第四章 實驗結果
5.2 未來展望
本篇論文研究的材料為 P3HT 奈米線,現階段探討其熱導性質,在下個階段可探 討 P3HT 奈米線的 Seebeck coefficient,以得到完整的熱電性質而取得 ZT 熱電優值。
太陽供給地球熱能與光,熱能可為一大能源,但較為少使用而散失。目前 P3HT 此材料主要是作為太陽能電池的主動層,也許未來可利用 P3HT 的熱電性質來結合現 今的太陽能電池,可同時轉換光能與熱能而產生電。
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參考文獻
[1] “Thermoelectric Materials: Principles, structure, properties, and applications”, Encyclopedia of Materials: Science and Technology, pp.1-11, 2002
[2] D. W. Rowe, “CRC Handbook of Thermoelectric”, CRC Press: New York, 1995 [3] Jihui Yang; Thierry Caillat, “Thermoelectric Materials for Space and Automotive
Power Generation”, MRS BULLETIN, Volume 31, 2006
[4] Terry M. Tritt; M.A. Subramanian, “ Thermoelectric Materials, Phenomena, and Applications: A Bird’s Eye View, MRS BULLETIN, Volume 31, 2006
[5] 陳尚謙, 「準單晶碲化鉍奈米線和薄膜的熱電性質研究」, 碩士論文, 國立政治大 學, 2011
[6] Lihong Shi; Donglai Yao; Gang Zhang and Baowen Li, “Size dependent thermoelectric properties of silicon nanowires”, Appl. Phys. Lett., 95, 2009
[7] Dong Wang; Wen Shi; Jianming Chen; Jinyang Xi and Zhigang Shuai, “Modeling thermoelectric transport in organic materials”, Phys. Chem. Phys., 14, pp16505-16520, 2012
[8] D. Li YW, P. Kim, L. Shi, P. Yang, A. Majumdar. Appl phys Lett, 83 (2934), 2004 [9] M. S. Dresselhaus1; G. Chen1; M. Y. Tang1; R. G. Yang1; H. Lee1; D. Z. Wang2; Z. F.
Ren2; J.-P. Fleurial3 and P. Gogna3, “New Directions for Low-Dimensional Thermoelectric Materials”, Advanced Materials, 19, (8), pp 1043–1053, 2007 [10] Tian An Chen ; Xiaoming Wu; Reuben Rieke; ”Regiocontrolled Synthesis of
Poly(3-alkythiophenes) Mediated by Rieke Zinc: Their Characterization and Solid-State Properties ”, J. Am Chem. Soc, 117(1), pp233-244, 1995
[11] Roncali, J., “Conjugated poly(thiophenes): synthesis, functionalization, and applications”, Chemical Reviews, 92, (4), pp.711-738, 1992
[12] Salleo, A., “Charge transport in polymeric transistors”, Materials Today, 10, (3),
pp.38-67
45, 2007
[13] Chen, J. T.; Hsu, C. S. Polymer Chemistry, 2, (12), pp.2707-2722, 2011
[14] Adachi, T.; Brazard, J.; Ono, R. J.; Hanson, B.; Traub, M. C.; Wu, Z.-Q.; Li, Z.;
Bolinger, J. C.; Ganesan, V.; Bielawski, C. W.; Vanden Bout, D. A.; Barbara, P. F, J.
Phys. Chem. Lett., 2, (12), pp.1400-1404, 2011
[15] Kiriy, N.; Jähne, E.; Adler, H.-J.; Schneider, M.; Kiriy, A.; Gorodyska, G.; Minko, S.;
Jehnichen, D.; Simon, P.; Fokin, A. A.; Stamm, M. Nano letters, 3, (6), pp.707-712, 2003 Ihn, K. J.; Moulton, J.; Smith, P. J. Polym. Sci. Pt. B-Polym. Phys., 31, (6), pp.735-742, 1993
[16] Oosterbaan, W. D.; Vrindts, V.; Berson, S.; Guillerez, S.; Douhéret, O.; Ruttens, B.;
D'Haen, J.; Adriaensens, P.; Manca, J.; Lutsen, L.; Vanderzande, D. Journal of aterials Chemistry, 19, (30), 2009
[17] Berson, S.; De Bettignies, R.; Bailly, S.; Guillerez, S. Advanced Functional Materials, 17, (8), pp.1377-1384, 2007
[18] 傅傳閔, 「以晶鬚法製備聚三己基噻吩奈米線並探討退火處理對其特性之影響」, 國立交通大學, 民國 102 年 7 月
[19] L.R. Harrott, Proceedings of the 1999 Particle Accelerator Conference, pp.595-599, 1999.
