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附圖 1. VC91BP的¹H-NMR光譜圖

附圖 3. D2Si1BA的¹H-NMR光譜圖

附圖 5. D2Si2BP的¹H-NMR光譜圖

附圖 7. D2Si2BA的¹³C-NMR光譜圖

附圖 9. D3Si1BA的¹H-NMR光譜圖

附圖 11. NPP的¹H-NMR光譜圖

附圖 13. D3SiNPP的¹H-NMR光譜圖

附圖 14. D3SiNPA的¹H-NMR光譜圖

附圖 15. D3SiNPA的¹³C-NMR光譜圖

附圖 17. VC9BPP的¹H-NMR光譜圖

附圖 19. D3SiBPA的¹H-NMR光譜圖

附圖 21. D2Si1BA 的 DSC 圖譜

附圖 23. D3Si1BA 的 DSC 圖譜

附圖 24. D3SiNPA 的 DSC 圖譜

附圖 25. D3SiBPA 的 DSC 圖譜

附圖 26. I-D2Si1BA 的 DSC 圖譜

附圖 27. II-D2Si1BA 的 DSC 圖譜

附圖 28. III-D2Si1BA 的 DSC 圖譜

附圖 29. V-D2Si1BA 的 DSC 圖譜

附圖 30. I-D2Si2BA 的 DSC 圖譜

附圖 31. II-D2Si2BA 的 DSC 圖譜

附圖 32. III-D2Si2BA 的 DSC 圖譜

附圖 33. V-D2Si2BA 的 DSC 圖譜

附圖 34. I-D3Si1BA 的 DSC 圖譜

附圖 35. II-D3Si1BA 的 DSC 圖譜

附圖 36. III-D3Si1BA 的 DSC 圖譜

附圖 37. V-D3Si1BA 的 DSC 圖譜

附圖 38. I-D3SiNPA 的 DSC 圖譜

附圖 39. II-D3SiNPA 的 DSC 圖譜

附圖 40. III-D3SiNPA 的 DSC 圖譜

附圖 41. V-D3SiNPA 的 DSC 圖譜

附圖 42. I-D3SiBPA 的 DSC 圖譜

附圖 43. II-D3SiBPA 的 DSC 圖譜

附圖 45. V-D3SiBPA 的 DSC 圖譜

200 400 600

100 D2Si1BA 347.86^oC

Weight(%)

Temperature(^OC)

100 200 300 400 500 600

0

Temperature(^OC)

100 200 300 400 500 600

0 20 40 60 80

100 D2Si2BA 391.53^oC

Weight(%)

Temperature(^OC)

100 200 300 400 500 600 700

0

D3SiNPA 380.13(^OC)

Weight(%)

Temperature(^OC)

100 200 300 400 500 600 700

0

D3SiBPA 404.14(^OC)

Weight(%)

Temperature(^OC)

附圖 46. D2Si1BA、D2Si2BA、D3Si1BA、D3SiNPA 與 D3SiBPA 之 TGA 圖

0 5 10 15 20 25 D2Si1BA

1.0 1.5 2.0 2.5 3.0

2 Theta(deg.)

Relatively intensity (a.u.)

2 Theta(deg.)

140^OC 39.31 A

0 5 10 15 20 25

D2Si2BA

1.2 1.4 1.61.8 2.0 2.22.4 2.62.8 3.0

2 Theta(deg.)

Relatively intensity (a.u.)

2 Theta(deg.)

180^OC 46.35 A

2 Theta(deg.)

Relatively intensity (a.u.)

2 Theta(deg.)

147^OC 52.65 A 148^OC 52.46 A

0 5 10 15 20 25

I-D2Si2BA

1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0

2 Theta(deg.)

Relatively intensity (a.u.)

2 Theta(deg.)

160^OC 35.24 A 170^OC 34.93 A

0 5 10 15 20 25

II-D2Si2BA

0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0

2 Theta(deg.)

Relatively intensity (a.u.)

