本實驗已確立於鎳鈦合金上施鍍之氧化鋁膜層性質，並針對不同 cycle 之參數 進行分析，得到彎曲測試、抗腐蝕性質測試、鎳溶出檢測等結果。而未來持續研 究工作將會以本實驗之參數，選擇一最佳化參數並針對施鍍膜層之血液相容性、
骨細胞相容性、細胞毒性等性質測試，以得到施鍍膜層之生物相容性結果，確立 膜層之最佳化參數，期以完成 ALD 表面改質鎳鈦合金於醫療產品之適用性評估，
並提供後續動物試驗與實際應用之重要參考依據。
參考文獻
1. Chang, L. and T. Read, PLASTIC DEFORMATION AND DIFFUSIONLESS PHASE CHANGES IN METALS THE BOLD-CADMIUM BETA PHASE. 1950, Columbia University.
2. Otsuka, K. and K. Shimizu, Pseudoelasticity and shape memory effects in alloys.
International Metals Reviews, 1986. 31(1): p. 93-114.
3. Wayman, C., Some applications of shape-memory alloys. JOM, 1980. 32(6): p.
129-137.
4. Sato, A., et al., Shape memory effect in γ⇄ ϵ transformation in Fe-30Mn-1Si alloy single crystals. Acta Metallurgica, 1982. 30(6): p. 1177-1183.
5. Pilate, F., et al., Shape-memory polymers for multiple applications in the materials world. European Polymer Journal.
6. Lendlein, A., et al., Chapter 09244 - Shape-Memory Polymers, in Reference Module in Materials Science and Materials Engineering. 2016, Elsevier.
7. Ramdas, M.R., K.S.S. Kumar, and C.P.R. Nair, Click polymerizations:
Encouraging route for shape memory polymers. Materials Letters, 2016. 172: p.
216-221.
8. Du, Z., et al., Size effects and shape memory properties in ZrO2 ceramic micro- and nano-pillars. Scripta Materialia, 2015. 101: p. 40-43.
9. Lobo, P.S., J. Almeida, and L. Guerreiro, Shape Memory Alloys Behaviour: A Review. Procedia Engineering, 2015. 114: p. 776-783.
10. Tadaki, T., K. Otsuka, and K. Shimizu, Shape memory alloys. Annual Review of Materials Science, 1988. 18(1): p. 25-45.
11. Ortin, J. and A. Planes, Thermodynamic analysis of thermal measurements in thermoelastic martensitic transformations. Acta metallurgica, 1988. 36(8): p.
1873-1889.
12. Tong, H.C. and C.M. Wayman, Characteristic temperatures and other properties of thermoelastic martensites. Acta Metallurgica, 1974. 22(7): p. 887-896.
13. Salzbrenner, R.J. and M. Cohen, On the thermodynamics of thermoelastic martensitic transformations. Acta Metallurgica, 1979. 27(5): p. 739-748.
14. Miyazaki, S., et al., Characteristics of deformation and transformation
pseudoelasticity in Ti-Ni alloys. Le Journal de Physique Colloques, 1982. 43(C4):
p. C4-255-C4-260.
15. Aaronson, H., et al., Solid to Solid Phase Transformations. Pittsburgh, Pa, 10-14 Aug. 1981, 1981: p. 1982.
16. Olson, G. and M. Cohen, Thermoelastic behavior in martensitic transformations.
Scripta Metallurgica, 1975. 9(11): p. 1247-1254.
17. Saburi, T., S. Nenno, and C. Wayman, Shape memory mechanisms in alloys.
ICOMAT 1979. Martensitic Transformations, 1979: p. 619-632.
18. Nishida, M. and T. Honma, All-round shape memory effect in Ni-rich TiNi alloys generated by constrained aging. Scripta Metallurgica, 1984. 18(11): p.
1293-1298.
19. Miyazaki, S., K. Otsuka, and Y. Suzuki, Transformation pseudoelasticity and deformation behavior in a Ti-50.6at%Ni alloy. Scripta Metallurgica, 1981. 15(3):
p. 287-292.
20. Hodgson, D.E., W. Ming, and R.J. Biermann, Shape memory alloys. ASM International, Metals Handbook, Tenth Edition., 1990. 2: p. 897-902.
