未來展望

1. 整理出擁有最佳場發射效率之氧化鋅奈米線參數:長度、線徑、密度、成 長方向。

2. 實際應用此氧化鋅奈米線/奈米鑽石薄膜複合結構於場發射式氣體感測 器和場發射顯示器。

參考文獻

[1] A. M. Morales and C. M. Lieber, “A laser ablation method for the synthesis of crystalline semiconductor nanowires”, Science, 279 (1998) 208−211.

[2] X. F. Duan, Y. Huang, Y. Cui, J. Wang, L. Lauhon, K. Kim, and C.M.

Lieber, “Logic gates and computation from assembled nanowire building blocks”, Science, 294 (2001) 1313−1317.

[3] Y. Cui and C.M. Lieber, “Functional nanoscale electronic devices assembled using silicon nanowire building blocks”, Science, 291 (2001) 851−853.

[4] X. F. Duan, Y. Huang, Y. Cui, J. Wang, and C.M. Lieber, “Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices”, Nature, 409 (2001) 66−69.

[5] T. W. Odom, J. L. Huang, P. Kim, and C.M. Lieber, “Atomic structure and electronic properties of single-walled carbon nanotubes”, Nature, 391 (1998) 62−64.

[6] H. Dai, J. Kong, C. Zhou, N. Franklin, T. Tmobler, A. Cassell, S. Fan, and M. Chapline, “Controlled chemical routes to nanotube architectures, physics, and devices”, Journal of Physical Chemistry B, 103 (1999) 11246−11255.

[7] S. J. Tans, R. M. Verschueren, and C. Dekker, “Room-temperature transistor based on a single carbon nanotube”, Nature, 393 (1998) 49−52.

[8] M. S. Fuhrer, J. Nygard, L. Shih, M. Forero, Y. G. Yoon, M. S. C. Mazzoni, H. J. Choi, J. Ihm, S. G. Louie, A. Zettl, and P. L. McEuen, “Crossed nanotube junctions”, Science, 288 (2000) 494−497.

[9] P. G. Collins, M. S. Arnold, P. Avouris, “Engineering carbon nanotubes and nanotube circuits using electrical breakdown”, Science, 292 (2001)

[10] Z. W. Pan, Z. R. Dai, and Z. L. Wang, “Nanobelts of semiconducting oxides”, Science, 209 (2001) 1947−1949.

[11] Z. R. Dai, Z. W. Pan, and Z. L. Wang, “Novel nanostructures of functional oxides synthesized by thermal evaporation”, Advanced Functional Materials, 13 (2003) 9−24.

[12] X. Y. Kong and Z. L. Wang, “Spontaneous polarization-induced nanohelixes, nanosprings, and nanorings of piezoelectric nanobelts”, Nano Letters, 3 (2003) 1625−1631.

[13] R. H. Fowler and L. Nordheim, “Electron emission in intense electric field”, Proceedings of the Royal Society of London Series A, 119 (1928) 173−181.

[14] C. A. Spindt, “A thin-film field-emission cathode”, Journal of Applied Physics, 39 (1968) 3504−3505.

[15] http://www.action.com.tw/tech/lcd/fed

[16] Y. J. Chen, Q. H. Li, Y. X. Liang, T. H. Wang, Q. Zhao, and D. P. Yu,

“Field-emission from long SnO nanobelt arrays”, Applied Physics Letters, 85 (2004) 5682−5685.

[17] T. Yamashita, S. Hasegawa, S. Nishida, M. Ishimaru, Y. Hirotsu, and H.

Asahi, “Electron field emission from GaN nanorod films grown on Si substrates with native silicon oxides”, Applied Physics Letters, 86 (2005) 082109−082110.

[18] Z. Pan, H.L. Lai, F. C. K. Au, X. Duan, W. Zhou, W. Shi, N. Wang, C. S.

Lee, N. B. Wong, S. T. Lee, and S. Xie, “Oriented Silicon Carbide Nanowires: Synthesis and Field Emission Properties”, Advanced Materials,

“Electron field emission from silicon nanowires”, Applied Physics Letters, 75 (1999) 1700−1703.

