本論文的研究主要在於改善感光高分子材料的全像記錄特性(繞射效率、動態儲存 範圍)的提升，藉由光學特性分析與化學分析，瞭解了所製備材料的優缺點與改善的方 向。
因此在本章節對於前面章節的研究所得的結果進行總結。
1.以PQ/Poly（HEMA-co-MMA） 系統的感光高分子，在混摻鑭系有機金屬化合物
加入後，全像記錄的特性繞射效率與動態範圍M#次序為：Lu(ac)3 ＞ Yb(ac)3 ＞ Er(ac)3
＞ PQ ＞ Nd(ac)3 ＞ Ce(ac)3。體積全像特性增加的趨勢與原子序（atomic number）增 加次序是一致（Lu＞Yb＞Er＞Nd＞Ce）與金屬離子半徑的次序相反（Lu3+ ＜Yb3+＜Er3+＜ Nd3+ ＜Ce3+）。混摻Lu(ac)3感光高分子的繞射效率與動態範圍M#提升 3.4 倍與 2 倍。在 FTIR與XPS 等光譜的分析下，發現了Lu（ac）3分子在曝光的過程中會與PQ 分子產生光
化學反應，而使Lu（ac）3
2. 以 PQ/PMMA 系統的感光高分子，在混摻非線性光學有機材料 DMNA 後，用紅
光雷射 647nm 對 2mm 厚的 DMNA：PQ/PMMA 感光高分子進行全像記錄其繞射效率最 大值～43％，其布拉格角度選擇率也非常接近理論預測的 sinc 平方函數；全像光學圖 /PQ/Poly（HEMA-co-MMA）感光高分子的全像記錄特性提升，
也使用UV-VIS和CV圖譜解釋了M#增加的原因。
76
案具有非常好的重建影像品質。這些實驗結果都說明了 DMNA：PQ/PMMA 感光高分子 在沒有紅光吸收的波段，其材料敏感度延伸到不吸收的紅光波段，此材料也可利於應用 在較長波段的體積全像應用上。
對於未來的研究方向，非線性光學有機分子是一個相當有趣的主題，應用於全像 材料上說不一定會有意外的收穫。第一：現有的材料 DMNA：PQ/PMMA 感光高分子可 以嘗試用 1064nm pulse laser 進行全像記錄；另外也可以混摻其他非線性光學有機分 子，如 N,N-diethyl-4-nitroaniline(DEMA)、N-cyanomethyl-N-methyl-4-nitroaniline(CMNNA) 與 p-nitroaniline(NA)於 PQ/PMMA 感光高分子，使用紅光雷射 647nm 記錄並探討之。
77
第一章 參考文獻
1. R. A. Lessard and G. Manivannan: Proc. SPIE 2405, 2,(1995).
2. F. H. Mok, Opt.Letts. 18, 915,(1993).
3. P. Gunter, J. P. Huignard Ed.,Springer Verlag 61, Berlin (1988).
4. B. L. Booth,Appl. Opt. 11, 2994,(1972).
5. C. P. Yang, S. H. Lin, M. L. Hsieh, K. Y. Hsu and T. C. Hsieh, Int’l J. of High Speed Electronics
& Systems 8, 749,(1997).
6. P. J. van Heerden,Appl. Opt. 2,393,(1963).
7. H. Kogelnik,Bell Syst. Tech. J. 48,2909,(1969).
8. P. Hariharan, Optical Holography: Principles, techniques, and applications, Cambridge,New York, 45,(1996).
9. G. W. Burr, “Doctoral Dissertation: Volume Holographic Storage Using the 90 °Geometry,”
California Institute of Technology, Pasadena, Calif.(1996).
10.K.Y. Hsu and S.H.Lin,Proc.SPIE 5206,142,(2003).
第二章 參考文獻
11. Cheben P, Calvo ML, Del Monte F,Opt. Spect. 103, 855,（2007）.
78
12. Passaro VMN, Magno F,Laser Phys. 17, 231,（2007）.
13.Smimova TN, Sakhno OV, Strelets IA,Tech. Phys. 43, 708（1998）.