21. 林世庭, Ti50Ni50 及 Ti49.3Ni50.7 鈦鎳形狀記憶合金變態及機械性能之研究, in 材料科學與工程學研究所. 2010, 國立臺灣大學: 台北市. p. 115.
22. Naito, H., et al., Analytical study on training effect of pseudoelastic
transformation of shape memory alloys in cyclic loading. Journal of intelligent material systems and structures, 2001. 12(4): p. 295-300.
23. Jackson, B., et al., Production of NiTi via the FFC Cambridge process. Journal of The Electrochemical Society, 2008. 155(12): p. E171-E177.
24. Jackson, C., H. Wagner, and R. Wasilewski, NASA-SP 5110. Technology Utilization Office, 1972.
25. Otsuka, K., T. Sawamura, and K. Shimizu, Crystal structure and internal defects of equiatomic TiNi martensite. Physica status solidi (a), 1971. 5(2): p. 457-470.
26. Šittner, P., et al., R-phase transformation phenomena in thermomechanically loaded NiTi polycrystals. Mechanics of Materials, 2006. 38(5–6): p. 475-492.
27. Saburi, T., New development of TiNi shape memory alloys, in Ecomaterials.
1994, Elsevier. p. 997-1002.
28. Ling, H.C. and K. Roy, Stress-induced shape changes and shape memory in the R and martensite transformations in equiatomic NiTi. Metallurgical Transactions A, 1981. 12(12): p. 2101-2111.
29. Duerig, T. and K. Bhattacharya, The influence of the R-phase on the superelastic behavior of NiTi. Shape Memory and Superelasticity, 2015. 1(2): p. 153-161.
30. Fernandes, D.J., et al., Understanding the shape-memory alloys used in orthodontics. ISRN dentistry, 2011. 2011.
31. Shaw, J.A. and S. Kyriakides, Thermomechanical aspects of NiTi. Journal of the Mechanics and Physics of Solids, 1995. 43(8): p. 1243-1281.
32. Furukawa-Techno-Material. Shape Memory Alloys & Super-elastic Alloys. 2000;
33. Otsuka, K. and X. Ren, Recent developments in the research of shape memory alloys. Intermetallics, 1999. 7(5): p. 511-528.
34. Starosvetsky, D. and I. Gotman, Corrosion behavior of titanium nitride coated Ni–Ti shape memory surgical alloy. Biomaterials, 2001. 22(13): p. 1853-1859.
35. Kohn, J., et al., Biomaterials science: an introduction to materials in medicine.
Academic, San Diego, 1996: p. 64-73.
36. Bronzino, J.D., Biomedical engineering handbook. Vol. 2. 1999: CRC press.
37. Yachia, D. and M. Beyar, New treatment modality for penile urethral strictures using a self-expanding and self-retaining coil stent: UroCoil. Follow-up of 16 months after removal of the stent. European urology, 1992. 24(4): p. 500-504.
38. Gil, F., J. Manero, and J. Planell, Relevant aspects in the clinical applications of NiTi shape memory alloys. Journal of Materials Science: Materials in Medicine, 1996. 7(7): p. 403-406.
39. Xu, J.L., et al., Microstructure, mechanical properties and superelasticity of biomedical porous NiTi alloy prepared by microwave sintering. Materials Science and Engineering: C, 2015. 46: p. 387-393.
40. Xu, J.L., et al., Effect of pore sizes on the microstructure and properties of the biomedical porous NiTi alloys prepared by microwave sintering. Journal of Alloys and Compounds, 2015. 645: p. 137-142.
41. Zhang, L., et al., Superelastic behaviors of biomedical porous NiTi alloy with high porosity and large pore size prepared by spark plasma sintering. Journal of Alloys and Compounds, 2015. 644: p. 513-522.
42. Huan, Z., et al., Porous NiTi surfaces for biomedical applications. Applied Surface Science, 2012. 258(13): p. 5244-5249.
43. Rocher, P., et al., Biocorrosion and biocompatibility of NiTi alloys. Eur Cell Mater, 2005. 9: p. 23-24.
44. Chu, C.L., et al., Surface structure and biomedical properties of chemically polished and electropolished NiTi shape memory alloys. Materials Science and Engineering: C, 2008. 28(8): p. 1430-1434.
