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The activities of MAPKs are necessary for the initiation of the innate immune

response. Both the activation of transcription factors by phosphorylation and the

stabilization of ARE-containing mRNA can help cells to produce pro-inflammatory

mediators or cytokines. The activations of MAPKs are turned off within several minutes,

and then the mRNAs of those pro-inflammatory mediators or cytokines will be

degraded rapidly. Some negative regulators such as Mkp-1 (phosphatase) and Ttp

(mRNA decay mediator) can help cells to return to the resting condition. Hence, the

gene expressions should be tightly controlled in both transcription and

post-transcription levels in the innate immune response.

We are the first to observe the protein expression profiles of endogenous TTP

family proteins during the period of LPS-stimulation in mouse macrophage RAW264.7

cells. There are two interesting observations. One is the protein expression profiles of

these three TTP family members were different, and the other is the uncorrelated mRNA

and protein expression profiles of Zfp36l1 and Zfp36l2.

Ttp was induced after LPS-stimulation, and Zfp36l1 and Zfp36l2 were constitutive

expressions (Figure 1A). This observation indicates that Zfp36l1 and Zfp36l2 may play

important roles in the resting condition, and the low expressions of pro-inflammatory

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mediators or cytokines are maintained by the mRNA destabilized abilities of Zfp36l1

and Zfp36l2.

As shown in Figure 1B, the mRNA expressions of Zfp36l1 and Zfp36l2 were

down-regulated after LPS-stimulation, but the protein expressions of Zfp36l1 and

Zfp36l2 were consistent. The mRNA expression profiles of Zfp36l1 and Zfp36l2 were

uncorrelated with their protein profiles after LPS-stimulation (Figure 1B). Some similar

observations of mRNA expression profiles of Zfp36l1 and Zfp36l2 were also reported

by Liang et al. [48] and Cao et al. [49]. This uncorrelated relationship implys the

expressions of Zfp36l1 and Zfp36l2 are regulated in the translational and

post-translational levels. The polysome analysis of their mRNA during LPS-stimulation

can be performed to verify the translational regulation. Furthermore, the

post-translational modifications such as phosphorylation (Figure 1C) may alter protein

stability [25]. Zfp36l1 and Zfp36l2 may be more stable in the hyper-phosphorylated

forms than the hypo-phosphorylated forms. Thus, their protein expression levels are

near consistent, even their mRNAs are decreased after LPS-stimulation.

To identify the possible mRNA targets of Zfp36l1 and Zfp36l2 in resting

macrophages, we knocked down Zfp36l1 and Zfp36l2 by using Lentivirus-carrying

shRNA. Based on previous reports, the candidates of mRNA targets are chosen by the

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ARE number in their 3’UTR, the associations with Ttp, and their mRNA expression

profiles which were categorized to the immediate-early genes [39,50].

In our study, the RNA and protein levels of Mkp-1 were increased in Zfp36l1,

Zfp36l2, and dual knockdown cells (Figure 2A, 2B). In addition, the RNA and protein

levels of Cox-2 were increased in the cells which Zfp36l2 was knocked down (Figure

2A, 2D). The mRNA expression levels of Mkp-1 and Cox-2 were increased through the

mRNA stabilities when Zfp36l1 and Zfp36l2 were knocked down, which were

correlated with the typical function of Zfp36l1 and Zfp36l2 in mRNA destabilization

(Figure 2C, 2E).

Tnf-α is one of the well-known targets of TTP family proteins. Much to our

surprise, the mRNA expressions of Tnf-α were decreased in all knockdown cells (Figure

2F). This result may be due to the importance of the transcription regulation of Tnf-α

mRNA controlled by activation of p38 MAPK [35]. Therefore, the increase of Mkp-1

expression in Zfp36l1 and Zfp36l2 knockdown cells repressed the activity of p38

MAPK (Figure 6A), which down-regulated the Tnf-D mRNA expression. Similarly, the

mRNA expression of Ccl-2 is also activated by p38 MAPK [51]. However, the mRNA

expression of Ttp and Icam-1 were no significant differences whether Zfp36l1 and

Zfp36l2 were knockdown or not (Figure 2F). The possible explanation is that the

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expressions of their mRNAs are controlled equally in both transcriptional and

post-transcriptional levels.

The mRNA targets of TTP family proteins are not all the same [52], although their

RNA binding domains are highly conserved. In Figure 2A and 2D, Cox-2 was the

Zfp36l2-specific mRNA target. However, the activity of luciferase containing Cox-2

3’UTR was down-regulated by both over-expressed Zfp36l1 and Zfp36l2 (Figure 3B).