14.Ono H, Mohamad NRB, Sasaki T,Liqu. Cryst. 35, 633,（2008）.
15.Bobrovsky A, Shibaev V, Wendorff J,Liqu. Cryst. 34, 1,（2007）.
16.Manivannan G, Lemelin G, Changkakoti R, Appl. Opt. 33, 34（1994）.
17.Trepanier F, Manivannan G, Changkakoti R,Can. j. phys. 71, 423,(1993).
18.Abbate G, Vita F, Marino A, Mol. cryst. liq. cryst. 453, 1,(2006).
19. Park MS, Kim BK, Nanotech. 17, 2012,(2006)
20. Mallavia R, Fimia A, Blaya S, J. mod. opt. 46, 599,(1999).
21. Cokbaglan L, Arsu N, Yagci Y,Macro.36, 2649,(2003).
22. Aydogan B, Gundogan AS, Ozturk T, Macro. 41, 3468,(2008).
23. Li SJ, Wu FP, Wang EJ, Photochem. Photobio A, 197, 74,(2008) 24. Li CD, Luo L, Wang SF,Chem. Phys. Lett. 340, 444,(2001).
25. Timothy JT, Joel E. B, Vicki L C, Chem. Mater. 12, 1431,(2000).
26. Jeong YC, Lee S, Park JK 2007, Opt. Expre.15,1497,(2007).
27. Liu GD, He QS, Luo SJ,Chin. Phys. Lett. 20,1733,(2003).
28. Chung DW, Kim JP, Kim D,J. Ind. Eng. Chem. 12, 783,(2006).
29. Choi DH, Cho MJ, Yoon H,Opt. Mater. 27, (2004).
79
30. Suratwala T, Hanna ML, Whitman P,J. non-cryst solid 349, 368,(2004).
31. Carretero L, Murciano A, Blaya S, Opt. Expre. 12, 1780,(2004) 32. Hsiao YN, Whang WT, Lin SH, Opt. Eng. 43, 1993,(2004).
33. Hsiao YN, Whang WT, Lin SH,Japan. J Appl. Phy. 44, 914,(2005).
34. Hsu KY, Lin SH, Hsiao YN,Opt. Eng. 42, 1390,(2003).
35. Hsiao YN, Whang WT, Lin SH, Hsu KY,Japan. J. Appl. Phy. 45, 8699,(2006).
36. Kim E, Woo J, Kim B,Liqu. Cryst. 34, 79,(2007).
37. Suleiman YS, Ghosh S, Abbasov ME, J. Mater. Sci., Mater. Electron. 19, 662,(2008).
38. Li X, Chon JWM, Gu M, Aust. j. chem. 61, 317,(2008).
39. Suzuki N, Tomita Y,Opt. Expre. 14, 12712,(2006).
40. Tomita Y, Furushima K, Ochi K, Appl. Phys. Lett. 88, 071103-1,(2006).
41. Suzuki N, Tomita Y,Appl. Opt. 43, 2125,(2004).
42. Naoki HAYASHIDA_, Atsuko KOSUDA, and Jiro YOSHINARI,Japan.J. Appl. Phy.
47, 5895,(2008)