[20] S. Iijima, “Helical microtubules of graphitic carbon,” Nature, 354 (1991) 56−58.

[21] S. Iijima and T. Ichihashi, “Single-shell carbon nanotubes of 1-nm diameter”, Nature, 363 (1993) 603−605.

[22] R. Saito, G. Dresselhaus, and M. S. Dresselhaus, “Physical properties of carbon nanotubes”, Imperial College Press, 1998.

[23] Q. Cui, Y. Huang, and Z. Zhu, “Synthesis and field emission of novel ZnO nanorod chains”, Current Applied Physics, 9 (2009) 426−430.

[24] Q. Wan, K. Yu, T. H. Wang, and C. L. Lin, “Low-field electron emission from tetrapod-like ZnO nanostructures synthesized by rapid evaporation”, Applied Physics Letters, 83 (2003) 2253−2256.

[25] Y. W. Zhu, H. Z. Zhang, X. C. Sun, S. Q. Feng, J. Xu, and Q. Zhao,

“Efficient field emission from ZnO nanoneedle arrays”, Applied Physics Letters, 83 (2003) 144−147.

[26] S. H. Jo, J. Y. Lao, Z. F. Ren, R. A. Farrer, T. Baldacchini, and J. T. Fourkas,

“Field-emission studies on thin films of zinc oxide nanowires”, Applied Physics Letters, 83 (2003) 4821−4823.

[27] Q. H. Li, Q. Wan, Y. J. Chen, T. H. Wang, H. B. Jia, and D. P. Yu, “Stable field emission from tetrapod-like ZnO nanostructures” Applied Physics Letters, 85 (2004) 636−639.

[28] R. C. Wang, C. P. Liu, J. L. Huang, S. J. Chen, Y. K. Tseng, and S. C. Kung,

“ZnO nanopencils: Efficient field emitters”, Applied Physics Letters, 87

[29] K. B. Zheng, H. T. Shen, J. L. Li, D. L. Sun, G. R. Chen, K. Hou, C. Li, and W. Lei, “The fabrication and properties of field emission display based on ZnO tetrapod-liked nanostructure”, Vacuum, 83 (2009) 261−264.

[30] J. I. Pankove, “Optical Progress in Semiconductors”, Dover, New York, 1975.

[31] Z. L. Wang, “ZnO nanowire and nanobelt platform for nanotechnology”, Materials Science and Engineering R, 64 (2009) 33−71.

[32] D. Bao, H. Gu, and A. Kuang, “Sol-gel-derived c-axis oriented ZnO thin films”, Thin Solid Films, 312 (1998) 37−39.

[33] F. D. Paraguay, J. Morales, W. L. Estrada, E. Andrade, and M. M. Yoshida,

“Influence of Al, In, Cu, Fe and Sn dopants in the microstructure of zinc oxide thin films obtained by spray pyrolysis”, Thin Solid Films, 366 (2000) 16−27.

[34] R. Wang, L. H. King, and A. Wang, “Highly conducting transparent thin films based on zinc oxide”, Journal of Materials Research, 11 (1996) 1659−1664.

[35] J. Jagadish and S. J. Pearton, “Zinc Oxide Bulk”, Thin Film and Nanostructures, Elsevier, 2006.

[36] R. Alexandrescu, A. Crunteanu, R. E. Morjan, I. Morjan, F. Rohmund, L. K.

L. Falk, G. Ledoux, and F. Huisken, “Synthesis of carbon nanotubes by CO2-laser-assisted chemical vapour deposition”, Infrared Physics and Technology, 44 (2003) 43−50.

[37] D. P. Yu, Z. G. Bai, Y. Ding, Q. L. Hang, H. Z. Zhang, J. J. Wang, Y.H. Zou,

(1998) 3458−3461.

[38] P. Yang, “The chemistry and physics of semiconductor nanowires”, Mrs Bulletin, 30 (2005) 85−91.

