第五章 結果與討論
6.2 建議
1. 在丙烯腈這方面的研究中，對於其衍生物之文獻是相當稀少的，因此 可嘗試多種物種，爲丙烯腈這一類之化學物質建立一個較完整毒性評 估的水體資料庫。
2. 針對丙烯腈化合物與醛類相混合後的變化，需要更詳細的機制來確定 是否產生新的化學物質，或嘗試不同的分析方法希望藉以得之切確的 結果來供探討。
參考文獻
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附 錄
Microtox試驗原始數據 2156 100.73 30.41 0.302 0.286 1078 103.19 49.08 0.476 0.450 539 101.66 71.48 0.703 0.666 4189.5 103.04 3.33 0.032 0.034 2094.75 91.59 19.56 0.214 0.223 1047.40 102.82 48.38 1 0.490
523.70 96.53 67.05 0.695 0.724 261.85 95 76 0.800 0.834 130.93 95 84 0.884 0.922
Toxicant：2-Chloroacrylonitrile
11.25 86.99 12.49 0.144 0.159 5.62 103.98 25.12 0.242 0.267 2.81 90.89 38.42 0.423 0.467 11.01 71.17 13.34 0.187 0.243 5.50 80.66 22.30 0.276 0.358 10.98 86.68 18.98 0.219 0.229 5.49 101.67 35.61 0.350 0.367 2.74 98.74 50.46 0.511 0.535 1.37 106 80 0.755 0.790 0.69 89 78 0.876 0.9174
Conc Initial light Final ligh Light ratio Q
mg/L
Control 91.01 86.59 0.951 1 22.16 84.92 10.20 0.120 0.126 11.08 86.47 22.95 0.265 0.279 5.54 85.11 35.97 0.423 0.444
21.69 96.93 11.65 0.120 0.141 10.84 94.62 20.38 0.215 0.254 5.42 91.57 30.84 0.337 0.396 11.09 95.5 23.08 0.242 0.260 5.55 100.33 41.31 0.412 0.443 2.77 99.17 50.67 0.511 0.550
1.39 99 57 0.576 0.620
0.69 97 65 0.670 0.721
Toxicant：Methacrylonitrile
580.5 91.79 50.38 0.549 0.631 290.25 87 58 0.667 0.767 3952.8 95.50 13.69 0.143 0.187 1976.4 108.38 33.19 0.306 0.399 988.2 107.93 47.21 0.437 0.5704
2196 102.80 29.50 0.287 0.371
1098 98.37 40.31 0.410 0.529
2358 103.53 19.17 0.185 0.226 1179 90.21 39.32 0.436 0.531 589.5 97.48 54.80 0.562 0.685 294.75 93 61 0.656 0.800 147.38 101 75 0.743 0.905Toxicant：Methoxyacrylonitrile
868.5 81.08 47.31 0.583 0.691 434.25 77.92 50.00 0.642 0.760 217.13 84 59 0.702 0.832 4302 104.36 18.76 0.180 0.201 2125 98.82 39.77 0.402 0.450 1075.5 99.68 55.25 0.554 0.620 537.75 94.43 58.55 0.620 0.693 268.88 90 63 0.700 0.782 3478.6 88.46 15.92 0.180 0.216 1739.3 81.27 30.87 0.380 0.456 869.65 79.94 47.07 0.589 0.706 434.82 86.04 56.18 0.653 0.783 217.41 84 59 0.702 0.843 108.71 89 70 0.787 0.9444
Conc Initial light Final ligh Light ratio Q
mg/L
Control 87.27 76.05 0.871 1 3506.4 88.46 17.7 0.200 0.230 1753.2 82.45 35.42 0.430 0.493
876.6 83.08 50.60 0.609 0.699 438.3 85.29 57.90 0.679 0.779 219.15 96 70 0.729 0.837 109.75 102 77 0.755 0.866
Toxicant：3-Ethoxyacrylonitrile
1
Conc Initial light Final ligh Light ratio Q
mg/L
Control 101.50 93.94 0.926 1 1306.8 94.73 18.42 0.194 0.210
653.4 94.35 33.02 0.350 0.378 326.7 108.91 44.95 0.413 0.446 163.35 94.58 60.20 0.636 0.688
81.68 95 77 0.810 0.876 1298.7 91.45 21.61 0.236 0.281 649.35 88.74 29.69 0.335 0.398 324.68 90.47 38.22 0.422 0.5021 162.34 84.93 54.91 0.647 0.768
81.17 88 64 0.727 0.864 40.59 90 68 0.756 0.898
4
Conc Initial light Final ligh Light ratio Q