[20] 馬力得, 「徘徊十字路口 微影技術面臨發展鴻溝」, 電子工程專輯, 2010 年 5 月 10 日
[21] 王敬堯,「單一奈米鑽石之光學特性研究」, 國立東華大學, 碩士論文, 2007 [22] Michael Quirk; Julian Serda, 半導體製程技術 Semiconductor Manufacturing
Technology, 台灣培生教育出版股份有限公司, 2004
[23] The Semiconductor International Manufacturing Process, Glossary of Semiconductor
68
Terms, Fullman Company, 1998
[24] 陳弘仁,「微機電系統的市場發展現況及未來趨勢」, 奈米通訊,19 卷 No.3 [25] Deyu Li; Yiying Wu; Philip Kin; Li Shi; Peidong Yang; Arun Majumdar, “Thermal
Transport in Individual Nanowires and Nanotubes”, Applied Physics Letter, Vol 83, 14, pp.2934-2936, 2003
[26] Shi L. “Mesoscopic Thermophysical Measurements of Microstructures and Carbon Nanotubes”, University of California, PhD thesis, 2001
[27] 柯廷育,「介觀下熱物理之單根高電阻三硒化二銻奈米線之量測方法與探討」, 國 立交通大學, 博士論文, 民國 103 年 11 月
[28] Xing Zhang; Huaqing Xie; Motoo Fujii; Koji Takahashi; Tatsuya Ikuta; Hiroki Ago;
Hidekazu Abe; Tetsuo Shimizu, International Journal of Heat and Mass Transfer, 49, pp.3879-3883, 2006
[29] Ming He; Jing Ge; Zhiqun Lin; Xuhui Feng; Xinwei Wang; Hongbin Lu; Yuliang Yang and Feng Qiu, “Thermopower enhancement in conducting polymer nanocomposites via carrier energy scattering at the organic-inorganic semiconductor interface”, Energy &
Environmental Science, 5, 8351, 2012
[30] Berson, S.; De Bettignies, R.; Bailly, S.; Guillerez, S. Advanced Functional Materials, 17, (8), pp.1377-1384, 2007
[31] Yamamoto, K.; Akita, S.; Nakayama, Y, J Appl Phys. (Jpn), 35, 917, 1996 [32] Bechloefer, J. ; Wilson, S., American Journal of Physics, 70(4), 393, 2002
[33] Baur CB; A. Koel; B. E, Madhukar; A., Montoya; N. Ramachandran; T. R., Requicha, A. A. G, Resch,R.; Will P, Nanotechnology, 9(360), 1998
[34] 粘正勳, 邱聞鋒, 「介電泳動─承先啟後的奈米操縱術」, 物理雙月刊, 二十三卷 六期, 2004 年 6 月
[35] Motoo Fujii; Xing Zhang; Huaqing Xie; Hiroki Ago; Koji Takahashi; Tatsuya Ikuta;
69
Hidekazu Abe; Tetsuo Shimizu, “Measuring the Thermal Conductivity of a Single Carbon Nanotube”, Physical Review Letters, 065502, 2005
[36] P. Kim; L. Shi; A. Majumdar; P.L. McEuen, Phys. Rev. Lett. 87, 215502, 2001 [37] Schӓfer, F.P, “Dye Lasers”, Principles of dye laser operation, in Topics in Applied
Physics, vol.1, pp.1-83, 1973
[38] 洪國川,「共焦拉曼與螢光顯微鏡之發展及其在材料診斷上之應用」,國立中央 大學,碩士論文,民國 99 年 6 月
[39] Junku Li; Qunqing Li; Yuan Zou, Qingkai Qian; Yuanhao Jin; Guanhong Li; Kaili Jiang and Shoushan Fan, “The Dependence of Graphene Raman D-band on Carrier Density”, Nano Lett., 13 (12), pp. 6170–6175, 2013
[40] David E. Motaug; Gerald F. Malgas; Christopher J. Arendse; Sipho. E Mavundla and D. Knoesen, “Structural and photo-physical properties of spin-coated poly
(3-hexylthiophene) thin films”, Materials Chemistry and Physics, Volume 116, Issue 1, pp.
279–283, 15 July 2009
[41] Aryal, M.; Trivedi, K.; Hu, W. ACS Nano, 3, (10), 3085-3090, 2009
[42] Yonemura, H.; Yuno, K.; Yamamoto, Y.; Yamada, S.; Fujiwara, Y.; Tanimoto, Y.
Synthetic Metals, 159, (9-10), pp.955-960, 2009
[43] 蘇明德,「能導電的高分子」, 科學發展, 452 期, 2010 年 8 月
[44] John C. Duada; Patrick E. Hopkins; Yang Shen, Mool C. Gupta, “Exceptionally Low Thermal Conductivities of Semiconducting Polymers and Fullerene Derivatives”, Phys.
Rev. Lett., 110, (1), 2013