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Volume 2010, Article ID 701096,16pages doi:10.1155/2010/701096

Research Article

On the Existence of a Weak Solution of a Half-Cell

Model for PEM Fuel Cells

Shuh-Jye Chern

1

and Po-Chun Huang

2

1Department of Mathematics, National Tsing-Hua University, Hsin-Chu 30013, Taiwan

2Department of Applied Mathematics, National Chiao-Tung University, Hsin-Chu 30010, Taiwan

Correspondence should be addressed to Po-Chun Huang,semihaha@math.nctu.edu.tw

Received 16 December 2009; Accepted 4 May 2010 Academic Editor: Katica R.Stevanovic Hedrih

Copyrightq 2010 S.-J. Chern and P.-C. Huang. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

A nonlinear boundary value problemBVP from the modelling of the transport phenomena in the cathode catalyst layer of a one-dimensional half-cell single-phase model for proton exchange membranePEM fuel cells, derived from the 3D model of Zhou and Liu 2000, 2001, is studied. It is a BVP for a system of three coupled ordinary differential equations of second order. Schauder’s fixed point theorem is applied to show the existence of a solution in the Sobolev space H1.

1. Introduction

The modelling of fuel cells has been an attractive topic in the field of electrochemical theory. In the last decade, models for proton exchange membrane PEM fuel cells have been formulated by many scientistssee, e.g., 1. Among these models, some complicated

systems of partial differential equations PDEs were constructed from principles of fluid mechanics, electrostatics, and heat transfers; however, most of them were solved by numerical simulations only. We are interested in the mathematical analysis of the system of differential equations and the discussion is restricted on the transport phenomenon of a single-phase model given by 2. The more complicated two-phase models, like those

mentioned in1,3, are not in the scope of this paper.

In4, by reducing space variables to one dimension and making several assumptions,

a system of PDEs in 5 was simplified to a boundary value problem BVP for a linear

system of decoupled ordinary differential equations ODEs, and an exact solution was constructed. In6, a 1D half-cell model reduced from 5 is considered; that model is a BVP

for a nonlinear system of three ODEs of second order which are no longer decoupled and it seems to be hard to find an exact solution. By Schaefer’s fixed point theorem, the study in6

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is able to show the existence of a solution in the space of continuously twice differentiable functions. In this paper, motivated by 4,6, we will derive a 1D half-cell model from the

3D model of 2; it is still a BVP for a nonlinear system of three ODEs of second order;

however, the nonlinearity is different from that of 6 and an alternative strategy will be

applied; namely, a weak formulation of the BVP will be considered. In this weak formulation, the function space is replaced by the Sobolev space H1 and an iteration process associated

with Schauder’s fixed point theorem will be adopted. The result of this paper indicates a direction of attacking the complicated system of PDEs for the modelling of PEM fuel cells.

Now, we briefly describe the contents of this paper. In Section 2, the governed equations and boundary conditions in the cathode catalyst layer for the 1D half-cell model of PEM fuel cells are derived. In Section 3, the weak form of a linear generalized Neumann problem is described. Existence and uniqueness of the generalized Neumann problem is guaranteed by the Lax-Milgram theorem and it will be shown that the solution for the linear problem has an a priori bound. In Section 4, Schauder’s fixed point theorem is applied to prove the existence of an H1solution for the nonlinear system of ODEs.

2. The Model

In this section, we will reduce a 3D model of Zhou and Liu2,7 to a 1D half-cell model. This

3D model was a modification of the 2D model given by Gurau et al.5, so the derivation of

the 1D model is quite the same with what we did in6, we describe the derivation here for

the reader’s convenience.