mg/L
Control 91.34 76.48 0.837 1 2193.75 84.08 12.42 0.148 0.176 1096.88 78.33 22.99 0.294 0.351 548.44 85.61 31.64 0.370 0.441 274.22 91.68 42.37 0.462 0.552 137.11 96 59 0.6145 0.734
68.56 93 61 0.656 0.783
Toxicant：3-Dimethylaminoacrylonitrile
1
Conc Initial light Final ligh Light ratio Q
mg/L
Control 105.64 81.42 0.771 1 456.3 99.53 32.53 0.327 0.424 228.15 93.25 40.92 0.439 0.569 114.08 88.55 47.61 0.538 0.698 57.04 99.15 61.42 0.619 0.804 28.52 91 59 0.648 0.841 1387.8 81.53 14.37 0.176 0.208
693.9 81.14 25.95 0.320 0.377 346.95 87.21 37.13 0.426 0.502 173.48 97 49 0.505 0.560 274.5 82.47 42.96 0.521 0.545 137.25 87 68 0.782 0.817
68.63 83 76 0.916 0.957
4
Conc Initial light Final ligh Light ratio Q
mg/L
Control 89.65 79.07 0.882 1 1778.4 88.45 16.19 0.183 0.208 889.2 84.88 27.56 0.325 0.368 444.6 85.59 32.45 0.379 0.430 222.3 86.19 41.92 0.486 0.551 111.15 98 60 0.612 0.694
55.58 100 74 0.740 0.839
Toxicant：Formaldehyde
21.825 76.26 11.56 0.152 0.174 10.9125 75.04 22.75 0.303 0.349 5.45625 78.02 37.10 0.476 0.547 2.728125 74.60 43.82 0.587 0.676 1.3640625 87 57 0.655 0.754 26.07 83.31 11.51 0.138 0.178 13.035 92.10 21.35 0.232 0.298 6.5175 84.75 31.05 0.366 0.472 3.25875 84 42 0.500 0.644 1.629375 91 58 0.637 0.82034
Conc Initial light Final ligh Light ratio Q
mg/L
Control 87.66 64.82 0.739 1 52.38 91.78 8.21 0.089 0.121 26.19 78.42 13.12 0.167 0.226 13.095 75.55 19.64 0.260 0.352 6.5475 82.29 28.98 0.352 0.476 3.27375 101.83 45.37 0.446 0.603 1.638875 97.09 52.85 0.544 0.736
5
Conc Initial light Final ligh Light ratio Q
mg/L
Control 94.72 74.67 0.788 1 38.71 102.56 7.91 0.077 0.097834946 19.35 94.97 13.73 0.144 0.183391684
9.68 89.84 22.73 0.253 0.320941021 4.84 86.74 35.47 0.409 0.518725154 2.42 96 52 0.542 0.687112182 1.21 89 60 0.674 0.855178516
Toxicant：Propionaldehyde
444.38 87.28 20.71 0.237 0.241 222.19 89.03 41.56 0.467 0.474 111.1 96.98 62.39 0.643 0.653 55.5 110 87 0.791 0.803 729.8 94.73 21.76 0.230 0.265 364.49 98.20 31.73 0.323 0.372 182.45 85.21 51.61 0.606 0.698 91.23 97.35 69.13 0.710 0.818 45.62 120 90 0.750 0.864507.6 87.34 20.94 0.240 0.304 253.8 81.15 37.50 0.462 0.586 126.9 93.92 55.32 0.589 0.748 63.45 105 75 0.714 0.907 31.73 100 77 0.770 0.977
4
Conc Initial light Final ligh Light ratio Q
mg/L
Control 100.94 88.32 0.875 1 931.5 93.69 12.2 0.130 0.149 465.75 83.13 23.65 0.284 0.325 232.88 91.92 38.63 0.420 0.480 116.44 116.17 74.27 0.639 0.731 58.22 110 81 0.736 0.842 921.6 91.68 10.43 0.114 0.131 460.8 92.14 23.37 0.254 0.291 230.4 86.94 39.52 0.455 0.521 115.2 88.87 52.32 0.589 0.675 57.6 92 65 0.707 0.810 868.4 95.00 15.60 0.164 0.171 434.2 99.31 28.26 0.285 0.296 217.1 98.67 48.93 0.496 0.516 108.55 89.26 63.26 0.709 0.738 54.28 87 70 0.805 0.838 27.14 83 72 0.867 0.903