45. Batalu, D. and H. Guoqiu, Improvement of the corrosion resistance of equiatomic NiTi shape memory alloy for medical implants by the electropolishing method. UPB Scientific Bulletin B, 2009. 71: p. 832.
46. COVIDIEN. Protege™ GPS™. 2014; Available from:
http://www.medicalexpo.com/prod/covidien/peripheral-stents-nitinol-self-expan ding-74674-552139.html.
47. ELLA-CS. Esophageal stent. 2014; Available from:
http://www.medicalexpo.com/prod/ella-cs/esophageal-stents-nitinol-78568-4899 66.html.
48. PLC, U.H. Niti-S Esophageal Stents. 2014; Available from:
http://www.aquilantinterventional.com/products/products_detail.asp?subp=prod ucts_by_all.asp&idProduct=846.
49. Medical, C. Our history: Nitinol stone extractors. 2014; Available from:
https://www.cookmedical.com/urology/our-history-nitinol-stone-extractors/.
50. Garrido Abad, P., et al., Dispositivos antimigración durante la litotricia
endoscópica con láser de holmium: YAG. Archivos Españoles de Urología (Ed.
impresa), 2008. 61(9): p. 1115-1125.
51. 醫源世界. 骨折修復術. 2006; Available from:
http://big5.39kf.com/cooperate/tu/yx/ss/gktk/2006-07-19-219353.shtml.
52. Stepan, L.L., D.S. Levi, and G.P. Carman, A thin film nitinol heart valve. Journal of biomechanical engineering, 2005. 127(6): p. 915-918.
53. Materials, S.A. Nitinol Dental Braces (Nickel titanium). 2013; Available from:
http://www.samaterials.com/nitinol/407-nitinol-dental-braces.html.
54. Handysides, R. Advances in clinical endodontic instruments. 2010; Available from:
http://dentistry.llu.edu/about/news/advances-clinical-endodontic-instruments.
55. Jia, W., et al., Nickel release from orthodontic arch wires and cellular immune response to various nickel concentrations. Journal of biomedical materials research, 1999. 48(4): p. 488-495.
56. Savarino, L., et al., Effects of metal ions on white blood cells of patients with failed total joint arthroplasties. Journal of biomedical materials research, 1999.
47(4): p. 543-550.
57. Blanco-Dalmau, L., H. Carrasquillo-Alberty, and J. Silva-Parra, A study of nickel allergy. The Journal of prosthetic dentistry, 1984. 52(1): p. 116-119.
58. Pereira, M.C., M.L. Pereira, and J.P. Sousa, Histological effects of iron accumulation on mice liver and spleen after administration of a metallic solution. Biomaterials, 1999. 20(22): p. 2193-2198.
59. Castleman, L. and S. Motzkin, The biocompatibility of nitinol. CRC Press, Inc., Biocompatibility of Clinical Implant Materials, 1981. 1: p. 129-154.
60. Black, J., Biological performance of materials: fundamentals of biocompatibility.
2005: CRC Press.
61. Remes, A. and D. Williams, Immune response in biocompatibility. Biomaterials, 1992. 13(11): p. 731-743.
62. Freiberg, K.E., et al., Effect of thermomechanical pre-treatment on short- and long-term Ni release from biomedical NiTi. Acta Biomaterialia, 2014. 10(5): p.
2290-2295.
biological effects of cobalt chrome alloy and 316L stainless steel prosthetic particles with age. Journal of biomedical materials research, 2000. 49(2): p.
167-175.
64. Torgersen, S., G. Moe, and R. Jonsson, Immunocompetent cells adjacent to stainless steel and titanium miniplates and screws. European journal of oral sciences, 1995. 103(1): p. 46-54.
65. Vreeburg, K., et al., Induction of immunological tolerance by oral
administration of nickel and chromium. Journal of dental research, 1984. 63(2):
p. 124-128.
66. Peitsch, T., et al., The release of nickel from orthodontic NiTi wires is increased by dynamic mechanical loading but not constrained by surface nitridation.
