5 結果與討論
5.2 電池數值模擬
除了高溫氣體供應系統以外,另外完成具有初步流道設計的腔體的單極板以供單電池三明 治夾片核心使用。在陽極與陰極的外側必須加上interconnect 以便將反應產生的電能引出到負 荷電器去使用。而且,interconnect 還須包含氣體流道,以便將高溫氫氣引入至陽極,以及將 grid)、單流道蛇紋式(single-channel serpentine)、多流道蛇紋式(multi-channel serpentine)、對角 分歧式(diagonal bifurcation)。
圖五 陽極與電解質介面上不同流道所造成的氫氣質量分率分佈,電池的電壓為 0.3V
其流道面積佔總電導體面積之比值盡量維持在0.63 至 0.66,以期盡量減低 Ohmic resistance 對燃料電池效能之影響,將重心放在流道設計之分析上。經由初步的流場模擬,可得到在所 預估的燃料電池操作進氣量下,不同流道設計內之氣體、電流密度、溫度分佈與所需壓差的 差異。結果顯示,蛇紋式的流道設計在同樣的功率輸出情形下,其流道流阻較大,而容易造 成氣體在電極上分佈不均與較大的溫度梯度等等問題。此初步結果顯示針對完整的電池組進
X
0 0.002 0.004 0.006 0.008 0.01
Y
0 0.002 0.004 0.006 0.008 0.01
Y
0 0.002 0.004 0.006 0.008 0.01
Y
0 0.002 0.004 0.006 0.008 0.01
Y
行電化學、熱流、電性的數值模擬,能在設計初期幫助找出潛在問題。更進一步的流道設計
0 0.002 0.004 0.006 0.008 0.01
Y
0 0.002 0.004 0.006 0.008 0.01
Y
0 0.002 0.004 0.006 0.008 0.01
Y
0 0.002 0.004 0.006 0.008 0.01
Y
5.2.2 電流密度分佈
0 0.002 0.004 0.006 0.008 0.01
Y
0 0.002 0.004 0.006 0.008 0.01
Y
0 0.002 0.004 0.006 0.008 0.01
Y
0 0.002 0.004 0.006 0.008 0.01
Y
道設計會得到較均勻之溫度分佈,這可歸因於在單一流道中的燃料流速較快,導致較佳之散 熱效果的緣故。
6 Reference
[1] Kyoto Protocol, 1997, http://unfccc.int/resource/docs/convkp/kpeng.html, United Nations Framework Convention on Climate Change.
[2] F. Issacci, 2003, "Thermal Management and Transport Phenomena in Fuel Cell System -
Practical Issues," Proceedings of the The 6th ASME-JSME Thermal Engineering Joint Conference, March 16-20, Torrance, California.
[3] J. R. Ferguson, J. M. Fiard, and R. Herbin, 1996, "Three-Dimensional Numerical Simulation for Various Geometries of Solid Oxide Fuel Cells," Journal of Power Sources 58(2), pp. 109-122.
[4] H. Yakabe, T. Ogiwara, M. Hishinuma, and I. Yasuda, 2001, "3-D Model Calculation for Planar Sofc," Journal of Power Sources 102(1-2), pp. 144-154.
[5] Z. Lin, J. W. Stevenson, and M. A. Khaleel, 2003, "The Effect of Interconnect Rib Size on the Fuel Cell Concentration Polarization in Planar SOFCs," Journal of Power Sources 117(1-2), pp.
92-97.
[6] J. Larmine and A. Dicks, 2000, Fuel Cell Systems Explained, 1st ed., John Wiley & Sons, West Sussex.
[7] C. S. Montross, H. Yokokawa, and M. Dokiya, 2002, "Thermal Stresses in Planar Solid Oxide Fuel Cells Due to Thermal Expansion Differences," British Ceramic Transactions 101(3), pp. 85-93.
[8] H. Yakabe, M. Hishinuma, M. Uratani, Y. Matsuzaki, and I. Yasuda, 2000, "Evaluation and Modeling of Performance of Anode-Supported Solid Oxide Fuel Cell," Journal of Power Sources 6th Grove Fuel Cell Symposium: Fuel Cells - The Competitive Option for Sustainable Energy Supply, Sep 13-Sep 16 1999 86(1-2), pp. 423-431.
[9] K. P. Recknagle, R. E. Williford, L. A. Chick, D. R. Rector, and M. A. Khaleel, 2003,
"Three-Dimensional Thermo-Fluid Electrochemical Modeling of Planar SOFC Stacks," Journal of Power Sources 113(1), pp. 109-114.
[10] J. Yuan, M. Rokni, and B. Sunden, 2003, "Three-Dimensional Computational Analysis of Gas and Heat Transport Phenomena in Ducts Relevant for Anode-Supported Solid Oxide Fuel Cells,"
International Journal of Heat and Mass Transfer 46(5), pp. 809-821.
[11] C. W. Tanner and A. V. Virkar, 2003, "A Simple Model for Interconnect Design of Planar Solid Oxide Fuel Cells," Journal of Power Sources 113(1), pp. 44-56.
[12] J. A. Rock, 2004, "Converging/Diverging Flow Channels for Fuel Cell," 6699614 B2.
[13] H. H. Voss and C. Y. Chow, 1993, "Coolant Flow Field Plate for Electrochemical Fuel Cells,"
5230966.
[14] J. A. Rock, 2001, "Serially-Linked Serpentine Flow Channels for PEM Fuel Cell," 6309773 B1.
[15] J. A. Rock, 2000, "Mirrored Serpentine Flow Channels for Fuel Cell," 6099984.
[16] N. G. Vitale, 1999, "Fluid Flow Plate for Decreased Density of Fuel Cell Assembly," 5981098.
[17] M. H. Nelson, 2001, "Fuel Cell Channeled Distribution of Hydrogen Water," 6303245 B1.
[18] S. J. Granata and B. M. Woodle, 1989, "Fuel Cell Plates with Skewed Process Channels for Uniform Distribution of Stack Compression Load," 4853301.
[19] X. Ren and S. Gottesfild, 2001, "Flow Channel Device for Electrochemical Cells," 01/48852 A1.
[20] V. Gurau, F. Barbir, and Jay K. Neutzler, 2003, "Fuel Cell Collector Plates with Improved Mass Transfer Channels," 6551736 B1.
[21] Y. S. Yoo, H. C. Lim, J. W. Park, and S. H. Park, 2004, "Solid Oxide Fuel Cells Having Gas Channel," 2004/0091766 A1.
[22] J. A. Rock, 2001, "Serially-Linked Serpentine Flow Channels for PEM Fuel Cell," 6309773 B1.
[23] Nicholas G. Vitale, 1999, "Fluid Flow Plate for Decreased Density of Fuel Cell Assembly,"
5981098.
[24] F. M. White, 1991, Viscous Fluid Flow, 2nd ed., McGraw-Hill, New York.
[25] B. E. Poling, J. M. Prausnitz, and J. P. O'Connell, 2001, The Properties of Gases and Liquids, McGraw-Hill, New York.