Recalle.g., see 8 the species equations are

0 ερDkeff∇2Yk

⎧ ⎨ ⎩

0, channel and diffusion layers,

ερSk, catalyst layer,

2.1

where Yk is the concentration of kth component gas mixture, and Dkeff is the effective

diffusivity of the kth component in the gas mixture, which is given by

Deffk  ⎧ ⎨ ⎩ Dk, channel, Dkε1.5, porous media. 2.2

At the cathode, the mass generation source terms Sk for oxygen, water, and protons are

jc/2Fc, −jc/2Fc, and jc/Fc, respectively. At the anode, the source terms for hydrogen

molecules and protons are −ja/2Fc and ja/Fc, where ja and jc are the transfer current

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is negative and jais positive. The relationships between ja, jcand the species concentration

YH2and YO2 are given by the Butler-Volmer equations

ja  airef0  a  YH2 YHref 2 1/2 exp αaF RT ηa − exp −1 − αaF RT ηa , jc  airef0  c  YO2 YOref 2  exp αcF RTηc − exp −1 − αcF RT ηc , 2.3

where a is the active catalyst surface area per unit volume of the catalyst layer, iref 0 is the

exchange current density under the reference conditions, T is the absolute temperature,

R is the universal gas constant, αa and αc are symmetric factors, and ηa and ηc are the

corresponding overpotentials. The energy equation is

0 keff∇2T

⎧ ⎨ ⎩

0, channels and diffusion layers,

Q, catalyst layer and membrane, 2.4

with keff ⎧ ⎪ ⎪ ⎨ ⎪ ⎪ ⎩ kg, channels, −2ks 1 ε/2ks kg   1 − ε/3ks , porous media, 2.5

where kg is the thermal conductivity of the gas while ks is the thermal conductivity of the

solid matrix of the porous media. The heat generation rates Q in different regions are given by Q ⎧ ⎪ ⎪ ⎪ ⎪ ⎪ ⎪ ⎨ ⎪ ⎪ ⎪ ⎪ ⎪ ⎪ ⎩ ja· ηa i 2 σcl

, anode catalyst layer, i2

σm, membrane

jc· ηc

i2

σcl, cathode catalyst layer.

2.6

Note that this is a main difference between the 3D model of 2 and the 2D model of 5.

The phase potential satisfies

∇ ·σ∇φ ⎧ ⎪ ⎪ ⎪ ⎨ ⎪ ⎪ ⎪ ⎩

jc, cathode catalyst layer,

0, membrane,

ja, anode catalyst layer,

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where φ is the phase potential, and σ is the ionic/electric conductivity which depends on T: σT  ηc kefflcl0.005139λ − 0.00326 exp 1268 1 303− 1 T . 2.8

The current density is given by

i −σ∇φ. 2.9

Next, we assume that T,Φ, Ykdepend on one space variable and restrict to the cathode

side of the catalyst layer, following4, only one species the oxygen i.e., k  1, and let

Y1 Y. For simplicity, the derivative with respect to x is denoted by  d/dx.

From2.4, the equation for energy becomes

T− kTY  λfTΦ2  0, x ∈ a, b, 2.10

where Φ is the catalyst layer phase potential, T is the energy, and Y is the oxygen mass fraction; fT ∈ C1

bR is a regularization of 1/λ · σT/keff away from T  0 so that

f≥ δ1> 0 is required, and kT ∈ C1bR is a regularization of

ηc keff  airef0  c  1 YOref 2  exp αcF RT ηc − exp −1 − αcF RT ηc . 2.11

By2.7, in the cathode catalyst layer, we have the following equation for the phase

potential  fTΦ gTY  0, x ∈ a, b, 2.12 where gT ∈ C1 bR is a regularization of − ηcjc kefflclY  − ηc kefflcl  airef0  c  1 Yref O2  exp αcF RTηc − exp −1 − αcF RT ηc . 2.13

And for the oxygen mass fraction, via2.2, we obtain the equation in the cathode catalyst

layer: Y− hTY  0, x ∈ a, b, 2.14 where hT ∈ C1 bR is a regularization of − jc 2FcDeffk Y  −1 Dkeff· 1 2Fc ·  airef0  c  1 YOref 2  exp αcF RTηc − exp −1 − αcF RT ηc . 2.15

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We can assume that h≥ δ2> 0. The boundary conditions for this 1D model are μ1Ta − μ2Ta  1, Tb  0,

Φb  βfTb · Φb  0, Φa  0, α1Ya − α2Ya  1, Yb  0,

2.16

where μ1, μ2, α1,α2, β > 0. It is convenient to let l b − a in the following discussions.

