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Chapter 5 Discussion

5.3 The tectonic setting of the East Taiwan Ophiolite

The nature and tectonic setting of the East Taiwan Ophiolite is a topic that is still under debate (Suppe et al., 1981; Jahn, 1986; Chung and Sun, 1992; Shao, 2015).

Suppe et al. (1981) studied the stratigraphy of the Lichi formation of the Coastal Range of East Taiwan and suggested that the East Taiwan Ophiolite is a submarine scree deposit consisting of angular mafic and ultramafic plutonic blocks that formed at a ‘leaky’ transform fault offsetting (Liou et al., 1977, Suppe et al., 1981). Jahn (1986) presented geochemical and isotopic data of glassy basalts, gabbros and plagiogranites and considered that the East Taiwan Ophiolite is derived from a spreading ridge of an open ocean or marginal basin. Furthermore, Chung and Sun (1992) proposed that the East Taiwan Ophiolite formed at a slow spreading ridge environment. Shao (2015), however, compared the Hf isotope of gabbros, diorites and plagiogranites of the East Taiwan Ophiolite to similar rocks from other ophiolites and proposed that the East Taiwan Ophiolite is probably the result of upwelling of a fore-arc subduction zone.

The rock sequence of East Taiwan Ophiolite is described by previous studies (Liou et al., 1977, Liou and Ernst, 1979, Suppe et al., 1981, Chung and Sun, 1992) (Fig. 19). The red shale layers between plutonic rocks and the extrusive rocks indicate that it was exposed under the carbonate compensation depth (CCD) for a period of time, perhaps a deep ocean setting at great distance from land. If this is the case, a mid-ocean ridge setting seems to be more promising than the original ‘leaky olistostrome’ interpretation of Suppe et al. (1981). On the other hand the absence of boninite, an important mafic volcanic rock that is rich in both Mg and Si and

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commonly found at subduction zones, suggests the East Taiwan Ophiolite is unlikely to related to a suprasubduction zone (SSZ) type ophiolite or to any subduction-related setting. The relatively high εNd(T) values of the gabbroic ETO ophiolitic rocks (i.e. >

+9) also suggests that the fore-arc subduction interpretation is vulnerable

The bulk rock geochemistry and mineral geochemistry of peridotites can be used to distinguish between different tectonic settings (Dick and Bullen, 1984;

Bonatii and Michael, 1989; Arai, 1992, 1994; Kamenetsky et al., 2001; Hebert et al., 2003). Some major and trace elements such as Mg, Cr and Al content, that are relatively immobile during serpentinization, can retain their original concentration or ratio and thus be used for interpreting the tectonic setting. Dick and Bullen (1984) compared a wide range of abyssal and Alpine-type spinel bearing peridotite and categorized the rocks by Cr# as an indicator of the degree of the depletion of the mantle source. Bonatti and Michael (1989) have demonstrated that whole rock Mg#

and Al content, and Cr# of spinel can be effective in distinguishing peridotites derived at ridge settings, passive margin settings, pre-oceanic rift and oceanic trench settings. Arai (1994) reviewed and discussed the Fo-Cr# trends in peridotites in different conditions (e.g. ocean-floor, back-arc basin, fore-arc, oceanic hot-spot, island arcs, subcontinental, subcratonic peridotite).

In this study the classification scheme of Bonatti and Michael (1989) is applied to the bulk rock geochemistry and spinel chemistry of the ETO peridotites.

The Mg# of the peridotites from this study and previous work range between 90 and 93 which are typical of a mid-ocean ridge setting like the North Atlantic (Fig. 20).

The bulk rock aluminum content of the serpentinized peridotites, although somewhat

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depleted, is consistent with the Mg# and an oceanic ridge setting (Fig. 21). The Cr#

of spinel is a particularly robust indicator for the tectonic setting of peridotites because it is relatively unaffected by hydrothermal conditions commonly experience by oceanic peridotites (Dick and Bullen, 1984; Bonatii and Michael, 1989; Arai, 1994). The mineral chemistry of the spinels as shown in Figure 22 is consistent with the previous results of bulk aluminum and Mg#. Therefore the peridotite whole rock and spinel geochemistry indicate that the ETO was formed at a mid-ocean ridge setting which is consistent with the interpretations of Liou et al. (1977) and Jahn (1986). However, it is uncertain if the ETO was a slow-spreading ridge as proposed by Chung and Sun (1992).

.

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Figure 19. Rock sequence of East Taiwan Ophiolite (revised from Liou, 1977).

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Figure 20. Whole rock Mg number (revised from Bonatti, 1988).

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Figure 21. Whole rock aluminum content (revised from Bonatti, 1988).

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Figure 22. Spinel chrome number (revised from Bonatti, 1988).

100 5.4 Implications for the South China Sea

The East Taiwan Ophiolite, representing the rock sequence of the oceanic crust and uppermost mantle, is considered to be a preserved remnant of oceanic crust from either the South China Sea (Liou et al. 1977; Suppe and Liou, 1979; Liou, 1979;

Suppe et al., 1981; Jahn, 1986; Chung and Sun, 1992). The spinel chemistry, Nd isotopes and whole rock Mg# and Al2O3 content from the peridotites indicates that the rocks were likely formed at a Mid-Ocean Ridge setting. Therefore the ETO is more likely to be a remnant of the South China Sea because there was no other active spreading center located within the region during the Miocene.

The tectonic development of the South China Sea is a highly debated subject.