Toxicant：Butyraldehyde
347.76 101.26 18.90 0.187 0.195 173.88 98.89 37.12 0.375 0.391 86.94 105.32 56.45 0.536 0.559 998 91.30 3.18 0.035 0.039 499 85.53 6.89 0.081 0.091 249.5 88.00 22.78 0.259 0.293 124.75 94.49 45.78 0.484 0.549962.38 100 60 0.600 0.680 104.8 94.56 37.93 0.401 0.590 52.4 91 48 0.527 0.776 26.2 90 54 0.600 0.883
4
Conc Initial light Final ligh Light ratio Q
mg/L
Control 91.54 66.13 0.722 1 1012.5 96.82 3.39 0.035 0.048 506.25 91.70 5.48 0.060 0.083 253.12 97.00 18.72 0.193 0.267 126.56 96.75 36.76 0.380 0.526 63.28 87 46 0.529 0.732 31.64 97 60 0.619 0.856
5
Conc Initial light Final ligh Light ratio Q
mg/L
Control 93.72 76.13 0.812 1 864.56 91.08 1.27 0.014 0.017 432.28 99.65 3.81 0.038 0.047 216.14 84.41 16.53 0.196 0.241 108.07 100.99 38.96 0.386 0.475 54.04 98 52 0.531 0.653 27.02 100 74 0.740 0.911
Toxicant：Glutaraldehyde
1
Conc Initial light Final ligh Light ratio Q
mg/L
Control 110.96 103.24 0.930 1 43.4 94.40 4.21 0.045 0.048 21.7 95.37 11.6 0.122 0.131 10.85 96.35 24.48 0.254 0.273
5.42 95.36 36.97 0.388 0.417 11.66 88.44 19.86 0.225 0.219 5.83 90.28 35.37 0.392 0.383 2.71 101.42 42.45 0.419 0.474 1.36 103 62 0.602 0.682 0.68 119 76 0.639 0.724
4
7.155 95.08 20.01 0.210 0.2793.58 84.23 27.78 0.330 0.437 11.53 95.22 15.50 0.163 0.191 5.76 95.43 28.55 0.299 0.351 2.88 101.44 47.94 0.473 0.555 1.44 104 60 0.577 0.677 12.92 96.53 14.62 0.151 0.183 6.46 93.21 23.01 0.247 0.299 3.23 89.50 40.78 0.456 0.552 1.62 94 53 0.564 0.683 0.81 93 62 0.667 0.807
7
Conc Initial light Final ligh Light ratio Q
mg/L
Control 89.36 72.38 0.810 1 21.78 86.52 6.96 0.080 0.099 10.89 93.69 16.50 0.176 0.217 5.45 101.45 32.28 0.318 0.393 2.72 88.20 45.60 0.517 0.638
1.36 97 57 0.588 0.725
0.68 96 63 0.656 0.810
Toxicant：3-Hydroxybenzaldehyde
70.84 76.74 8.4 0.109 0.150 35.42 78.15 19.82 0.254 0.349 17.71 82.08 25.93 0.316 0.435 8.86 80.08 35.18 0.439 0.605 95.4 92.45 9.51 0.103 0.147 47.7 90.30 16.33 0.181 0.258 23.85 88.95 22.91 0.258 0.368 11.92 93.71 31.10 0.332 0.474 5.96 104.31 45.37 0.435 0.621 2.98 98.06 49.76 0.507 0.7254
Conc Initial light Final ligh Light ratio Q
mg/L
Control 92.46 87.21 0.943 1 88.56 91.41 12.06 0.132 0.140 44.28 91.98 20.05 0.218 0.231 22.14 73.07 22.66 0.310 0.329 11.07 95.04 47.07 0.495 0.525 5.54 75 47 0.627 0.664 2.77 96 78 0.813 0.861
5
Conc Initial light Final ligh Light ratio Q
mg/L
Control 87.61 84.76 0.967 1 65.14 91.76 17.16 0.187 0.193 32.57 92.09 28.98 0.315 0.325 16.28 99.59 41.80 0.420 0.434 8.14 95.10 50.79 0.534 0.552 4.07 98 67 0.684 0.707
2.04 87 72 0.828 0.855
Toxicant：Acrylonitrile+Fromaldehyde
Toxicant：Methacrylonitrile+ Formaldehyde
Conc Initial light Final ligh Light ratio Q