Journal of Biomedical Materials Research Part A, 2007. 82(3): p. 731-739.
67. Xu, J.L., et al., Formation of Al2O3 coatings on NiTi alloy by micro-arc oxidation method. Current Applied Physics, 2009. 9(3): p. 663-666.
68. Cisse, O., et al., Effect of surface treatment of NiTi alloy on its corrosion behavior in Hanks’ solution. Journal of biomedical materials research, 2002.
61(3): p. 339-345.
69. Michiardi, A., et al., New oxidation treatment of NiTi shape memory alloys to obtain Ni‐free surfaces and to improve biocompatibility. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 2006. 77(2): p. 249-256.
70. Müller, B., et al., Cell growth on pore-graded biomimetic TiO2 bone scaffolds.
Journal of biomaterials applications, 2014: p. 0885328214559859.
71. Ng, K.W., H.C. Man, and T.M. Yue, Corrosion and wear properties of laser surface modified NiTi with Mo and ZrO2. Applied Surface Science, 2008.
254(21): p. 6725-6730.
72. Sun, T. and M. Wang. Chemical stability of the titania layer formed synthetically on NiTi shape memory alloy as a barrier to prevent nickel ion release. in
Information Technology and Applications in Biomedicine, 2008. ITAB 2008.
International Conference on. 2008. IEEE.
73. Wang, X., et al., Structure and properties of Al2O3 coatings formed on NiTi alloy by cathodic plasma electrolytic deposition. Surface and Coatings Technology, 2016. 285: p. 128-133.
74. Ying, Y., et al., Surface Modification of NiTi Alloy via Cathodic Plasma Electrolytic Deposition and its Effect on Ni Ion Release and Osteoblast Behaviors. Plasma Science and Technology, 2013. 15(7): p. 648.
75. Bernard, S.A., et al., Bone cell–materials interactions and Ni ion release of anodized equiatomic NiTi alloy. Acta Biomaterialia, 2011. 7(4): p. 1902-1912.
76. Wunderlich, W., The Atomistic Structure of Metal/Ceramic Interfaces Is the Key
Issue for Developing Better Properties. Metals, 2014. 4(3): p. 410-427.
77. BeneQ. Equipment for Roll to Roll Atomic Layer Deposition. 2010; Available from:
http://nextbigfuture.com/2010/04/equipment-for-roll-to-roll-atomic-layer.html.
78. Clark, R.D., Emerging Applications for High K Materials in VLSI Technology.
Materials, 2014. 7(4): p. 2913-2944.
79. ALD Japan, I. 成膜装置の代表例. 2015; Available from: http://aldjapan.com/.
80. Elam, J., et al., Conformal coating on ultrahigh-aspect-ratio nanopores of anodic alumina by atomic layer deposition. Chemistry of Materials, 2003.
15(18): p. 3507-3517.
81. Knaut, M., et al., Atomic layer deposition for high aspect ratio through silicon vias. Microelectronic Engineering, 2013. 107: p. 80-83.
82. Cornagliotti, E., et al., Large area p-type PERL cells featuring local p+ BSF formed by laser processing of ALD Al2O3 layers. Solar Energy Materials and Solar Cells, 2015. 138: p. 72-79.
83. Werner, F., A. Cosceev, and J. Schmidt, Silicon Surface Passivation by Al2O3:
Recombination Parameters and Inversion Layer Solar Cells. Energy Procedia, 2012. 27: p. 319-324.
84. Härkönen, J., et al., Atomic Layer Deposition (ALD) grown thin films for ultra-fine pitch pixel detectors. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment.
85. Pan, F.-M. 原子層化學氣相沉積(Atomic Layer Chemical Vapor Deposition, ALCVD). Available from: http://web.it.nctu.edu.tw/~FMPANLAB/ALD.htm.
86. Hatanpää, T., M. Ritala, and M. Leskelä, Precursors as enablers of ALD
technology: Contributions from University of Helsinki. Coordination Chemistry Reviews, 2013. 257(23–24): p. 3297-3322.
87. Emslie, D.J.H., P. Chadha, and J.S. Price, Metal ALD and pulsed CVD:
Fundamental reactions and links with solution chemistry. Coordination Chemistry Reviews, 2013. 257(23–24): p. 3282-3296.