Note that the derivation of these boundary conditions can be found in6; therefore

we do not repeat here.

Now, we formulate a weak form of the boundary value problem2.10∼2.16.

LetΩ  a, b and consider T, Φ, Y ∈ H1Ω3; thus it is a weak solution of2.10∼

2.16 if the following equations hold:

μ 1Ta − 1 μ2 · ϕa − b a T· ϕdx b a kTYϕdx − λ b a fTΦ2ϕdx, ∀ϕ ∈ H1Ω, −1 βΦb · ϕb − b a fTΦ· ϕdx b a gTYϕdx  0, ∀ϕ ∈ H1Ω,α1Ya − 1 α2 · ϕa − b a Y· ϕdx b a hTYϕdx, ∀ϕ ∈ H1Ω. 2.17 For2.17, we have the following existence theorem.

Theorem 2.1. There exists at least one solution T, Φ, Y of 2.17 in H1Ω3.

3. Linear Results

Before we prove Theorem 2.1, some linear results should be proved and we still use the notation T, Φ, Y for the solution of the following weak linear generalized Neumann problem: − α1Ya − 1 α2 · ϕa − b a Y· ϕdx b a hTYϕdx, ∀ϕ ∈ H1Ω, 3.1 −1 βΦb · ϕb − b a fT∗Φ· ϕdx b a gTYϕdx 0, ∀ϕ ∈ H1Ω, 3.2 − μ 1Ta − 1 μ2 · ϕa − b a T· ϕdx b a kTYϕdx− λ b a fT∗Φ∗ 2 ϕdx, ∀ϕ ∈ H1Ω, 3.3 where T, Y∗,Φ∗∈ H1Ω. Since the equations for T, Φ, Y are decoupled, they can be treated

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The existence and uniqueness of the solution for the linear generalized Neumann problem3.1∼3.3 is guaranteed by the following Lax-Milgram Theorem see 9.

Theorem 3.1 A theorem on linear monotone operators. Let A : X → Xbe a linear

continuous operator on the real Hilbert space X. Suppose thatA is strongly monotone, that is, there is a c > 0 such that

Au, u ≥ c u 2 ∀u ∈ X, 3.4 then for each given b∈ X, the operator equation

Au  b, u ∈ X, 3.5

has a unique solution.

Next, we show that the solution for the linear problem has an a priori bound which can be shown to be independent ofT,Φ∗, Y∗ so that a domain for the iteration process exists.

Theorem 3.2. Suppose that Y, Φ, T is a weak solution for 3.1∼3.3, then one has

Y H1Ω≤ N1, 3.6

Φ H1Ω≤ N2 Y∗ ∞, 3.7

T H1Ω≤ N3Φ22 N4 Y∗ ∞ N5, 3.8 where N1, N2, N3, N4, N5are positive constants, and they depend on f , g , h .

Proof. 1◦ Equation 3.6 holds. Since

α1Ya − 1 α2 · ϕa − b a Y· ϕdx b a hTYϕdx, ∀ϕ ∈ H1Ω, 3.9

let ϕ Y ∈ H1Ω; therefore we have

α1 α2 Y2a  1 α2 Ya  b a Y2 dx b a hTY2dx≥ minδ2, 1 Y 2H1. 3.10

By3.10, we can get that

Y 2 H1 ≤ 1 minδ2, 1 −α1 α2 Y2a  1 α2 Yaminδ1 2, 1· 1 1α2 . 3.11

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2◦ Equation 3.7 holds. From 3.2, −1 βΦb · ϕb − b a fT∗Φ· ϕdx b a gTYϕdx 0, ∀ϕ ∈ H1Ω. 3.12