[39] Y. F. Zhang, Y. H. Zhang, N. Wang, D. P. Yu, C. S. Lee, I. Bello, and S. T.

Lee, “Silicon nanowires prepared by laser ablation at high temperature”, Applied Physics Letters, 72 (1998) 1835−1838.

[40] N. Wang, Y. F. Zhang, Y. H. Tang, C. S. Lee, and S. T. Lee,

“SiO2-enhanced synthesis of Si nanowires by laser ablation”, Applied Physics Letters, 73 (1998) 3902−3905.

[41] S. D. Hutagalung, K. A. Yaacob, and A. F. A. Aziz, “Oxide-assisted growth of silicon nanowires by carbothermal evaporation”, Applied Surface Science, 254 (2007) 633−637.

[42] Z. W. Pen, Z. R. Dai, and Z. L. Wang, “Nanobelts of semiconducting oxides”, Science, 291 (2001) 1947−1949.

[43] C. J. Lee and J. Park, “Growth model of bamboo-shaped carbon nanotubes by thermal chemical vapor deposition”, Applied Physics Letters, 77 (2000) 3397−3400.

[44] Z. Y. Juang, J. F. Lai, C. H. Weng, J. H. Lee, H. J. Lai, T. S. Lai, and C. H.

Tsai, “On the kinetics of carbon nanotube growth by thermal CVD method”, Diamond and Related Materials, 13 (2004) 2140−2146.

[45] M. P. Siegal, D. L. Overmyer, and P. P. Provencio, “Precise control of multiwall carbon nanotube diameters using thermal chemical vapor deposition”, Applied Physics Letters, 80 (2002) 2171−2174.

[46] S. Porro, S. Musso, M. Vinante, L. Vanzetti, M. Anderle, F. Trotta, and A.

Physica E: Low-dimensional Systems and Nanostructures, 37 (2007) 58−61.

[47] T. D. Makris, L. Giorgi, R. Giorgi, N. Lisi, and E. Salernitano, “CNT growth on alumina supported nickel catalyst by thermal CVD”, Diamond and Related Materials, 14 (2005) 815−819.

[48] Z. H. Wu, X.U. Mei, D. Kim, M. Blumin, and H. E. Ruda, “Growth of Au-catalyzed ordered GaAs nanowire arrays by molecular-beam epitaxy”, Applied Physics Letters, 81 (2002) 5177−5180.

[49] Y. F. Chan, X. F. Duan, S. K. Chan, I. K. Sou, X. X. Zhang, and N. Wang,

“ZnSe nanowires epitaxially grown on GaP (111) substrates by molecular-beam epitaxy”, Applied Physics Letters, 83 (2003) 2665−2668.

[50] L. Schubert, P. Werner, N. D. Zakharov, G. Gerth, F. M. Kolb, L. Long, and U. Gosele, “Silicon nanowhiskers grown on (111) Si substrates by molecular-beam epitaxy ”, Applied Physics Letters, 84 (2004) 4968−4970.

[51] M. T. Bjork, B. J. Ohlsson, T. Sass, A. I. Persson, C. Thelander, M. H.

Magnusson, K. Deppert, L. R. Wallenberg, and L. Samuelson,

“One-dimensional heterostructures in semiconductor nanowhiskers”, Applied Physics Letters, 80 (2002) 1058−1060.

[52] D. Polsongkram, P. Chamninok, S. Pukird, L. Chow, O. Lupan, G. Chai, H.

Khallaf, S. Park, and A. Schulte, “Effect of synthesis conditions on the growth of ZnO nanorods via hydrothermal method”, Physical B, 403 (2008) 3713−3717.

[53] S. Dalui, S. N. Das, R. K. Roy, R. N. Gayen, and A. K. Pal, “Aligned Zinc Oxide nanorods by hybrid wet chemical route and their field emission

[54] M. Eskandari, V. Ahmadi, and S. H. Ahmadi, “Low temperature synthesis of ZnO nanorods by using PVP and their characterization”, Physical B, 404 (2009) 1924−1928.

