稱有機合成
1 H-NMR、 13 C-NMR
光譜圖
10 9 8 7 6 5 4 3 2 1 ppm 1.48 2.21 5.26 0.97
0.82
1.00
4.75 1.81 1.80
Current Data Parameters NAME PCN-p-CN EXPNO 4 PROCNO 1 F2 - Acquisition Parameters Date_ 20120329 Time 13.45 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 362 DW 69.000 usec DE 6.50 usec TE 298.3 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300087 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 1.14 1.36 1.15 5.22 1.02
0.95
1.00
1.93 3.11 2.00 1.87
Current Data Parameters NAME PCN-p-Br-1st EXPNO 4 PROCNO 1 F2 - Acquisition Parameters Date_ 20120327 Time 13.26 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 181 DW 69.000 usec DE 6.50 usec TE 298.5 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300096 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 1.04 2.06 5.06 0.98
0.90
1.00
4.95 1.87
1.86
Current Data Parameters NAME PCN-p-NO2-1st EXPNO 5 PROCNO 1 F2 - Acquisition Parameters Date_ 20120327 Time 13.35 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 256 DW 69.000 usec DE 6.50 usec TE 298.5 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300090 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 0.99 1.09 1.06 4.93 0.98
0.93
1.00
1.84 5.00 1.77
Current Data Parameters NAME PCN-p-Cl-1st EXPNO 5 PROCNO 1 F2 - Acquisition Parameters Date_ 20120327 Time 13.22 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 256 DW 69.000 usec DE 6.50 usec TE 298.5 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300096 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 0 ppm
10 9 8 7 6 5 4 3 2 1 ppm 1.21 2.19 5.06 0.96
0.90
1.00
2.85 0.96 1.00 1.82 1.82
Current Data Parameters NAME PCN-m-NO2 EXPNO 3 PROCNO 1 F2 - Acquisition Parameters Date_ 20120328 Time 21.25 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 256 DW 69.000 usec DE 6.50 usec TE 298.2 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300084 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 1.05 1.33 1.02 4.83 0.91
0.84
1.00
2.78 4.67 1.83
Current Data Parameters NAME PCN-Ph EXPNO 1 PROCNO 1 F2 - Acquisition Parameters Date_ 20120328 Time 11.03 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 322.5 DW 69.000 usec DE 6.50 usec TE 298.3 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300096 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 1.37 2.28 1.24 6.92 1.07 3.09 0.83
1.00
3.97 3.07 1.85
Current Data Parameters NAME PCN-p-Me EXPNO 1 PROCNO 1 F2 - Acquisition Parameters Date_ 20120130 Time 11.45 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 181 DW 69.000 usec DE 6.50 usec TE 299.3 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300109 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 2.48 1.13 6.03 1.05
0.87 1.00 2.92
1.96 1.87 3.03 1.84
Current Data Parameters NAME PCN-p-OMe EXPNO 1 PROCNO 1 F2 - Acquisition Parameters Date_ 20120120 Time 17.56 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 128 DW 69.000 usec DE 6.50 usec TE 301.6 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300113 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 0 ppm
10 9 8 7 6 5 4 3 2 1 ppm 2.2 4
5.9 5
2.0 1
0.8 1
1.0 0
1.9 8
4.0 7
1.9 0
Current Data Parameters NAME Hui203 EXPNO 10 PROCNO 1 F2 - Acquisition Parameters Date_ 20110922 Time 9.40 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 181 DW 69.000 usec DE 6.50 usec TE 299.7 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300096 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 2.51
6.57 1.10
0.99
1.00
2.10 1.01 3.32 2.07
Current Data Parameters NAME PCN-2-thienyl EXPNO 2 PROCNO 1 F2 - Acquisition Parameters Date_ 20120327 Time 13.30 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 181 DW 69.000 usec DE 6.50 usec TE 298.4 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300096 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 1.13 1.20 1.18 5.57 1.08
0.96
1.00
6.44 0.98 5.46
