1. 原水濁度越高,其pH、鹼度與導電度有下降的趨勢,且濁度升高 則其顆粒表面ζ值會降低。
2. 最適加藥量大多發生在快混後顆粒ζ值偏正的劑量,而此時的ζ值依 原水水質及顆粒特性的狀況不同,因此有所差異,但大略落在2~6 mV之間,此時的混凝機制以沉澱掃除為主;一般濁度原水之快混 後pH以接近中性偏鹼時的混凝效果最好,混凝機制同樣依靠沉澱 掃除。
3. 原水參數當中以鹼度影響最適加藥量最為明顯。在原水低濁度時,
最適加藥量與原水鹼度呈現正相關;在原水高濁度時,最適加藥 量與鹼度呈現負相關。
第六章 建議
因最適加藥量與天然原水鹼度的相關性不低,所以可嘗試配製濁度 相同,但控制鹼度條件的人工原水來進行試驗,進一步探討最適加藥 量與鹼度的相關性。
參考文獻
Annadurai,G., Sung, S.S. and Lee, D.J (2004) “Simultaneous removal of turbidity and humic acid from high turbidity stormwater” Advances in Environmental Research, 8, 713-725.
Chen, Z., Luan, Z., Jia, Z. and Li, X. (2009) “Study on the hydrolysis/precipitation behavior of Keggin Al13 and Al30 polymers in polyaluminum solutions” Journal of Environmental Management, 90, 2831-2840.
Duan, J. and Gregory, J. (2003) “Coagulation by hydrolysing metal salts” Advances in Colloid and Interface Science, 100-102, 475–502.
Gao, B.Y., Yue, Q.Y., Wang, B.J. and Chu, Y.B. (2003)“Poly-aluminum-silicate -chloride (PASiC)-a new type of composite inorganic polymer coagulant” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 229, 121-127.
Gao, B.Y., Chu, Y.B., Yue, Q.Y., Wang, B.J. and Wang, S.G. (2005) “Characteri- zation and coagulation of a polyaluminum chloride (PAC) coagulant with high Al13
content” Journal of Environmental Management, 76, 143-147.
Gao, B., Chu, Y., Yue, Q. and Wang, Y. (2009) “Purification and characterization of Al13 species in coagulant polyaluminum chloride” Journal of Environmental Sciences, 21, 18-22.
Hsu, B.M. and Huang, C. P. (2001) “Influence of ionic strength and pH on hydrophobicity and zeta potential of Giardia and Cryptosporidium” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 201, 201-206.
Hu, C., Liu, H. and Qu, J. (2005) “Preparation and characterization of polyaluminum chloride containing high content of Al13 and active chlorine ” Colloids and Surfaces A:
Physicochemical and Engineering Aspects, 260, 109-117.
Hu, C., Liu, H., Qu, J., Wang, D. and Ru, J. (2006) “Coagulation Behavior of Aluminum Salts in Eutrophic Water:Significance of Al13 Species and pH Control”
Environmental Science & Technology, 40, 325-331.
Kretzschmar, R., Holthoff, H. and Sticher, H. (1998) “Influence of pH and Humic Acid on Coagulation Kinetics of Kaolinite: A Dynamic Light Scattering Study”
Journal of Colloid and Interface Science, 202, 95-103
Lee, S.J., Lee, Y.J. and Nam, S.H. (2008) “Improvement in the coagulation perfor- mance by combining Al and Fe coagulants in water purification” Korean Journal of Chemical Engineering, 25(3), 505-512
Lin, J.R., Chin, C. J., Huang, C. P., Pan, J. R. and Wang, D. (2008) “Coagulation behavior of Al13 aggregates” Water Research, 42, 4281-4290.
Lin, J. R., Huang, C. P., Pan, J. R. and Wang, D. (2008) “Effect of Al(III) speciation on coagulation of highly turbid water” Chemosphere, 72, 189-196.
Morfesis, A., Jacobson, A. M., Frollini, R., Helgeson, M., Billica, J. and Gertig, K. R.
(2009) “Role of Zeta (ζ) Potential in the Optimization of Water Treatment Facility Operations” Industrial& Engineering Chemistry Research, 48, 2305-2308.
Sansalone, J.J. and Kim, J.Y. (2008) “Zeta potential of clay-size particles in urban rainfall–runoff during hydrologic transport” Journal of Hydrology, 356, 163-173.
Sansalone, J.J. and Kim, J.Y. (2008) “Suspended particle destabilization in retained urban stormwater as a function of coagulant dosage and redox conditions” Water Research, 42, 909-922.
Wang, D., Sun W., Xu.Y., Tang, H. and Gregory, J. (2004)“Speciation stability of inorganic polymer flocculant-PACl” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 243, 1-10.
Wang, D. and Tang, H. (2006)“Quantitative model of coagulation with inorganic polymer flocculant PACI : Application of the PCNM”. Journal of Environmental Engineering., 132, 434-441.
Wu, X., Ge, X., Wang, D. and Tang, H. (2007) “Coagulation of silica microspheres with hydrolyzed Al(III)-Significance of Al13 and Al13 aggregates” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 330, 72-79.
Wu, X., Wang, D., Ge, X. and Tang, H. (2008) “Distinct coagulation mechanism and
model between alum and high Al13-PACl” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 305, 89-96.
Wu, X., Ge, X., Wang, D. and Tang, H. (2009) “Distinct mechanisms of particle aggregation induced by alum and PACl: Floc structure and DLVO evaluation”
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 347, 56-63.
Xiao, F., Ma, J., Yi, P. and Huang, H. J. C. (2008) “Effects of low temperature on coagulation of kaolinite suspensions” Water Research, 42, 2983-2992.
Xiao, F., Zhang, X. and Lee, C. (2008) “Is electrophoretic mobility determination meaningful for aluminum(III) coagulation of kaolinite suspension?” Journal of Colloid and Interface Science, 327, 348-353.
Ye, C., Wang, D., Shi, B., Yu, J., Qu, J., Edwards, M. and Tang, H. (2007)
“Alkalinity effect of coagulation with polyaluminum chlorides:Role of electrostatic patch ” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 294, 163-173.
Yan, M., Wang, D., Qu, J., He, W. and Chow, C. (2007) “Relative importance of hydrolyzed Al(III) species (Ala, Alb, and Alc) during coagulation with polyaluminum chloride: A case study with the typical micro-polluted source waters” Journal of Colloid and Interface Science, 316, 482-489.
Yan, M., Wang, D., Yu, J., Ni, J., Edwards, M. and Qu, J. (2008) “Enhanced coagulation with polyaluminum chlorides:Role of pH/Alkalinity and speciation”
Chemosphere, 71, 1665-1673.
李坤峰 (2000) “飲用水處理程序二階段添加PAC與污泥毯穩定度提昇之研
碩士論文。
陳韋弘 (2005) “混凝劑 Al 型態對高濁水混凝行為之影響”,國立交通大學環境 工程研究所碩士論文。
莊竣皓 (2007) “淡水河流域鹼度、酸鹼值與主要離子之時空變化”,國立中央大 學水文科學研究所碩士論文。
劉奕甫 (2007) “低濁原水處理策略評估:實驗室及現場診斷”,國立交通大學環 境工程研究所碩士論文。
陳曼莉 (2008) “自來水設施維護管理指南 第七篇 淨水設施”,中華民國自來水 協會技術報告。
黃志彬、袁如馨 (2007) “高純度 Al13混凝劑之混凝特性及製備研究”,台灣自來 水公司研究報告十月。
黃志彬 (2008) “水公司淨水場低濁度難處理原水處理最適化之研究”,台灣自來 水公司研究報告七月。