[55] S. R. Hejazi, H. R. M. Hosseini, and M. S. Ghamsari, “The role of reactants and droplet interfaces on nucleation and growth of ZnO nanorods synthesized by vapor-liquid-solid (VLS) mechanism”, Journal of Alloys and Compounds, 455 (2008) 353−357.

[56] O. Gunawan and S. Guha, “Characteristics of vapor–liquid–solid grown silicon nanowire solar cells”, Solar Energy Materials and Solar Cells, 93 (2009) 1388−1393.

[57] X. D. Wang, J. H. Song, and Z. L. Wang, “Single-crystal nanocastles of ZnO”, Chemical Physics Letters, 424 (2006) 86−90.

[58] G. Cao, “Nanostructures and nanomaterials: synthesis, properties, and application”, Imperial College Press, 1st edition 2004.

[59] W. J. Li, E. W. Shi, W. Z. Zhong, and Z. W. Yin, “Growth mechanism and growth habit of oxide crystals”, Journal of Crystal Growth, 203 (1999) 186−196.

[60] A. Sugunan, H. C. Warad, M. Boman, and J. Dutta, “Zinc oxide nanowires in chemical bath on seeded substrates: Role of hexamine”, Journal of Sol-gel

Science and Technology, 39 (2006) 49−56.

[61] R. S. Wagner and W. C. Ellis, “Vapor-Liquid-Solid mechanism of single crystal growth”, Applied Physics Letters, 4 (1964) 89−91.

[62] N. Wang, Y. Cai, and R.Q. Zhang, “Growth of nanowires”, Materials Science and Engineering R, 60 (2008) 1−51.

[63] M. H. Huang, S. Mao, H. Feick, H. Q. Yan, Y. Y. Wu, H. Kind, E. Weber, R.

Russo, and P. D. Yang, “Room-temperature ultraviolet nanowire nanolasers”, Science, 292 (2001) 1897−1899.

[64] J. E. Field, “The Properties of Diamonds”, Academic, London, 1979.

[65] Q. Wang, Z. L. Wang, J. J. Li, Y. Huang, Y. L. Li, and C. Z. Gu, “Field electron emission from individual diamond cone formed by plasma etching”, Applied Physics Letters, 89 (2006) 063105−063106.

[66] Y. S. Zou, K. L. Ma, W. J. Zhang, Q. Ye, Z. Q. Yao, Y. M. Chong, and S. T.

Lee, “Fabrication of diamond nanocones and nanowhiskers by bias-assisted plasma etching”, Diamond and Related Materials, 16 (2007) 1208−1212.

[67] W. Y. Sung, W. J. Kim, S. M. Lee, H. Y. Lee, Y. H. Kim, K. H. Park, and S.

Lee, “Field emission characteristics of CuO nanowires by hydrogen plasma treatment”, Vacuum, 81 (2007) 851−856.

[68] Y. Z. Hu, R. Sharangpani, and S. P. Tay, “In situ rapid thermal oxidation and reduction of copper thin films and their application in ultralarge scale integration”, Journal of The Electrochem Society, 148 (2001) G669−G675.

[69] T. C. Cheng, J. Shieh, W. J. Huang, M. C. Yang, M. H. Cheng, H. M. Lin, and M. N. Chang, “Hydrogen plasma dry etching method for field emission application”, Applied Physics Letters, 88 (2006) 263118-1−263118-3.

[70] J. M. Lee, K. K. Kim, S. J. Park, and W. K. Choi, “Low-resistance and nonalloyed ohmic contacts to plasma treated ZnO”, Applied Physics Letters, 78 (2001) 3842−3844.

[71] Y. F. Tzeng, Y. C. Lee, C. Y. Lee, H. T. Chiu, and I. N. Lin, “Electron field

[72] Y. H. Yang, C. X. Wang, B. Wang, N. S. Xu, and G. W. Yang, “ZnO nanowire and amorphous diamond nanocomposites and field emission enhancement”, Chemical Physics Letters, 403 (2005) 248−251.

