Combining molecular imprinting and photonic crystal techniques, an advanced IPC sensing device was developed for convenient, sensitive and quick detection of BPA. The IPC can operate easily and directly couple a readable optical signal to report molecular recognition events immediately. The fabrication of the sensing device involves with self-assembly of PS colloidal crystals and infiltration of the PS template with BPA-imprinted sol solution. The temperature applied for the self-assembly dominated the quality of the colloidal crystals. In addition, the relative ratio among the constituents in the sol solution controlled the imprinted capability, rebinding capacities and sensitivities of the IPC. A close pack hexagonal colloidal crystals were obtained using 2.5 μL latex solutions at 50oC. When the ZPO/PTMOS/BPA/EtOH molar ratio was 30/1/1/80, the IPC exhibited the highest sensitivity. The presented sensing device is possesses three desirable and attractive features.
Firstly, the IPC is high affinity and molecule-specific for the imprinted BPA molecules from analogues. Secondly, the IPC exhibited a large linear detection range of 1-60 mg/L in pure water and of 1-100 mg/L in the raw water of Pao-Shan reservoir. The third and the most important one is that it included a rapid response time of 4 min, good recyclability and reproducibility due to the rational hierarchical structure. These properties enable the IPC been promising to be applied for in-situ and on-site analysis.
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Appendix
EDX patterns of MIP and IPC (ZPO/PTMOS/BPA/EtOH=30:1:1:80)
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