本次實驗成功運用氣相層析儀分離技術結合微哨偵測器和自動 進樣裝置進行氫氣即時監測，有效地分離出混合氣體中的氫氣，數據 分析後可得到氫氣總生成量並進行其生成速率與防鏽程度的探討，實 驗經由 30 ℃、40 ℃和 50 ℃鏽化反應可得 50 ℃下飽和沒食子酸洗下 氫氣生成速率最快、防銹效果較優且耗時最短，此研究方法有利於爾 後進行其他配方的測量和防鏽探討！以提供一個既簡單又快速的分 析技術來尋找較佳的酸洗配方。
此新型自動化氣體偵測器使用上方便簡易，待測物不需要複雜的 前處理過程，而微哨偵測器也具備近乎無耗損、無殘留、環保可多次 重複使用的優點，樣品更不僅僅是這次實驗所測量的氫氣氣體，只要 是待測氣體具有相對應的分離管柱即可進行複雜樣品的分離與測 量！
未來發展方面，本實驗室也正著手開發微型化攜帶式微哨偵測器，
如圖 5-1 所示，希望能成為有效且簡易的氣體感測器。
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圖 5-1 攜帶型微行氣哨偵測器實際圖
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研討會發表
參與會議：第二十三屆台灣化學感測器科技研討會 會議時間：中華民國 107 年 6 月 2 日
主辦單位：國立臺灣師範大學理學院 科技與工程學院 生命科學 專業學院 光電科技研究所/化學系、社團法人台灣化學感測器科 技協會、社團法人中華民國微系統暨奈米科技協會
題目：利用氣相層析/微哨偵測系統同步監測鐵在酸洗防鏽處理
過程中產生的氫氣濃度變化並探討其反應速率對防鏽程度的影響
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參考資料
[1] Michael J.Hynes, Máirtı́nÓ Coinceanainn, Journal of Inorganic Biochemistry.
2001, 85(2-3), 131-142
[2] Li-li Lu, Ying-hua, Li, Xiu-yang Lu, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2009, 74(3), 829-834
[3] Isara Phiwchal, Wiphawee Yuensook, Natsaree Sawaengsiriphon, Saowalak Krungchanuchat, Chalermchai Pilapong, European Journal of Pharmaceutical Sciences. 2018, 114, 64-73
[4] Lokesh K.N., Channarayappa, Marikunte Venkataranganna, Gunti Gowtham Raj, Hansraj Patil, Hardik Davec, Journal of Trace Elements in Medicine and Biology. 2018, 45, 114-124
[5] Elisa June Teresa McGee, Levente László Diosady, LWT. 2018, 89, 756-762 [6] Mamdouh S. Masoud, Alaa E. Ali, Sawsan S. Haggag, Nessma M. Nasr,
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.
2014, 120, 505-511
[7] Abdelatty Mohamed Radalla, ScienceDirect. 2015, 4(2), 174-182
[8] Huiyu Dong, Carme Sans, Wentao Li, Zhimin Qiang, Separation and Purification Technology. 2016, 171, 144-150
[9] Dries Knockaert, Katleen Raes, Karin Struijs, Christophe Wille, John Van Camp, LWT. 2014, 55, 335-340
[10] Wentworth GR1, Al-Abadleh HA, Phys Chem Chem Phys. 2011, 13(14), 6507-16
[11] Pruncu CI, Azari Z, Casavola C, Pappalettere C, Int Sch Res Notices. 2015, 2015, 594147
[12] Rouchon V, Duranton M, Burgaud C, Pellizzi E, Lavédrine B, Janssens K, de Nolf W, Nuyts G, Vanmeert F, Hellemans K, Anal Chem. 2011, 83(7), 2589-97
[13] Lopes GK, Schulman HM, Hermes-Lima M, Biochim Biophys Acta. 1999, 1472(1-2), 142-52