Thus let ϕ Φ ∈ H1Ω so that

−1 βΦ 2b − b a fT∗Φ2dx b a gTYΦdx  0. 3.13 It follows that b a fT∗Φ2dx −β1Φ2b  b a gTYΦdx ≤g Y∗ ∞ Φ 2· l1/2. 3.14 Since 0 < δ1 ≤ f, we have δ1 b a  Φ2 dx≤g Y∗ ∞ Φ 2· l1/2. 3.15

To prove3.7 we need a lemma see 10.

Lemma 3.3. Let X denote a real Banach space, and let u ∈ W1,p0, τ; X for some 1 ≤ p ≤ ∞.

Then

i u ∈ C0, τ; X (after possibly being redefined on a set of measure zero), and ii ut  us t

suxdx for all 0 ≤ s ≤ t ≤ τ. ByLemma 3.3, we get Φ 2 H1 b a |Φx|2dx b a Φx2 dx≤ b a b x Φtdt |Φb| 2 dx b a Φx2 dx. 3.16 By3.15, for 3.16, we arrive at Φ 2 H1≤ 2 b a b x Φtdt 2 dx 2 b a |Φb|2dx 1 δ1 g ∞ Y∗ ∞ Φ 2· l1/2 ≤ b aΦ tdt 2 · 2l  2Φb2l 1 δ1 g Y∗ ∞ Φ 2· l1/2. 3.17

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On the other hand, for3.2, we take ϕ  1 ∈ H1Ω, so we know that

Φb  β b

a

gTYdx. 3.18

Substituting3.18 into 3.17, we arrive at

Φ 2 H1 ≤ 2 b a Φt2 dt· l2 2β2 b a gTYdx 2 · l  1 δ1 l1/2g Y∗ ∞ Φ 2 ≤ 2 δ1 l5/2g ∞ Y∗ ∞ Φ H1 1 δ1 l1/2g ∞ Y∗ ∞ Φ H1 2β2l2g2 Y∗ 2. 3.19 Set x Φ H1, B 2/δ1l5/2 g Y  1/δ1l1/2 g Y , C 2β2l2 g 2 Y 2so that we have x2− Bx − C≤ 0. 3.20

Hence, we get that

xB   B2 4 C 2  1 2 ⎛ ⎝ 2 δ1 l5/2 1 δ1 l1/2  2 δ1 l5/2 1 δ1 l1/2 2  8β2l2 ⎞ ⎠g Y∗ ∞. 3.21 Take N2 1/22/δ1l5/2 1/δ1l1/2  2/δ1l5/2 1/δ1l1/22 8β2l2 g , and from 3.21, we get 3.7.

3◦ Equation 3.8 holds. For 3.3, take ϕ  T ∈ H1Ω; thus we have

μ1 μ2T 2a  1 μ2Ta − b a  T2dx b a kTYTdx− λ b a fT∗Φ∗2Tdx. 3.22

Now we introduce the following lemmasee 9.

Lemma 3.4. Let G be a bounded region in RNwith N≥ 1, and u ∈ H1G, set

u H1   G  u2 ΣNj1Dju 2 dx 1/2 , u H1  G ΣN i1Diu2dx  ∂G u2 1/2 , 3.23

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Hence we consider the H1G norm with the type u H1  G ΣN i1Diu2dx  ∂G u2 1/2 , 3.24 and estimate by b a 