[73] Powder Diffraction File, Joint Committee on Powder Diffraction Standards, ICDD, Swarthmore, PA, 1996, Card 36−1451 (ZnO).

[74] C. Bundesmann, N. Ashkenov, M. Schubert, D. Spemann, T. Butz, E.M.

Kaidashev, M. Lorenz, and M. Grundmann, “Raman scattering in ZnO thin films doped with Fe, Sb, Al, Ga, and Li”, Applied Physics Letters, 83 (2003) 1974−1977.

[75] C. A. Arguello, D. L. Rousseau, and S. P. S. Porto, “First-order Raman effect in wurtzite-type crystals”, Physical Review, 181 (1969) 1351-1363.

[76] T.C. Damen, S.P.S. Porto, B. Tell, “Raman effect in zinc oxide”, Physical Review, 142 (1966) 570−574.

[77] Y. J. Xing, Z. H. Xi, Z. Q. Xue, X. D. Zhang, J. H. Song, R. M. Wang, J. Xu, Y. Song, S. L. Zhang, and D.P. Yu, “Optical properties of the ZnO nanotubes synthesized via vapor phase growth”, Applied Physics Letters, 83 (2003) 1689−1692.

[78] Y. Wang, X. Li, N. Wang, X. Quan, and Y. Chen, “Controllable synthesis of ZnO nanoflowers and their morphology-dependent photocatalytic activities”, Separation and Purification Technology, 62 (2008) 727−732.

[79] J. T. Chen, J. Wang, R. F. Zhuo, D. Yan, J. J. Feng, F. Zhang, and P. X. Yan,

“The effect of Al doping on the morphology and optical property of ZnO nanostructures prepared by hydrothermal process”, Applied Surface Science, 255 (2009) 3959−3964.

M. Gao, “Growth mechanism and optical properties of ZnO nanotube by the hydrothermal method on Si substrates”, Journal of Alloys and Compounds, 475 (2009) 741−744.

[81] P. Zhao, Y. B. Xia, L. J. Wang, J. M. Liu, R. Xu, H. Y. Peng, and W. M. Shi,

“Performance improvement of ZnO film by room-temperature oxygen plasma pretreatment”, Transactions of Nonferrous Metals Society of China, 16 (2006) s310−s312.

[82] H. S. Uh, S. W. Ko, and K. D. Lee, “Growth and field emission properties of carbon nanotubes on rapid thermal annealed Ni catalyst using PECVD”, Diamond and Related Materials, 14 (2005) 850−854.

[83] D. Pradhan, Y. C. Lee, C. W. Pao, W. F. Pong, and I. N. Lin, “Low temperature growth of ultrananocrystalline diamond film and its field emission properties”, Diamond and Related Materials, 15 (2006) 2001−2005.

[84] F. A. M. Koeck, M. Zumer, V. Nemanic, and R. J. Nemanich, “Photo and field electron emission microscopy, from sulfur doped nanocrystalline diamond films”, Diamond and Related Materials, 15 (2006) 880−883.

[85] F. A. M. Kock, J. M. Garguilo, and R. J. Nemanich, “Direct correlation of surface morphology with electron emission sites for intrinsic nanocrystalline diamond films”, Diamond and Related Materials, 13 (2004) 1022−1025.

[86] J. Chen, W. Lei, W. Q. Chai, Z. C. Zhang, C. Li, and X. B. Zhang, “High field emission enhancement of ZnO-nanorods via hydrothermal synthesis”, Solid-State Electronics, 52 (2008) 294−298.

86 (2009) 1159−1161.

[88] Powder Diffraction File, Joint Committee on Powder Diffraction Standards, ICDD, Swarthmore, PA, 1996, Card 65−2870 (Gold).

[89] http://www.creatingpnanotech/technology2.html

[90] C. C. Lin, H. P. Chen, H. C. Liao, and S. Y. Chen, “Enhanced luminescent and electrical properties of hydrogen-plasma ZnO nanorods grown on wafer-scale flexible substrates”, Applied Physics Letters, 86 (2005) 183103−183104.