建議

1. 零價鋁於本研究中僅限於去除過氯酸鹽，未來可進一步探討不同陰離 子之污染物，例如NO₃^-、PO₄^-等，使零價鋁去除更具實用性。

2. 本研究配製零價鋁僅限於利用酸洗反應，未來可將其改質(例如:添加 界面活性劑、增加表面積與電荷)，應用在廢水處理實務上。

3. 針對本研究可進一步套用表面錯合模式(Surface complexation model) 分析，與液相內之陰、陽離子產生錯合反應，而形成表面錯合物，

此模式可以同時探討水溶液中多種離子被吸附的型態。

4. 進行管柱實驗，確認氫氧化鋁之最佳可行性，而深入探討其最佳操作 條件，以達到去除污染物之成效與貢獻度。

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附錄

口試委員意見回覆 口試委員: 台灣大學環境工程研究所 吳先琪 教授

1. 本研究目的中，有提到兩種去除機制，是否拿到文獻回顧比較好?

回覆: 已修正於論文 p.16 與 p.30。

2. 論文中第三章實驗方法，是否改寫成文章，不要用條列式比較好?

回覆: 已修正於論文 p.43。

3. 確認氯離子被吸附在氫氧化鋁表面之質量平衡

回覆: 實驗部份已補做，並列於論文 p.82 中重新修正。

4. 論文中提到溫度對吸附之影響，過氯酸鹽被氫氧化鋁吸附後，為什麼 會濃度回升?

回覆: 實驗部份已補做，並列於論文 p.75 中重新修正。

5. 論文中氯離子與硫酸根脫附劑的比較，是否標示加入時間?

回覆: 實驗部份已補做，並列於論文中重新修正。

6. 結論中有提到氫氧化鋁是一種良好吸附劑，是否可修改一下，結論下 的太果斷?

回覆: 已做修改論述 p.85~p.86。

7. 對於氫氧化鋁吸附過氯酸鹽，套用 Langmuir Isotherm 與 Freundlich Isotherm，建議可用表面錯合模式(surface complexation model)套用

回覆: 已放在論文 p.86 建議部份回覆。

口試委員: 義守大學土木與生態工學系 翁誌煌 教授

1. 本研究利用零價鋁去除過氯酸鹽，是否存在還原反應機制?

回覆: 經由系統性實驗證實，本研究去除機制主要是藉由吸附作用。

2. 本研究中是否有利用零價金屬去除氯酸鹽與次氯酸鹽?

回覆: 本研究利用零價金屬去除氯酸鹽與次氯酸鹽，此化合物易被 還原。

零價鋁金屬 5g 去除氯酸鹽

Time (hr)

0 1 2 3 4 5

ClO3- (mM)

0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16

ClO₃ -Cl

-3. 論文中文獻回顧零價鐵，建議填寫鐵之尺寸.

回覆: 已修正於論文 p.17

4. 本研究零價鋁金屬與氫氧化鋁之粒徑大小?

回覆: 已在論文中論述。

5. 在不同 pH 值條件下，零價鋁還原過氯酸鹽實驗，建議需重覆試驗 回覆: 已在修正於論文 p.63~p.64

6. 本研究添加硫酸鎂當脫附劑，是利用氫氧根還是硫酸根致換過氯酸鹽?

回覆: 主要是藉由硫酸根置換過氯酸鹽，其原因硫酸根親和力強，有足夠 能力取代過氯酸鹽。

7. 論文中再生性實驗，是否需要再重覆試驗?

回覆: 實驗部份已補做，並於論文 p.81~p.83 重新修正。

8. 氯離子與硫酸根濃度建議使用 mol/L 回覆: 已統一使用當量濃度。

9. 論文中零價鋁金屬於不同 pH 值去除 10 mg/L 過氯酸鹽，是否把反應 時間縮短，與求反應速率常數?

回覆: (a) 反應時間已縮短。

(b) 零價鋁在反應過程中會產生自發性放熱，溫度無法定溫，故無 法正確性求出反應速率常數，會放在建議部份。

10. 本研究氫氧化鋁吸附過氯酸鹽，套用 Freundlich Isotherm 等溫吸附模

式，其中n 值代表有利於吸附?可用線性求解?

回覆: 依該模式表示，當 n＞1 為有利吸附，n＜1 為不利吸附，本研究 n 值大於1，故是有利於吸附的。

口試委員: 高雄大學土木與環境工程學系 袁菁 教授

1.論文第三章建議把研究架構做為 3.1 節討論，並把架構分為兩部份，讓 研究鮮明易懂

回覆: 已修正於論文 p.39。

2.QA/QC 是否有做?

回覆: QA/QC 已放於論文 p.52~53。

3.論文中文獻引用之編排、格式、引用，需再重新確認 回覆: 已修正於論文。

4.論文中第三章實驗材料，建議標示分析級與試藥級 回覆: 已修正標示清楚每藥品等級於 p.40。

5.論文單位表示問題，建議 HR 應改 hr，ppm 改成 mg/L，測氫氣 cc 數改 mL

回覆: 已修正單位表示。

6.零價鋁金屬在放熱過程中會產生氫氣，氫氣如何偵測?是否有質量平衡?

回覆: 本研究使用針筒量測氫氣，該方法在論文 p.39 述說。

7.論文中圖 4-9 與圖 4-10 建議合併放在一起比較 回覆: 已修正於論文中。

8.論文中圖 4-12，零價鋁去除過氯酸鹽於溫度 75~80°C 反應，溫度的準 確性?溫度對過氯酸鹽之影響是否可用熱力學計算?

回覆: (a) 於恆溫培養箱操作，溫度準確性 80±2°C。

(b) 本研究目前沒探討到熱力學部份。

9.可比較本研究氫氧化鋁與活性碳之差異性?

回覆: 本活性碳文獻回顧都是利用管柱實驗來探討吸附量，而本研究為批

回覆: 本活性碳文獻回顧都是利用管柱實驗來探討吸附量，而本研究為批

在文檔中 利用零價鋁金屬去除過氯酸鹽之研究 (頁 93-114)