43. Davidenko NA, Spitsyna NG, Lobach AS, High Ener. Chem. 42, 45,(2008).
44. Mosinger J, Janoskova M, Lang K,J. Photochem. Photobio A 181, 283,(2006).
45. Anbalagan V, J. Coord. Chem. 56, 161,(2003).
46. Hayes JA, Schubert DM, Amonette, J. Photochem. Photobio A 197,245,(2008).
80
47. Park, HY; Lee, DW; Lee, HS,React. Kinet Cat. Lett. 79, 245,(2003).
48. Suzuki N, Tomita Y, Appl. Opt. 46, 6809,(2007).
49. Suzuki N, Tomita Y, Ohmori K,Opt. Expre. 14, 12712,(2006).
50. Kim WS, Jeong YC, Park JK,Opt. Expre. 14, 8967,(2006).
51. Annapoorna A, Sergei L. Sochava, Lambertus H,Opt. Lett. 22, 919,(1997).
52. Judeinstein P, Oliveira PW, Krug H, Schmidt H, Adv. Mater. Opt. Elect. 7, 123,(1997).
53. Hyo-jin Lee, Bhimrao D, Sarwade, Jiyoung P, Eunkyoung, Opt.Mater. 30,637.(2007).
54. Kim MR, Choi YI, Park SW, Lee JW, Lee JK.J. Appl. Poly. Sci. 100, 4811,(2006).
55. Pu A, Curtis K, Psaltis D,Opt. Eng. 35, 2824,(1996).
56. Linke RA, Redmond I, Thio T, Chadi DJ, J. Appl. Phys. 83, 661,(1997).
57. Kim YH, Sohn SD, Lee YH,Appl. Opt. 43, 2118,(2004).
58. Y. N. Hsiao, W. T. Whang and S. H. Lin, Opt. Eng. 43, 1993, (2004),
59. J. Mumbru, I. Solomatine, D. Psaltis, S. H. Lin, K. Y. Hsu, W. Z. Chen and W. T.Whang, Opt.
Commun. 194, 103, (2001).
60. S. Farid, D. Hess, G. Pfundt, K. H. Scholz and G. Steffan, Chem. Commun. 434, 638, (1968).
61. B. D. Padalia, W. C. Lang, P. R. Norris, L. M. Watson, D. J. Farbian, Proc. Roy. Soc. London Ser. A, Math. Phys, 354, 269, (1977).
62. A. Zenkevich, Y. Lebedinshii, G. Scarel, M. A. Fanciulli, NATO Sci. Seri.II Math., Phys. Chem.,
81
220, 147, (2006).
63. R. A. Bartolini, A. Bloom, and H. A. Weakliem, Appl. Opt. 15, 1261,(1976).
64. Y. L. Freilich, M. Levy and S. Reich, J. Polym. Sci. Chem. Ed. 15,1811,(1977).
65. A. Pu and D. Psaltis, Appl. Opt. 35, 2389, (1996).
66. V. L. Colvin, R. G. Larson, A. Haris and M. L. Shilling, J. Appl. Phys. 81,5914,(1997).
67. H. Ono, T. Tamoto, A. Emoto and N. Kawatsuki, Jap. J. Appl. Phys. 44,1783,(2005).
68. U. V. Mahilny, D. N. Marmysh, A. I. Stankevich, A. L. Tolstik, V. Matusevich and R.Kowarschik, Appl. Phys. B 82, 299, (2006).
69. D. H. Close, A. D. Jacobson, J. D. Margerum, R. G. Brault and F. J. McClung, Appl.Phys. Lett.
14,159, (1969).
70. H. Franke, Appl. Opt. 23, 2729,(1984).
71. C. Carre and D. J. Lougnot, J. Phys. (Paris) III 3, 1445, (1993).
72. R. A. Lessard and G. Manivannan, Proc. SPIE 2405,2,(1995).
73. D. A. Waldman, H. Y. S. Li and M. G. Horner, J. Imag. Sci. Tech. 41, 497, (1997).
74. D. A. Waldman, H. Y. S. Li and E. A. Cetin, Proc. SPIE 3291, 89, (1998).
75. J. Steckman, I. Solomatine, G. Zhou and D. Psaltis, Opt. Lett. 23, 1310,(1998).
76. L. Dhar, A. Hale, H. E. Katz, M. L. Schilling, M. G. Schnoes and F. C. Schilling, Opt.Lett. 24, 487, (1999).
82
77. M. L. Schilling, V. L. Colvin, L. Dhar, A. L. Harris, F. C. Schilling, H. E. Katz, T.Wysocki, A.
Hale, L. L. Blyler, and C. Boyd, Chem. Mater. 11, 247, (1999).