Current Data Parameters NAME PCN-2-Nath EXPNO 2 PROCNO 1 F2 - Acquisition Parameters Date_ 20120327 Time 13.11 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 128 DW 69.000 usec DE 6.50 usec TE 298.5 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300131 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 1.06 1.52 5.22 1.07 1.12
1.00
1.56 5.77 3.32
Current Data Parameters NAME PCN-o-Br EXPNO 6 PROCNO 1 F2 - Acquisition Parameters Date_ 20120217 Time 13.21 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT DMSO NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 128 DW 69.000 usec DE 6.50 usec TE 299.2 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300018 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 0.99 1.10 1.08 5.01 0.99
0.90
1.00
1.85 1.84 1.88 1.81
Current Data Parameters NAME PCN-p-Br-p-Br EXPNO 1 PROCNO 1 F2 - Acquisition Parameters Date_ 20120327 Time 14.27 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 322.5 DW 69.000 usec DE 6.50 usec TE 298.3 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300091 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 0 ppm
10 9 8 7 6 5 4 3 2 1 ppm 1.17 1.41 1.19 5.84 1.04
1.43 1.00 2.92
2.01 1.96 2.03 1.93
Current Data Parameters NAME Hui216 EXPNO 3 PROCNO 1 F2 - Acquisition Parameters Date_ 20111024 Time 20.52 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 8 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 71.8 DW 69.000 usec DE 6.50 usec TE 300.3 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300114 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 3.22 1.22 1.18 1.06
0.96 1.00
1.03
5.76 2.14 2.08
Current Data Parameters NAME H238 EXPNO 1 PROCNO 1 F2 - Acquisition Parameters Date_ 20111125 Time 21.03 INSTRUM spect PROBHD 5 mm PABBO BB- PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 1 DS 0 SWH 9057.971 Hz FIDRES 0.276427 Hz AQ 1.8088436 sec RG 228.1 DW 55.200 usec DE 6.50 usec TE 296.9 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 14.00 usec PL1 0 dB SFO1 500.1330008 MHz F2 - Processing parameters SI 16384 SF 500.1300129 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 3.74 1.93
1.13
1.03
1.00
2.16 7.19 2.39
Current Data Parameters NAME Et-A-p-Br EXPNO 4 PROCNO 1 F2 - Acquisition Parameters Date_ 20120220 Time 11.36 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 1 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 71.8 DW 69.000 usec DE 6.50 usec TE 296.5 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300136 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 3.97 2.35
1.14
1.07
1.00
6.70 2.56 2.39
Current Data Parameters NAME Et-A-p-NO2 EXPNO 2 PROCNO 1 F2 - Acquisition Parameters Date_ 20120222 Time 11.43 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT CDCl3 NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 228.1 DW 69.000 usec DE 6.50 usec TE 299.1 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300078 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 3.08 1.24
0.41 1.02
1.00 0.38
0.35 0.99
14.65
Current Data Parameters NAME Me-A-p-Br-500 EXPNO 5 PROCNO 1 F2 - Acquisition Parameters Date_ 20120218 Time 17.01 INSTRUM spect PROBHD 5 mm PABBO BB- PULPROG zg30 TD 32768 SOLVENT Acetone NS 16 DS 0 SWH 9057.971 Hz FIDRES 0.276427 Hz AQ 1.8088436 sec RG 161.3 DW 55.200 usec DE 6.50 usec TE 300.0 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 14.00 usec PL1 0 dB SFO1 500.1330008 MHz F2 - Processing parameters SI 16384 SF 500.1297793 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00
200 180 160 140 120 100 80 60 40 20 ppm
10 9 8 7 6 5 4 3 2 1 ppm 4.27
1.39
1.00 0.34
0.36 0.96
15.69
Current Data Parameters NAME Me-A-p-CN EXPNO 4 PROCNO 1 F2 - Acquisition Parameters Date_ 20120214 Time 22.10 INSTRUM spect PROBHD 5 mm BBO BB-1H PULPROG zg30 TD 32768 SOLVENT DMSO NS 16 DS 0 SWH 7246.377 Hz FIDRES 0.221142 Hz AQ 2.2610421 sec RG 256 DW 69.000 usec DE 6.50 usec TE 298.9 K D1 2.00000000 sec TD0 1 ======== CHANNEL f1 ======== NUC1 1H P1 11.70 usec PL1 4.00 dB SFO1 400.1324008 MHz F2 - Processing parameters SI 16384 SF 400.1300017 MHz WDW EM SSB 0 LB 0 Hz GB 0 PC 1.00