T2dx εT2b  εT2aεis a small positive number to be determined

 −μ1 μ2 T2a  1 μ2 Ta  λ b a fT∗Φ∗ 2 Tdx− b a kTYTdx εT2b  εT2a ≤ −μ1 μ2 T2a  1 μ2 Ta  λ b a fT∗Φ∗ 2 Tdx  ε b a T2xdx  Cε b a |k|2|Y ∗|2dx   εT2b  εT2a ≤ −μ1 μ2 T2a  1 μ2 Ta  λ⎝ ε 2 T 2 ∞1 b a fT∗Φ∗ 2 dx 2⎞ ⎠  ε T 2 H1  Cε k 2∞ Y∗ ∞2 · l  εT2b  εT2a. 3.25

ByLemma 3.3, we have that

|Tx| ≤ x

a

Ttdt |Ta|, ∀x ∈ a, b. 3.26

Substituting3.26 into the bound 3.25, we arrive at

b a  T2dx εT2b  εT2a ≤ −μ1 μ2T 2a  1 μ2Ta  λ⎝ ε 2 T 2 ∞1 b a fT∗Φ∗2dx 2⎞ ⎠  ε T 2 H1  Cε k 2 Y∗ 2∞· l  ε ⎛ ⎝2b a Tdt 2  2|Ta|2 ⎞ ⎠  εT2a ε ε ≤ −μ1 μ2 T2a  1 μ2 Ta λε 2 c 2 1 T 2H1 λ b a fT∗Φ∗2dx 2  ε T 2 H1  Cε k 2∞ Y∗ 2∞· l  2ε b a  Tt2dt· l  2εT2a  εT2a. 3.27

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By3.27, we have that  1− 2εl  b a  Tt2dt εT2b  εT2a ≤−μ1 μ2  3ε  T2a  1 μ2Ta  λε 2 c 2 1 T 2H1 λ b a fT∗Φ∗2dx 2  ε T 2 H1 Cε k 2 Y∗ 2∞· l, 3.28

where c1is the constant that appeared in the Sobolev inequalitysee 11 and note that Ω ⊂ R

u ≤ c1 u H1Ω 3.29 for all u∈ H1Ω. Hence, ε T 2H1≤ C1  ε b a  Tt2dt εT2b  εT2a  ≤ C1   1− 2εl  b a  Tt2dt εT2b  εT2a  ≤ C1 ⎡ ⎣−μ1 μ2  3ε  T2a  1 μ2Ta  λε 2 c 2 1 T 2H1 λ b a fT∗Φ∗2dx 2  ε T 2 H1 Cεl k 2 Y∗ 2∞ ⎤ ⎦, 3.30

where C1> 0, and εis chosen to satisfy ε< min{1/1  2l, μ1/3μ2}.

From3.30, we arrive at ε−λε 2 c 2 1C1− εC1 T 2 H1 ≤ C1 −μ1 μ2  3ε  T2a  1 μ2 C1Ta  λ 2εC1 b a fTΦ2dx 2  CεC1 k 2∞ Y∗ 2∞· l. 3.31 Now we choose ε > 0 such that ε− λε/2c2

1C1− εC1 > 0. Note that, in3.3, if we

choose test function ϕ 1 ∈ H1Ω, then

μ 1Ta − 1 μ2  b a kTYdx− λ b a fT∗Φ∗ 2 dx. 3.32

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Hence, we obtain that Ta is bounded by a number depending on Y∗ ∞, l, Φ∗ H1Ω, k

and f , and is independent of T. So

T 2 H1≤ C1  ε− λε/2c12C1− εC1   λ f 2 ∞Φ∗42 Cε k 2 ∞ Y∗ 2∞· l − 1 −4μ1μ2 12εμ22  , 3.33 where−1/μ2

2/4−μ123ε is the maximum of −μ123εT2a1/μ2Ta. By 3.33,

we have that T H1 ≤ C2 ⎡ ⎣  λ f∞Φ  ∗22  Cεl k Y∗ ∞  1 1μ2− 12εμ22 1/2⎦, 3.34 where C2 C1/ε− λε/2c21C1− εC11/2. Let N3 C2  λ f∞, N4 C2  Cεl k , N5  C2  1 1μ2− 12εμ22 1/2 , 3.35 so3.8 is proved.