88. Zhang, L. and M. Knez, Chapter 16 - Atomic Layer Deposition for Biomimicry, in Engineered Biomimicry. 2013, Elsevier: Boston. p. 399-428.
89. Barbos, C., et al., Characterization of Al2O3 Thin Films Prepared by Thermal ALD. Energy Procedia, 2015. 77: p. 558-564.
90. Dingemans, G. and W. Kessels, Status and prospects of Al2O3-based surface passivation schemes for silicon solar cells. Journal of Vacuum Science &
Technology A, 2012. 30(4): p. 040802.
silicon wafers passivated with a dielectric with fixed negative charge. Solar Energy Materials and Solar Cells, 2006. 90(18–19): p. 3438-3443.
92. Hoex, B., et al., Ultralow surface recombination of c-Si substrates passivated by plasma-assisted atomic layer deposited Al2O3. Applied Physics Letters, 2006.
89(4): p. 042112.
93. plasma-ald.com. Plasma Enhanced Atomic Layer Deposition. 2015; Available from: http://www.plasma-ald.com/?q=peald.
94. Dillon, A.C., et al., Surface chemistry of Al2O3 deposition using Al(CH3)3 and H2O in a binary reaction sequence. Surface Science, 1995. 322(1–3): p.
230-242.
95. Puurunen, R.L., Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process. Journal of applied physics, 2005. 97(12):
p. 121301.
96. George, S.M., Atomic layer deposition: an overview. Chemical reviews, 2009.
110(1): p. 111-131.
97. Wind, R. and S. George, Quartz Crystal Microbalance Studies of Al2O3 Atomic Layer Deposition Using Trimethylaluminum and Water at 125° C†. The Journal of Physical Chemistry A, 2009. 114(3): p. 1281-1289.
98. Venables, J., Introduction to surface and thin film processes. 2000: Cambridge University Press.
99. Matero, R., et al., Effect of water dose on the atomic layer deposition rate of oxide thin films. Thin Solid Films, 2000. 368(1): p. 1-7.
100. Kim, S.K., et al., Low temperature (< 100 C) deposition of aluminum oxide thin films by ALD with O3 as oxidant. Journal of The Electrochemical Society, 2006.
153(5): p. F69-F76.
101. Widjaja, Y. and C.B. Musgrave, Quantum chemical study of the mechanism of aluminum oxide atomic layer deposition. Applied Physics Letters, 2002. 80(18):
p. 3304-3306.
102. Yun, S.J., et al., Dependence of atomic layer-deposited Al2O3 films
characteristics on growth temperature and Al precursors of Al (CH3) 3 and AlCl3. Journal of Vacuum Science & Technology A, 1997. 15(6): p. 2993-2997.
103. Groner, M., et al., Low-temperature Al2O3 atomic layer deposition. Chemistry of Materials, 2004. 16(4): p. 639-645.
104. Wang, X., et al., Improvement of blood compatibility of artificial heart valves via titanium oxide film coated on low temperature isotropic carbon. Surface and Coatings Technology, 2000. 128–129: p. 36-42.
105. Gibson, T.P., W.A. Briggs, and B.J. Boone, Delivery of di-2-ethylhexyl phthalate to patients during hemodialysis. The Journal of laboratory and clinical medicine,
1976. 87(3): p. 519-524.
106. Gieraltowska, S., et al., Properties and characterization of ALD grown dielectric oxides for MIS structures. arXiv preprint arXiv:1107.5401, 2011.
107. Jakschik, S., et al., Physical characterization of thin ALD–Al2O3 films. Applied Surface Science, 2003. 211(1–4): p. 352-359.
108. Barbos, C., et al., Al2O3 thin films deposited by thermal atomic layer deposition:
Characterization for photovoltaic applications. Thin Solid Films.
109. Wang, P.C., et al., Effects of pre-sputtered Al interlayer on the atomic layer deposition of Al2O3 films on Mg–10Li–0.5Zn alloy. Applied Surface Science, 2013. 270: p. 452-456.