This result indicates that both of Zfp36l1 and Zfp36l2 can recognize and destabilize the

Cox-2 mRNA in HEK 293T cells. However, overexpression of Zfp36l1 and Zfp36l2 in

HEK 293T cells may not reflect their “real” functions and the “real” conditions in

RAW264.7 cells. The RNA pull-down assay was shown that both of Zfp36l1 and

Zfp36l2 could associate with Cox-2 3’UTR in RAW264.7 cells (Figure 3C). Both of

Zfp36l1 and Zfp36l2 do not have enzyme activity of mRNA decay, so the difference of

their associated proteins may alter their functions. Mass spectrometry may be used to

identify the associated proteins of Zfp36l1 and Zfp36l2, and the detailed regulation can

be further studied. In conclusions, the mRNA expression of Cox-2 is Zfp36l2-specific

regulation in the post-transcriptional level.

The rapid mRNA activation of Mkp-1 after the LPS-stimulation was regulated

through mRNA stability (Figure 4A, 4B). In Figure 4C, the interaction between Zfp36l1

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and Mkp-1 3’UTR was consistent during LPS-stimulation, but the interaction between

Zfp36l2 and Mkp-1 3’UTR was variable with the protein expression of Zfp36l2. This

result suggests that the decline of Zfp36l2 on Mkp-1 3’UTR stabilizes Mkp-1 mRNA.

Knockdown of Zfp36l1 and Zfp36l2 increased the mRNA expression of Mkp-1 through

RNA stability in the early stage of LPS-stimulation (Figure 5A, 5B). This result

confirms that the mRNA activation of Mkp-1 is regulated by Zfp36l1 and Zfp36l2 after

LPS-stimulation.

In addition, the activation of Mkp-1 is also regulated by MAPKs in both

transcriptional and post-translational levels. The activation of ERK signaling pathway

increases the transcription of Mkp-1 [53], and the activation of ERK and p38 MAPK

signal pathway can increase the protein stability of Mkp-1 by phosphorylation [54,55].

Associated proteins may change the functions of Zfp36l1 and Zfp36l2. We were

the first to observe that TTP family proteins, Zfp36l1 and Zfp36l2, could associate with

deadenylase Caf1a and degrade mRNA targets by removing poly-A tails (Figure 4C).

However, Zfp36l1 could be phosphorylated after LPS-stimulation and form the complex

with 14-3-3 (Figure 4D). This complex may repress the function of Zfp36l1 [26], and

Mkp-1 mRNA can be stabilized.

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Knockdown of Zfp36l1 and Zfp36l2 increased the protein expression of Mkp-1

(Figure 6B), and the activity of p38 MAPK was down-regulated in the resting condition

(Figure 6A). Therefore, p-38 mediated mRNA expressions of Ttp and Tnf-α were

repressed (Figure 6C). According to the results, we proposed the following model for

the mechanism (Figure 7). In the resting condition, Zfp36l1 and Zfp36l2 destabilize

mRNA of Mkp-1, and the cells are sensitive to the stimuli such as LPS under the low

expression of Mkp-1. In LPS-stimulation, the induction of Mkp-1 mRNA is done by

hyper-phosphorylated Zfp36l1 which losing its ability of mRNA decay and decreasing

the expression of Zfp36l2.

A number of important ARE-containing genes are commonly involved in

inflammation and cancer [45]. Both MKP-1 and COX-2 have been reported playing

important roles in human cancers. MKP-1 is over-expressed in many human cancer cell

lines, including breast, lung, prostate, ovarian, pancreatic, liver, and gastric cancer [56],

and due to MKP-1 expression, the lung and ovarian cell lines are resistant to

chemotherapy such as cisplatin [57]. TTP mRNA and protein levels are significantly

decreased in tumors of the thyroid, lung, ovary, uterus, and breast compared to

non-transformed tissues [58,59]. Another study showed that the mRNA expression

levels of TTP family proteins were repressed in lung and ovarian cancers [60]. However,

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rare studies clearly elucidate the expression and function of three TTP family members

in a cancer cell. Combining previous researches with our observations, the possible

explanation of MKP-1 overexpression is losing of ZFP36L1 and ZPL36L2 in cancer

cells, and the detailed mechanism can be further investigated.

The abnormal expression of COX-2 in breast cancer cells is reported in many

studies[61,62], and it may involve in tumorigenesis and angiogenesis in the breast

cancers [63,64]. The relationship between COX-2 and TTP is confirmed [65], but

whether the overexpression of COX-2 is regulated by ZFP36L2 in breast cancer cells is

unclear.

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