[14] Singh K, Kumar A, Food Chem. 2018, 265, 96-100
[15] Cherepanov PV, Rahim MA, Bertleff-Zieschang N, Sayeed MA, O'Mullane AP, Moulton SE, Caruso F, ACS Appl Mater Interfaces. 2018, 10(6), 5828-5834
[16] Mu X, Yan C, Tian Q, Lin J, Yang S, Int J Nanomedicine. 2017, 12, 7207-7223
[17] Quici N, Litter MI, Photochem Photobiol Sc. 2009, 8(7), 975-84
54
[18] Masoud MS, Ali AE, Haggag SS, Nasr NM, Spectrochim Acta A Mol Biomol Spectrosc. 2014, 120, 505-11
[19] Yang S, Bai G, Chen L, Shen Q, Diao X, Zhao G, Food Chem. 2014, 157, 302-9
[20] Nkhili E, Loonis M, Mihai S, El Hajji H, Dangles O, Food Funct. 5(6), 1186-202
[21] Zeng J, Cheng M, Wang Y, Wen L, Chen L, Li Z, Wu Y, Gao M, Chai Z, Adv Healthc Mater. 2016, 5(7), 772-80
[22] Mahajan A, Swarnalatha R, Sherwani K, Kumar N, J Med Eng Techno. 43(1), 48-54
[23] Eichhorn S, Reisinger T, Böhm J3,4, Voss S, Doppler S, Lange R, Krane M, Australas Phys Eng Sci Med. 42(2), 611-617
[24] Xu Y, Tan Z, Luo Y, Zhongguo Yi Liao Qi Xie Za Zhi. 42(6)431-433
[25] Zhou H, Yang D, Qiu X, Wu X, Li Y, Appl Microbiol Biotechnol. 97(24), 10309-20
[26] Dussadee N, Reansuwan K, Ramaraj R, Bioresour Technol. 2014, 155,438-41 [27] Ben Hsouna A, Ben Halima N, Smaoui S, Hamdi N, Lipids Health Dis. 2017,
16(1),46
[28] Zareei L, Divband B, Mesbahi A, Khatamian M, Kiani A, Gharehaghaji N, J Biomed Phys Eng. 2019, 9(2), 211-216
[29] Kiskira K, Papirio S, Mascolo MC, Fourdrin C, Pechaud Y, van Hullebusch ED, Esposito G, i Total Environ. 2019, 8687, 401-412
[30] Ravines P, Nazarenko AY, Microsc Microanal. 1-15
[31] Amaral MSS, Marriott PJ, Bizzo HR, Rezende CM, Anal Bioanal Chem. 2018, 410(19), 4615-4632
[32] Min Cheng, Guangming Zeng, Danlian Huang, Cui Lai, Yang Liu, Chen Zhang, Rongzhong Wang, Lei Qin, Wenjing Xue, Biao Song, Shujing Ye, Huan Yi, Journal of colloid and sciencr. 2018, vol515, 232-239
[33] Y.Chen, X.H.Chen, Y.W.Liu, Z.N.Yang, Z.Zhang, Journal of Chimical thermodynamics. 2018, vol126, 147-159
[34] Montgomery JM, Lipp MJ, Rev Sci Instrum. 2019, 90(2), 023903
[35] Barbesi D, Vicente Vilas V, Millet S, Sandow M, Colle JY, Aldave de Las Heras L, J Radioanal Nucl Chem. 2017, 313(1), 217-227
[36] Tovar G, Biochem Mol Biol Educ. 2018, 46(1), 39-46
[37] Acri G, Testagrossa B, Sestito A, Bonanno L, Vermiglio G, Z Med Phys.
