 十 九 卷 , 第 四 期,2003,pp.43-48

57

44.L. K. Lamikov and G. V. Samsonov, “Soviet Non-Ferrous Metals Res.”(USSR), 1964, vol.9, pp.79-83

45.K. A. Gschneidner and F. W. Calderwood, “Bull. Alloy Phase Diagr.”, 1989, Vol.10, pp.34-38

46.G. M. Novotny and A. J. Ardell, “Precipitation Of Al3Sc In Al-Sc Alloys”, Materials Science & Engineering A, 2001, Vol.318A, pp. 144-154

47.“Applications of Scandium In Al-Sc Alloys”, Ashurst Technology Web Page (http://www.scandium.org/Sc-Al.htm)

48.K. B. Hyde, A. F. Norman and P. B. Prangnell, “The Effect of Cooling Rate on the Morphology of Primary Al3Sc Intermetallic Particles in Al-Sc Alloys”, Acta Materialia, 2001, Vol.49, pp.1327-1337

49.L. L. Rokhlin, T. V. Dobatkina, N. R. Bochvar and E. V. Lysova, “Investigation of phase equilibria in alloys of the Al-Zn-Mg-Cu-Zr-Sc system”, Journal of Alloys and Compounds, 2004, Vol.367, pp.10-16

50.Z. Yin, Q. Pan, Y. Zhang and F. Jiang, “Effect of Minor Sc and Zr on the Microstructure and Mechanical Properties of Al-Mg Based Alloys”, Materials Science & Engineering A, 2000, Vol.280A, pp. 151-155

51.B. Forbord, W. Lefebvre, F. Danoix, H. Hallem and K. Marthinsen, “Three dimensional atom probe investigation on the formation of Al3(Sc,Zr)-dispersoids in aluminim alloys”, Scripta Materialia, 2004, Vol.51, pp.333-337

52.V. Ocenasek and M. Slamova, “Resistance To Recrystallization Due To Sc And Zr Addition to Al-Mg Alloys”, Material Characterization, 2001, Vol. 47, pp.157-162

53.E. A. Marquis and D. N. Seidman, “Nanoscale Structure Evolution Of Al3Sc Precipitation in Al(Sc) Alloys”, Acta Materialia, 2001, Vol.49, pp.1909-1919

54.D. N. Seidman, E. A. Marquis and D. C. Dunand, “Precipitation Strengthening at

58

Ambient and Elevated Temperature of Heat- Treatable Al(Sc) Alloys”, Acta Materialia, 2002, Vol.50, pp.4021- 4035

55.M. L. Kharakterova, “Phase Composition of Al-Cu-Sc Alloys at Temperatures of 450 and 500℃”, Izvestiya Akademii Nauk SSSR. Metally, 1991, No. 4, pp.195-199

56.V. V. Zakharov and T. D. Rostova, “On the Possibility of Scandium Alloying of Copper-Containing Aluminum Alloys”, Metal Science and Heat Treatment, 1995, Nol.37, No.1-2, pp.65-69

57.A. F. Norman, K. B. Hyde, F. Costello, S. Thompson, S. Birely and P. B. Prangnell,

“Examination of the Effect of Sc on 2000 and 7000 Series Aluminium Alloy Casting : For Improvements in Fusion Welding”, Materials Science & Engineering A, 2003, Vol.354A, pp. 188-198

58.K. Yu, W. Li, S. Li and J. Zhao, “Mechanical Properties and Microstructure of Aluminum Alloy 2618 with Al3(Sc,Zr) Phases”, Materials Science & Engineering A, 2004, Vol.368A, pp.88-93

59.簡朝棋, “A201 鋁合金添加稀土元素後之機械性能研究”, 國立台灣大學材料科學 與工程研究所碩士論文, 2002

60.陳永斌, “微量 Sc、Zr 對 Al-4.6Cu-0.3Mg-0.6Ag 合金微結構與機械性質之影響”, 國 立中央大學機械工程研究所碩士論文, 2004

61.M.Arhami,F.Sarioglu,A.Kalkanli,M.Hashemipour,“Microstructural Characterization of Squeeze-Cast Al-8Fe-1.4V-8Si”,Materials Science & Engineering A, 2008, pp.218-223 62. “ASTM E112-88”, Annual Book of ASTM Standards, 1990, Vol.03.NO.01

63.A. K. Mukhopadhyay, “On the Nature of the Second Phase Particles Present in an As-Cast Al-Cu-Mg-Ag Alloy”, Scripta Materialia, 1999, Vol.41, pp.667-672

64.A. K. Mukhopadhyay, “Compositional Characterization of Cu-Rich Phase Particles Present in As-Cast Al-Cu-Mg-(Li) Alloys Containing Ag”, Metallurgical and Materials

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