Toxicant：Methoxyacrylonitrile+Formaldehyde
0.25 102.25 59.76 0.584 0.724 0.125 96 64 0.667 0.825 0.0625 90 65 0.722 0.894Toxicant： 3-Ethoxyacrylonitrile+Formaldehyde
Conc Initial light Final ligh Light ratio Q 0.125 95.16 68.65 0.721 0.798 0.0625 94.72 72.66 0.767 0.848
Toxicant：3-dimethylaminoacrylonitrile+Formaldehyde
0.125 85.17 57.11 0.671 0.694 0.0625 106.51 74.07 0.695 0.720Toxicant：Acrylonitrile+ Propionaldehyde
Toxicant：Methacrylonitrile+Propionaldehyde (1:3)
Toxicant：3-Ethoxyacrylonitrile+Propionaldehyde
Toxicant：3-Dimethylaminoacrylonitrle+ Propionaldehyde
Conc Initial light Final ligh Light ratio Q 0..5 100.56 46.11 0.459 0.559 0.25 105 54 0.514 0.627 0.125 98 60 0.612 0.746
Toxicant：3-Dimethylaminoacrylonitrle+ Propionaldehyde (1:3)
Conc Initial light Final ligh Light ratio Q
Toxicant：3-Dimethylaminoacrylonitrle+ Propionaldehyde (3:1)
Toxicant：Acrylonitrile+ Butyraldehyde
Conc Initial light Final ligh Light ratio Q 0.25 106.54 61.99 0.582 0.625 0.125 92 61 0.663 0.712 0.0625 92 66 0.717 0.770
Toxicant：2-Chloroacrylonitrile+ Butyraldehyde
Conc Initial light Final ligh Light ratio Q
Toxicant：Methacrylonitrile+Butyraldehyde
Toxicant：Methoxyacrylonitrile+Butyraldehyde (1:3)
Conc Initial light Final ligh Light ratio Q
Toxicant：Methoxyacrylonitrile+Butyraldehyde (3:1)
0.25 101.52 70.94 0.699 0.721 0.125 86 70 0.814 0.840Toxicant：Acrylonitrile+Glutaraldehyde
Toxicant：Acrylonitrile+Glutaraldehyde (1:3)
Conc Initial light Final ligh Light ratio Q
Toxicant：Acrylonitrile+Glutaraldehyde (3:1)
Conc Initial light Final ligh Light ratio Q
Toxicant：2-Chloroacrylonitrile+Glutaraldehyde
Toxicant：2-Chloroacrylonitrile+Glutaraldehyde (1:3)
Conc Initial light Final ligh Light ratio Q
Toxicant：2-Chloroacrylonitrile+Glutaraldehyde (3:1)
Conc Initial light Final ligh Light ratio Q
Toxicant：Methacrylonitrile+Glutaraldehyde
Toxicant：Methacrylonitrile+Glutaraldehyde (1:3)
Conc Initial light Final ligh Light ratio Q
Toxicant：Methacrylonitrile+Glutaraldehyde (3:1)
Conc Initial light Final ligh Light ratio Q
Toxicant：Methoxyacrylonitrile+Glutaraldehyde
Toxicant：Acrylonitrile+3-Hydroxybenzaldehyde
Toxicant：Methoxyacrylonitrile+Hydroxybenzaldehyde
Toxicant：3-Ethoxyacrylonitrile+Hydroxybenzaldehyde (1:3)
Conc Initial light Final ligh Light ratio Q
Toxicant：3-Ethoxyacrylonitrile+Hydroxybenzaldehyde (3:1)
Toxicant：3-Dimethylaminoacrylonitrile+3-Hydroxybenzaldehyde (1:3)
Conc Initial light Final ligh Light ratio Q
Toxicant：3-Dimethylaminoacrylonitrile+3-Hydroxybenzaldehyde (3:1)
Conc Initial light Final ligh Light ratio Q
TU
Control 94.87 84.62 0.892 1 4 88.07 12.97 0.147 0.165 2 89.39 25.29 0.283 0.317 1 99.23 41.31 0.416 0.467 0.5 92.78 52.99 0.571 0.640 0.25 91 62 0.681 0.764 0.125 101 74 0.733 0.821
丙醛檢量線