4. Proof of

Theorem 2.1

Now, we show the proof ofTheorem 2.1.

Step 1. Under the assumptions made inSection 3, for eachTn,Φn, Yn ∈ H1Ω3, n ∈ N ∪

{0}, we first consider the linear generalized Neumann problem,μ 1Tn1a − 1 μ2 · ϕa − b a Tn1· ϕdx b a kTnYnϕdx− λ b a fTn  Φ n 2 ϕdx, −1 βΦn1b · ϕb − b a fTn  Φ n1  · ϕdxb a gTnYnϕdx 0,α1Yn1a − 1 α2 · ϕa − b a Yn1· ϕdx b a hTnYn1ϕdx, 4.1 for all ϕ∈ H1Ω.

Denote by Rv ≡ Yn1,Φn1, Tn1  RYn, RΦn, RTn the unique solution of problem

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FromTheorem 3.2, we know that Yn1 H1Ω≤ N1≡ M1, Φn1 H1Ω≤ N2 Yn ≤ N2c1 Yn H1Ω≤ N2c1M1≡ M2, Tn1 H1Ω≤ N3Φn 2 2 N4 Yn N5 ≤ N3 Φn 2H1 N4c1 Yn H1Ω N5 ≤ N3M22 N4c1M1 N5≡ M3. 4.2

Now we consider the convex set

S " v1,v2, v3 ∈  H1Ω3: v1 H1≤ M1, v2 H1Ω≤ M2, v3 H1Ω≤ M3 # . 4.3

By the estimate4.2, we know that R maps S into S.

Step 2. We show that R is continuous on S, that is,

lim j→ ∞ R T j− R T H1  R$Φj− R Φ H1  R$Yj− R Y H1   0 4.4 if Tj, $Φj, $Yj →  T, Φ, Y in S, as j → ∞.

Consider the equations

−  α1R Yja − 1 α2  ϕa − b a  R Yj  ϕdx− b a hTj  R Yj  ϕdx 0, −  α1R Ya − 1 α2  ϕa − b a  R Yϕdx− b a hTR Yϕdx 0, 4.5

for all ϕ∈ H1Ω. The difference 4.5 gives

α1 α2  R Yj− R Y  a · ϕa  b a  R Y − R Yj  ϕdx b a  hTR Y− hTj  R Yj  ϕdx 0. 4.6 By4.6, we have −α1 α2  R Yj− R Y  a · ϕa  b a  R Y− R Yj  ϕdx  b a % hTj  R Y− R Yj   R YhT− hTj & ϕdx 0. 4.7

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Set Dj R Y − R Yj, and let ϕ Djin4.7, then b a  Dj2dx δ2 b a Dj2dx≤R Y ∞h  ∞Dj T − Tj 2l 1/2. 4.8

Since 0 < δ2 ≤ h, we know that

minδ2,1Dj2H1≤ c1R Y ∞h  ∞DjH1 T − Tj H1l 1/2. 4.9

Since limj→ ∞ Tj− T H1 0, hence we have

lim j→ ∞  R Yj− R Y H1 0. 4.10 The proof of lim j→ ∞  R$Φj− R Φ H1 0, jlim→ ∞  R Tj− R T H1 0 4.11

is similar and is omitted. Hence, R is continuous on S.

Before the next step, we first state a regularity theorem, see 12. Consider the

operator Lu  Di  aijxD ju bixu   cixD iu dxu, 4.12

whose coefficients aij, bi, ci, di, j  1, . . . , n are continuous on a domain Ω ⊂ Rn.