78. P. Cheben and M. L. Calvo, Appl. Phys. Lett. 78, 1490, (2001).
79.S. H. Lin, J. H. Lin, P. L. Chen, Y. N. Shiao and K. Y. Hsu, J. Non. Opt. Phys. Mater.
15, 239, (2006).
80. Y. N. Hsiao, W. T. Whang, S. T. Lin, Opt. Eng., 43, 1993 (2004).
81.Y. N. Hsiao, W. T. Whang, S.T. Lin, Jap. J. Appl. Phys., 44, 914 (2005).
82. F. D. Monte, O. Martínez, J . A. Rodrigo, M. L. Calvo, P. Cheben, Adv. Mater., 18, 2014 (2006).
83. E. Kim, J. Park, C. Shin, N. Kim, Nanotech., 17, 2899 (2006).
第三章 參考文獻
84.T. A. Shankoff, Appl. Opt. 7, 2101,(1968).
85.R. A. Lessard y G. Manivannan,Proc.SPIE 2405, 2, (1995).
86.N. Sadlej and B. Smolinska,Opt. Laser Technol. 7, 175,(1975).
87. S. Calixto, Appl. Opt. 26,3904, (1987).
88. S. Yoshida and M. Yamamoto,Jpn. J. Appl. Phys.48,03A027,(2009).
89. M. R. Gleeson and J. T. Sheridan, J. Opt. A: Pure Appl. Opt. 11,24008,(2009).
90. B. L. Booth,Appl. Opt. 14, 593,(1975).
83
91. K. Curtis and D. Psaltis,Appl. Opt. 33,5396,(1994).
92. R. T. Ingwall and M. Troll,Opt. Eng. 28, 586,(1989).
93. D. A. Waldman, H. Y. S. Li and E. A. Cetin, Proc. SPIE 3291, 89, (1998).
94. A. Fimia, N. Lopez and F. Mateos, Proc. SPIE 1732,105,(1992).
95. M. Eich, J. H. Wendorff, B. Reck and H. Ringsdorf, Macromol. Rapid Commun. 8,59, (1987).
96. P. Rochon, E. Batalla and A. Natasohn, Appl. Phys. Lett. 66,136, (1995).
97. D. Y. Kim, S. K. Tripathy, L. Li and J. Kumar, Appl. Phys. Lett. 66, 1166,(1995).
98. Y. H. Cho, C. W. Shin, N. Kim, B. K. Kim and Y. Kawakami, Chem. Mater. 17, 6263, (2005).
99. V. K. S Hsiao, C. G. Lu, G. S. He, M. Pan, A. N. Cartwright, P. N. Prasad, R.Jakubiak, R. A.
Vaia and T. J. Bunning, Opt. Exp. 13, 3787, (2005).
100. C. Solano, R. A. Lessard and P. C. Roberge, Appl. Opt. 24, 1189, (1985).
101. C. Solano, R. A. Lessard and P. C. Roberge, Appl. Opt. 26, 1989,(1987).
102. N. Capolla and R. A. Lessard, Appl. Opt. 27, 3008,(1988).
103. N. Capolla, R. A. Lessard, C. Carre and D. J. Lougnot, Appl. Phys.B 52, 326,(1991).
104. J. Blyth, Appl. Opt. 30, 1598,(1991).
105. C. Pizzocaro, C. Lafond and M. Bolte, J. Photoch. Photobio. A 151, 221, (2002).
106. G. Manivannan, G. Mailhot, M. Bolte and R. A. Lessard, Pure Appl. Opt. 3, 845,(1994).
84
107. G. Manivannan, R. Changkakoti and R. A. Lessard, Opt. Eng. 32, 671 (1993).
108. G. Manivannan, R. Changkakoti and R. A. Lessard, Polym. Adv. Tech. 4, 569,(1993).
109. Sh. D. Kakichashvili, Opt. Spektrosk. 33, 324,(1972).
110. T. Todorov, L. Nikolova, N. Tomova and V. Dragostinova, IEEE J. Quantum Electron.
QE-22,1262,(1986).