The duration of spreading, in particular, is a one of a number of issues that has yet to be fully resolved. Originally Taylor and Hayes (1980, 1983) proposed a magnetic anomaly chronology for South China Sea basin which is still widely accepted (11 to 5d, Taylor and Hayes, 1980, 1983; revised to 11 to 5c, Briais et al., 1993). They identified an E-W oriented spreading center between the Macclesfield Bank and Reed Bank (Fig. 23), where the symmetric anomalies 5d through 6c have been modeled to the north and south. Beyond the Macclesfield Bank and close to the South China were anomalies 7 to 11. The spreading ridge has a conjunction from NW-SE direction to E-W direction, and it is said to be a result of a ridge jump that occurred at anomaly 7 (~24.8-25 Ma) (Brais et al. 1993; Barckhausen and Roeser, 2004; Barckhausen et al. 2014; Li et al. 2014)

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Figure 23. South China Sea spreading ridge and magnetic anomalies (revised from Taylor and Hayes, 1983; Briais et al., 1993).

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Currently the duration of tectonic/magmatic activity of the South China Sea is widely accepted to be 32-15.5 Ma (Taylor and Hayes, 1980, 1983; Briais et al., 1993), however Barckhausen and Roeser (2004) suggested the South China Sea was active for only 12 Ma from 32 to 20.5 Ma, about 4-5 million years earlier than previous researches. Barckhausen et al. (2014) supported the interpretation by proposing a new spreading rate of the South China Sea before and after the ridge jump, suggesting a 56 mm/yr rate in the early stages and increasing to 72 mm/yr after the ridge jump in the central and NE sub-basin, and increasing to 80 mm/yr in the SW sub-basin. Li et al. (2014), based on the new deep tow magnetic anomalies and IODP Expedition 349 core, pulled back the age of spreading to 33-15 Ma and suggested the ridge jump occurred at ~23.6 Ma. Li et al. (2014) also disagreed the spreading rate that proposed by Barckhausen et al. (2014) as they pointing out that the spreading rate decreased from ~50 mm/yr to ~35 mm/yr at the later stage of the spreading instead of increasing to 72 mm/yr after the ridge jump. Chang et al. (2015) also commented on Barckhausen’s saying that Barckhausen and Roeser (2004) and Barckhausen et al. (2014) had neglected the radioactive age dating (Jahn, 1986) and nanofossil assemblage from the ETO (Hunag et al., 1979) and re-announced the slow-spreading ridge is the more plausible ocean spreading motion of the South China Sea.

If the East Taiwan Ophiolite is really a remnant of the South China Sea, the new age result dated in this study and by Shao (2015) suggest that magmatism and thus extensional tectonism of the South China Sea lasted until at least the mid Miocene (i.e. ~14 Ma) and is ~1.5 million years later than the accepted age now.

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Jahn (1986) predicted that the East Taiwan Ophiolite had a life span of < 10 Ma based on a spreading rate of ~10 cm/yr indicating that it traveled a maximum distance of 1000 km. However, the ~10 cm/yr rate may be too fast and the ~1000 km distance may be too large but a rate of 5-8 cm/yr and maximum distance of 500 km to 800 km may be suitable (Ben-Avraham and Uyeda, 1973; Hall et al., 1995; Teng and Lin, 2004). From previous studies, the collision of the Luzon Arc with the Eurasian continental margin took place at ~4-5 Ma. (Jahn, 1986; Teng, 1987, 1990, 2007). Thus the duration of the displacement of East Taiwan Ophiolite from the ridge to where it is now would take ~ 10 million years (i.e. ~14.3 Ma to ~4.5 Ma). Based on a 5-8 cm/yr moving rate and 10 million years duration, the possible displacement distance is between 500 km and 800 km, which are drawn as dashed circles in figure 24. Figure 24 shows the estimated part of the South China Sea spreading ridge (dashed line in figure 24) that was consumed beneath the Manila trench (Lee and Lawver, 1995; Zhu et al., 2004). The orange zone is the probable area that the spreading ridge would be and also as the possible place that formed the East Taiwan Ophiolite. Therefore as the Luzon arc collided with proto-Taiwan it likely brought fragments of the youngest portion of the South China Sea spreading center with. The oceanic fragments were accreted to Taiwan and become known as the ETO.

Table 6. Various age estimates of the South China Sea (SCS) basin from previous studies.

Authors Ages (Ma) Study Area Year of Publication Data used

Taylor and Hayes 32 – 17 East sub-basin 1980, 1983 Magnetic anomaly

Briais et al. 32 – 15.5 Central SCS basin 1993 Magnetic anomaly

Barckhausen and Roeser

31 – 20.5 Central SCS basin 2004, 2014 Magnetic anomaly

Hsu et al. 37 – 15 Central SCS basin &

NE SCS sub-basin

2004 Magnetic anomaly

Li et al. 33 – 15

33 – 16

NE SCS sub-basin SW SCS sub-basin

2014 Magnetic anomaly

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Figure 24. Tectonic development of the East Taiwan Ophiolite at 15 Ma. (revised from Lee and Lawver, 1995)

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106

Chapter 6

Conclusion

The new whole rock major and trace elemental and isotopic geochemistry, mineral chemistry and zircon U/Pb age date presented here and data from previously published works suggest that the East Taiwan Ophiolite has characteristics that are typically found in the oceanic crust that formed at a spreading ridge of an ocean basin.

The Cr# of spinel from the peridotite and bulk rock Al and Mg content are consistent with the oceanic ridge setting. The relatively high 143Nd/144Nd isotope ratio and the N-MORB-like REE pattern of the ETO gabbro also suggest a mid-ocean ridge environment. The mid Miocene zircon U/Pb age of the ETO gabbro is about ~1 Ma younger than the last magnetic anomaly of South China Sea (i.e. 5c) and suggests the tectonomagmatic activity was still ongoing at that time. The age result and assuming a 5-8 cm/yr moving rate, the possible emplacement distance is between 500 and 800 km which corresponds to an area of ~100 000 km2.

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