Theorem 4.1. Let u ∈ H1Ω be a weak solution of the equation Lu  p in Ω where L is strictly

elliptic onΩ, the coefficients aij, bi i, j  1, . . . ., n are uniformly Lipschitz continuous on Ω, the

coefficients ci i  1, . . . , n, d are essentially bounded on Ω, and the function p is in L2Ω. Also, assume that ∂Ω is of class C2and that there exists a function ϕ∈ H2Ω for which u − ϕ ∈ H1

0Ω. Then one has also u∈ H2Ω and

u H2Ω≤ C  u L2ΩpL2ΩϕH2Ω  for C Cn, λ, K, ∂Ω, 4.13 where K max{ aij, bi , ci, d}.

Remark 4.2. Theorem 4.1continues to hold for sufficiently smooth ∂Ω with ϕ ∈ H2Ω if we

assume only that the principal coefficients aijare in C0Ω. Step 3. RS is precompact.

ByTheorem 4.1, one has the following:

Yn1 H2Ω≤ C Yn1 L2ΩY ϕ n1   H2Ω , 4.14

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where Ynϕ1∈ H2Ω is a function for which Y n1− Ynϕ1∈ H01Ω, Φn1 H2Ω≤ C Φn1 L2ΩgTnYnL2ΩΦ ϕ n1H2Ω , 4.15

whereΦϕn1∈ H2Ω is a function for which Φ

n1− Φϕn1∈ H01Ω, Tn1 H2Ω≤ C Tn1 L2ΩkTnYn λfTn  Φ n 2 L2Ω  Tnϕ1 H2Ω , 4.16

where Tnϕ1∈ H2Ω is a function for which T

n1− Tnϕ1∈ H01Ω. For4.14∼4.16, set Ynϕ1x  Yn1b − Yn1a b− a x − a  Yn1a, Φϕn1x  Φn1b − Φn1a b− a x − a  Φn1a, Tnϕ1x  Tn1b − Tn1a b− a x − a  Tn1a, 4.17

for all x∈ a, b.

By4.17, we obtain that  Ynϕ1x Yn1b − Yn1a b− a x − a  Yn1a   ≤ b a Y n1dx |Yn1a| ≤  l1/2 c1  M1, 4.18

for all x∈ a, b.

From4.14, 4.18 and by a simple calculation, we obtain

Yn1 H2Ω≤ C Yn1 L2ΩY ϕ n1H2Ω ≤ C⎝M1 M1  l1/2 c2 1l 4c12 l ⎞ ⎠ ≡ γ1. 4.19

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Using the same formula, we also obtain that Φn1 H2Ω≤ C Φn1 L2ΩgTnYnL2ΩΦ ϕ n1H2Ω ≤ C⎝M2gM1 M2  l1/2 c2 1l 4c2 1 l ⎞ ⎠ ≡ γ2, Tn1 H2Ω≤ C Tn1 L2ΩkTnYn λfTn  Φ n 2  L2Ω  Tnϕ1 H2Ω ≤ C⎝M3 k M1 λf  c41γ24l1/2 M3   l1/2 c12l 4c 2 1 l ⎞ ⎠ ≡ γ3. 4.20 Thus, we have RYn H2Ω≤ γ1, RΦn H2Ω≤ γ2, RTn H2Ω≤ γ3, ∀n ∈ N. 4.21

So, R maps S into a bounded set inH2Ω3, since H2Ω is compactly imbedded in H1Ω see, e.g., 9; hence, RS is precompact in H1Ω3.

Hence by Schauder’s fixed point theorem, R has a fixed point and there exists a T, Φ, Y ∈ H1Ω3satisfyng2.17. Thus, we complete the proof ofTheorem 2.1.

References

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2 T. Zhou and H. Liu, “3-D model of proton exchange membrane fuel cells,” in Proceeding of the ASME Heat Transfer Division, pp. 43–49, Orlando, Fla, USA, 2000.

3 V. Gurau and J. A. Adin Mann Jr., “A critical overview of computational fluid dynamics multiphase models for proton exchange membrane fuel cells,” SIAM Journal on Applied Mathematics, vol. 70, no. 2, pp. 410–454, 2009.

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