111. H. Taunaumang, M. Solyga, M. O. Tija and A. Miniewicz, Thin Solid Films 461,108,316,(2004).
112. Y. J. Zhang, Z. F. Lu, X. F. Deng, Y. C. Liu and Y. Y. Zhao, Opt. Commun. 220,289,(2003).
30. Y. Zhao, S. Y. Bai, K. Asatryan and T. Galstian, Adv. Funct. Mater. 13,781,(2003).
113. M. J. Kim, C. Chun, T. Nakayama and D. Y. Kim, Jpn. J. Appl. Phys. 45,L169-171, (2006).
114. S. C. Fu, Y. C. Liu, L. Dong, Z. F. Lu, W. L. Hu and M. G. Xie, Mater. Lett. 59,1449,(2005).
115. V. Weiss, A. A. Friesem and V. A. Krongauz, J. Img. Sci. Tech. 41,371,(1997).
116. C. S. Paik and H. Morawetz, Marcomolecules 5,171,(1972).
117. Z. Chen, A. Lewis, H. Takei and I. Nebenzahl, Appl. Opt. 30, 5188, (1991).
118. G. S. He, C. J. Wung, G. C. Xu and Paras N. Prasad, Appl. Opt. 30, 3810, (1991).
119. V. I. Sukhanov, A. M. Kursakova, S. A. Kuchinsky, E. R. Gavrilyuk and T. W. Zerda,J.
Sol-Gel Sci. Tech. 8, 1111,(1997).
120. P. Judeinstein, P. W. Oliveira, H. Krug and H. Schmidt, Adv. Mater. Opt. Electro.
85
7,123,(1997).
121. I. G. Marine, D. Bersani and P. P. Lottici, Opt. Mater. 15, 279,(2001).
122. S. Kucharski and R. Janik, Opt. Mater. 27,1637,(2005).
123. L. Carretero, A. Murciano, S. Blaya, M. Ulibarrena, and A. Fimia, Opt. Express 12,1780,(2004).
124. B. Plagemann, F. R. Graf, S. B. Altner, A. Renn and U. P. Wild, Appl. Phys. B 66,109, 67,(1998).
125. A. V. Turukhin, A. A. Gorokhovsky, C. Moser, I. V. Solomatin and D. Psaltis, J.
Lumi.86,399, (2000).
126. A. V. Turukhin, R. S. Pandher, A. A. Gorokhovsky, Z. Liu, I. V. Solomatin and D.Psaltis, J.
Lumin. 98, (2002),(2002).
127. A. Bloom, R. A. Bartolini and P. L. K. Hung, Polym. Eng. Sci. 17,356,(1977).
128. A. Bloom, R. A. Bartolini and D. L. Ross, Appl. Phy. Lett. 24,612,(1974).
參考文獻 第四章
129.Messier, J, Karjzar,F. Prasad, P., Ulrich, D. Eds. ASI Ser., Ser. E. 162 (1989).
130. Singer, K.D., Lalama, S.J., Sohn,J. E. Soc. Opt. Eng. Proc. SPIE 578, 130 (1985).
131.Meredith,G.G.,VanDusen,J.G., Williams, D.J. Macro., 15,1385,(1982).
132. Hampsch H.L., Yang,J., Wong, G. K.,Torkelson, J,M, Macro., 21,526,(1988).
86
133.Hill. J. R., Panties,P.,Abbasi,F.,Hodge,P.J. Appl. Phys., 64,2749, (1988).
134.Singer, K.D., Kuzyk,M.G.,Holland,W. R.,Sohn, J.E., Lalama,S. J.,Comizzol, R.B.,Kata, H.E.,Schiling. M.L. Appl. Phys. Lett.53,128, (1988).
135. Eich, M.,Reck, B.,Yoon,D.Y.,Willson, C.G.,Bjorlund, G. C. Appl. Phys. 66, 3241, (1989).
136.羅景峰,國立交通大學應用化學所,碩士論文,民國 82 年.
137.陳建宏,國立交通大學材料科學與工程研究所,碩士論文,民國 82 年.