110. Naumann, V., et al., Interface and Material Characterization of Thin ALD-Al2O3 Layers on Crystalline Silicon. Energy Procedia, 2012. 27: p.
312-318.
111. Chang, M.L., et al., Improvement of oxidation resistance of copper by atomic layer deposition. Applied Surface Science, 2012. 258(24): p. 10128-10134.
112. Moret, M., et al., Atomic Layer Deposition of zinc oxide for solar cell applications. Superlattices and Microstructures, 2014. 75: p. 477-484.
113. Dobbelaere, T., et al., Plasma-enhanced atomic layer deposition of zinc phosphate. Journal of Non-Crystalline Solids, 2016. 444: p. 43-48.
114. Shan, C.X., X. Hou, and K.-L. Choy, Corrosion resistance of TiO2 films grown on stainless steel by atomic layer deposition. Surface and Coatings Technology, 2008. 202(11): p. 2399-2402.
115. Marin, E., et al., Chemical and electrochemical characterization of hybrid PVD + ALD hard coatings on tool steel. Electrochemistry Communications, 2009.
11(10): p. 2060-2063.
116. Fedel, M. and F. Deflorian, Electrochemical characterization of atomic layer deposited Al2O3 coatings on AISI 316L stainless steel. Electrochimica Acta.
117. Zhang, Y., et al., Electroplating to visualize defects in Al2O3 thin films grown using atomic layer deposition. Thin Solid Films, 2009. 517(11): p. 3269-3272.
118. Chang, M.L., et al., Investigation of defects in ultra-thin Al2O3 films deposited on pure copper by the atomic layer deposition technique. Applied Surface Science, 2015. 359: p. 533-542.
119. Zhang, Y., et al., Investigation of the defect density in ultra-thin Al 2 O 3 films grown using atomic layer deposition. Surface and Coatings Technology, 2011.
205(10): p. 3334-3339.
120. Schad, R., et al., Pinhole analysis in magnetic tunnel junctions. Applied Physics Letters, 2000. 76(5): p. 607-609.
strains for cracking of Al2O3 films grown by atomic layer deposition. Journal of Applied Physics, 2011. 109(8): p. 084305.
122. McClure, C.D., C.J. Oldham, and G.N. Parsons, Effect of Al2O3 ALD coating and vapor infusion on the bulk mechanical response of elastic and viscoelastic polymers. Surface and Coatings Technology, 2015. 261: p. 411-417.
123. Zhang, Y., et al., Fluorescent tags to visualize defects in Al2O3 thin films grown using atomic layer deposition. Thin Solid Films, 2009. 517(24): p. 6794-6797.
124. 楊政修, 增進鈦鎳形狀記憶合金抗沖蝕特性之研究, in 材料科學所. 2002, 逢甲大學: 台中市. p. 169.
125. SIGMA-ALDRICH. Trimethylaluminum. 2016; Available from:
http://www.sigmaaldrich.com/catalog/product/aldrich/597775?lang=en®ion=
TW.
126. Ultratech/CambridgeNanoTech. Thin Film Deposition - Savannah. 2014;
Available from:
http://www.cambridgenanotechald.com/thin-film-deposition.shtml#.
127. Henry, D. Wavelength-Dispersive X-Ray Spectroscopy (WDS). 2012; Available from: http://serc.carleton.edu/research_education/geochemsheets/wds.html.
128. Components, j.M.M. Measuring Transformation Temperatures in Nitinol Alloys.
2016; Available from:
http://jmmedical.com/resources/211/Measuring-Transformation-Temperatures-in -Nitinol-Alloys.html.
129. corporation, S. X-ray Diffraction. 2015; Available from:
http://www.shimadzu.com/an/elemental/xrd/onesight.html.
130. Wikipedia. X-ray photoelectron spectroscopy. 2016; Available from:
https://en.wikipedia.org/wiki/X-ray_photoelectron_spectroscopy.
131. Lubomirsky, I., Manual Ellipsometer. 2016.
132. Wikipedia. Transmission electron microscopy. 2016; Available from:
https://en.wikipedia.org/wiki/Transmission_electron_microscopy.
133. Materials, A. Attenuated Total Reflection (ATR) Mode – Advantages for FT-IR Spectroscopy. 2016; Available from:
http://www.azom.com/article.aspx?ArticleID=5958.