2018, 28(1), 6-13
[38] Vincenzo Aquilanti, Nayara Dantas Coutinho, and Valter Henrique Carvalho-Silva, Philos Trans A Math Phys Eng Sci. 2017, 375(2092)
55
[39] Golda RL, Golda MD, Peterson TD, Needoba JA, Data Brief. 2017, 12, 463-470
[40] Ovejero MC, Pérez Vega-Leal A, Gallardo MI, Espino JM, Selva A, Cortés-Giraldo MA, Arráns R, Rev Sci Instrum. 2017, 88(2), 025104
[41] Barabas FM1, Masullo LA1, Stefani FD1, Rev Sci Instrum. 2016, 87(12), 126103
[42] González I, Calderón AJ, Mejías A, Andújar JM, Sensors (Basel). 2016, 16(11)
[43] Sfakis L1, Kamaldinov T1, Larsen M2, Castracane J1, Khmaladze A3, Tissue Eng Part C Methods. 2016, 22(11), 1028-1037
[44] Guzel Aydin S, Kaya T, Guler H, Brain Inform. 2016, 3(2), 109-117 [45] Cui Y, Hanley L, Rev Sci Instrum. 2015, 86(6), 065106
[46] C. -H.; He, Y. -S.; Lin, C. -H.; Fan, G. -T.; Chen, H. -K., Anal. Sci. 2014, 30,
[51] Z. Xu et al.; Agriculture, Ecosystems and Environment. 2006, 115, 105–112 [52] Baskin, C.; C., Baskin, J.M., Academic Press, New York. 1998..
[53] Taiz, L.; Zeiger,E., PlantPhysiology.MA:bySinauerAssociates,Inc.1998 [54] S. Luo et al., Scientia Horticulturae. 2017, 221, 73–82
[55] Costa, M.L.; Civello, P.M.; Chaves, A.R., Martinez, G.A. 2005. E
[56] Doehlert, D.C.; Kuo, T.M.; Felker, F.C., Plant Physiol. 1988, 86, 1013–1019 [57] Donald Voet; Judith G. Voet, Biochemistry 4th Edition. 2010, p.797~p.831 [58] LatiesG.G., AnnRevPlantPhysiol.1982
[59] Donald Voet; Judith G. Voet, Biochemistry 4th Edition. 2010, p.798
[60] Delele, M.A.; Nicolai, B.M. Storage of respiratory produce. 2015, European patent.
[61] Telugu Academi, Botany text book. 2007, p.226~p.274
[62] Taiz, L.; Zeiger,E.,PlantPhysiology.MA:bySinauerAssociates,Inc.1998 [63] Bain, J. M.; Mercer, F. V. , L. Aust. J. Biol. Sci.1966, 19, 69-84.
[64] Gasser, F.; Eppler, T.; Naunheim, W.; Gabioud, S.; Hoehn, E., Acta Hortic.
2008, 796, 69–76.
[65] Bergholz, K.; Jeltsch, F.; Weiss, L.; Pottek, J.; Geißler, K.; Ristow, M., Oikos.
2015, 124, 1547–1554.
[66] Bilir, N.; Prescher, F.; Lindgren, D.; Kroon, J., New For.2008, 36, 187–199
56
[67] Bladé, C., Vallejo, V.R., 2008. Seed mass effects on performance of Pinus halepensis
[68] Mill. For. Ecol. Manage. 2007 255, 2362–2372.
[69] Atherton, J. G. ; Farooque, A. M., Plant. Physiol.1983, 79, 49-67.
[70] Y. Xu et al., Chemical Engineering Journal. 2016, 299201–208
[71] D. M.; Dresch et al., American Journal of Plant Sciences. 2014, 5, 2555-2565 [72] D. Jimenez-Cordero; F. Heras; N. Alonso-Morales; M.A. Gilarranz, J.J.
Rodriguez, Biomass Bioenergy. 2013, 299, 123–132.
[73] Sharma SK. Indian J Plant Physiol. 1997, 2, 171–3.
[74] Kenneth Connors, Chemical Kinetics. 1990, VCH Publishers
[75] I. Kranner; L. Colville, Environmental and Experimental Botany. 2011, 72 ,93–105
[76] M. Nishiyama et al., Chemical Physics Letters. 2009, 482, 332–336 [77] M. Nishiyama et al., Chemical Physics Letters. 2009, 482, 352–329 [78] V. Aquilanti et al., Chemical Physics Letters. 2010, 498, 209–213 [79] Kang, -H.; Lee, W. -S.,J Plant Bio. 2001 , 44(3), 131-140
[80] Zeng, Q. -L.; Zhou, Q., Journal of Environment Science. 2004, 23, 1073-1076 [81]