138. C.J. Ko, Po-Lin Chen, Yi-Nan Hsiao, Shiuan-Huei Lin, Wha-Tzong Whang, Ken Y. Hsu, Yu-Sheng Hsiao, Chun-Chao Chen, J. Appl. Poly. Sci., (2012).
139. http://www.sigmaaldrich.com/taiwan.html
140.A. S. Dvornikov, I. Cokgor, M. Wang, F. B. Jr. McCormick, S. C. Esener, P. M. Rentzepis, IEEE Transactions on components, packaging and manufacturing technology-Part A, 20,203, (1997).
141. R. R. Naik, L. L. Brott, F. Rodriguez, G. Agarwal, S. M. Kirkpatrick and M. O. Stone, Prog.
Organ. Coat. 47, 249, (2003).
142. G. Barbastathis and D. J. Brady, Proceedings of the IEEE 87, 2098, (1999).
143. G. C. Bjorklund, Chr. Bräuchle, D. M. Burland, D. C. Alvarez, Opt. Lett. 6, 159, (1980).
144. C. Bräuchle, U. P. Wild, D. M. Burland, G. C. Bjorklund, and D. C.Alvarez, Opt. Lett. 7, 177 (1982).
87
145. V. Gerbig, R. K. Grygier, D. M. Burland, and G. Sincerbox, Opt. Lett. 8, 404, (1983).
146. G. C. Bjorklund, D. M. Burland, D. C. Alvarez, J. Chen. Phys. 73, 4321, (1980).
147. K. Hirabayashi, H. Kanbara, Y. Mori, T. Kurihara, M. Shimizu and T. Hiyama, Appl. Opt.
46, 8402, (2007).
148. P. L. Chen, S. L. Cho, J. H. Lin, S. H. Lin, K. Y. Hsu and S. Chi, Opt. Eng. Lett. 51 (2012).
149. G. Björk, J. Söderholm, L. L. Sanchez-Soto: J. Opt. B-Quant. Semi. Opts. 6, S478 (2004).
150. W. Heisenberg, The Physical Principles of Quantum Theory, Translated by Carl Eckart and F. C. Hoyt, Chicago, 1930.
151. D. E. Damschen, C. D. Merritt, D. L. Perry, G. W. Scott and L. D. Talley, J. Phys. Chem. 82, 2268, (1978).
152. S. H. Lin, K. Y. Hsu, W. Z. Chen and W. T. Whang, Opt. Lett. 25, 451, (2000).
153. K. Y. Hsu, S. H. Lin, Y. N. Hsiao, and W. T. Whang, Opt. Eng. 42, 1390, (2003).
154. S. H. Lin, Y.-N. Hsiao, P.-L. Chen and K. Y. Hsu, J. Non. Opt. Phys. Mats. 15, 239,(2006).
155. J. C. Dalton and N. J. Turro, Annu. Rev. Phys. Chemistry 21, 499, (1970).
156. J. Chilton, L. Giering, and C. Steel, J. Am. Chem. Soc. 98, 1865, (1976).
157. H. Kogelnik, “Coupled wave theory for thick hologram grating,” Bell System Tech. J. 48, 2909, (1969).
158. S. Cox, T. Gier, and G. Stucky, Chem. Mater. 2, 609, (1990).
88
159. K. T. Holman, A. M. Pivovar, M. D. Ward, Science 294 1907, (2001)
160. I. Roth, F. Simon, C. Bellmann, A. Seifert and S. Spange, Chem. Mater. 18, 4730, (2006).
161. R. A. Ando, G. M. Nascimento, R. Landers and P. S. Santos, Spectrochim. Acta. A 69, 319, (2008).
162. C. D. Wagner, W. M. Riggs, L. E. Davis, J. F. Moulder, G. E. Mullenberg, Handbook of X-ray Photoelectron Spectroscopy, Perkin–Elmer Corporation, Eden Prairie, (1992).
163. B. C. Roy, M. D. Gupta and J. K. Ray, Macro. 28, 1727, (1995).