134. Zhang, C. FTIR Spectrum. 2015; Available from:
http://terpconnect.umd.edu/~zhangx/html/ftir.html.
135. Njobuenwu, D.O., E. Oboho, and R.H. Gumus, Determination of contact angle from contact area of liquid droplet spreading on solid substrate. Leonardo Electronic Journal of Practices and Technologies, 2007. 10: p. 29-38.
136. Karthega, M., V. Raman, and N. Rajendran, Influence of potential on the electrochemical behaviour of β titanium alloys in Hank’s solution. Acta
Biomaterialia, 2007. 3(6): p. 1019-1023.
137. Kokubo, T. and H. Takadama, How useful is SBF in predicting in vivo bone bioactivity? Biomaterials, 2006. 27(15): p. 2907-2915.
138. Research, P.A. PARSTAT 4000+ Overview. 2010; Available from:
http://www.princetonappliedresearch.com/Our-Products/Potentiostats/PARSTAT -4000.aspx.
139. Kahrilas, G. Inductively Coupled Plasma–Mass Spectrometry. 2016; Available from: https://icp-ms.wikispaces.com/.
140. Cao, Y., L. Nyborg, and U. Jelvestam, XPS calibration study of thin‐film nickel silicides. Surface and Interface Analysis, 2009. 41(6): p. 471-483.
141. Grosvenor, A.P., et al., New interpretations of XPS spectra of nickel metal and oxides. Surface Science, 2006. 600(9): p. 1771-1779.
142. Wang, R.M., et al., Surface XPS characterization of NiTi shape memory alloy after advanced oxidation processes in UV/H2O2 photocatalytic system. Applied Surface Science, 2007. 253(20): p. 8507-8512.
143. Ferguson, J., A. Weimer, and S. George, Atomic layer deposition of Al2O3 films on polyethylene particles. Chemistry of materials, 2004. 16(26): p. 5602-5609.
144. Goldstein, D.N., J.A. McCormick, and S.M. George, Al2O3 atomic layer deposition with trimethylaluminum and ozone studied by in situ transmission FTIR spectroscopy and quadrupole mass spectrometry. The Journal of Physical Chemistry C, 2008. 112(49): p. 19530-19539.
145. Rai, V.R., V. Vandalon, and S. Agarwal, Influence of surface temperature on the mechanism of atomic layer deposition of aluminum oxide using an oxygen plasma and ozone. Langmuir, 2011. 28(1): p. 350-357.
146. Wang, W., et al., Trimethylethoxysilane-modified super heat-resistant alumina aerogels for high-temperature thermal insulation and adsorption applications.
RSC Advances, 2014. 4(97): p. 54864-54871.
147. Birnin-Yauri, U.A. and F.P. Glasser, Friedel’s salt, Ca2Al(OH)6(Cl,OH)·2H2O:
its solid solutions and their role in chloride binding. Cement and Concrete Research, 1998. 28(12): p. 1713-1723.
148. Young, T., An essay on the cohesion of fluids. Philosophical Transactions of the Royal Society of London, 1805. 95: p. 65-87.
149. Wenzel, R.N., Resistance of solid surfaces to wetting by water. Industrial &
Engineering Chemistry, 1936. 28(8): p. 988-994.
150. Cassie, A. and S. Baxter, Wettability of porous surfaces. Transactions of the Faraday Society, 1944. 40: p. 546-551.
151. Makkonen, L., Young’s equation revisited. Journal of Physics: Condensed Matter,
152. Wikipedia. Hydrophobicity. 2015; Available from:
https://zh.wikipedia.org/wiki/%E7%96%8F%E6%B0%B4%E6%80%A7.
153. Schroeder, H.A., J.J. Balassa, and I.H. Tipton, Abnormal trace metals in man — nickel. Journal of Chronic Diseases, 1962. 15(1): p. 51-65.
154. Bour, H., et al., Establishment of Nickel-Specific T Cell Lines from Patients with Allergic Contact Dermatitis: Comparison of Different Protocols. Clinical Immunology and Immunopathology, 1994. 73(1): p. 142-145.