2 Theta(deg.)

171^OC 57.76 A 180^OC 55.27 A

0 5 10 15 20 25

V-D2Si1BA

0.5 1.01.5 2.02.5 3.0 3.54.0 4.55.0

2 Theta(deg.)

Relatively intensity (a.u.)

2 Theta(deg.)

110^OC 46.66 A

2 Theta(deg.)

Relatively intensity (a.u.)

2 Theta(deg.)

150^OC 34.33 A

0 5 10 15 20 25

V-D2Si2BA

0.5 1.01.5 2.0 2.5 3.03.5 4.0 4.55.0

2 Theta(deg.)

Relatively intensity (a.u.)

2 Theta(deg.)

130^OC 51.12 A 150^OC 50.59 A

附圖 47. D2Si1BA 、D2Si2BA 與其氫鍵複合物之變溫 XRD 圖

4000 3500 3000 2500 2000 1500 1000 500 60 D2Si1BA

T(%)

wave number(cm^-1) RT

4000 3500 3000 2500 2000 1500 1000 500

10

wave number(cm^-1) RT

4000 3500 3000 2500 2000 1500 1000 500

II-D2Si1BA

T(%)

wave number(cm^-1) RT

148 220

4000 3500 3000 2500 2000 1500 1000 500

III-D2Si1BA

RT 103 180

T(%)

wave number(cm^-1)

4000 3500 3000 2500 2000 1500 1000 500

V-D2Si1BA

T(%)

wave number(cm^-1) RT

115 180

4000 3500 3000 2500 2000 1500 1000 500

I-D2Si2BA

T(%)

wave number(cm^-1) RT

115 220

4000 3500 3000 2500 2000 1500 1000 500

II-D2Si2BA

T(%)

wave number(cm^-1) RT

180 220

4000 3500 3000 2500 2000 1500 1000 500

III-D2Si2BA

T(%)

wave number(cm^-1) RT

130 220

4000 3500 3000 2500 2000 1500 1000 500

V-D2Si2BA

T(%)

wave number(cm^-1) RT

100 220

附圖 48. D2Si1BA 、D2Si2BA 與其氫鍵複合物之變溫 IR 圖

D2Si1BA 140^oC D2Si2BA 200^oC

D3Si1BA 95^oC D3SiNPA 133^oC

D3SiBPA 180^oC II- D2Si1BA 148^oC

II- D2Si1BA 148^oC III- D2Si1BA 104^oC

附圖 49. 未通電壓下之偏光紋理圖

V- D2Si1BA 126^oC V- D2Si1BA 126^oC

I-D2Si2BA 151^oC II-D2Si2BA 171^oC

III-D2Si2BA 175^oC

V-D2Si2BA 157^oC V-D2Si2BA 154^oC

V-D2Si2BA 154^oC II-D2Si2BA 160^oC

附圖 50. 未通電壓下之偏光紋理圖

I-D3Si1BA 69^oC II-D3Si1BA 106^oC

III-D3Si1BA 88^oC V-D3Si1BA 90^oC

I-D3SiNPA 67^oC I-D3SiNPA 94^oC

II-D3SiNPA 116^oC II-D3SiNPA 128^oC

III-D3SiNPA 113^oC V-D3SiNPA 88^oC

附圖 51. 未通電壓下之偏光紋理圖

I-D3SiBPA 127^oC II-D3SiBPA 153^oC

III-D3SiBPA 94^oC III-D3SiBPA 75^oC

V-D3SiBPA 140^oC

附圖 52. 未通電壓下之偏光紋理圖

-0.010 -0.005 0.000 0.005 0.010 -2

0 2

Time (s)

Switching Current (a.u.)

-150 III-D2Si1BA 150

Apply voltage (V)

-0.010 -0.005 0.000 0.005 0.010

-2 0 2

Time (s)

Switching Current (a.u.)

-200

Apply voltage (V)

-0.002 -0.001 0.000 0.001 0.002

-3 II-D2Si1BA 150

Switching Current (a.u.)

Time (s)

Apply voltage (V)

附圖 53. 具反鐵電性質之偏光紋理圖(左)與三角波之光電量測圖(右)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004

Switching Current (a.u.)

Time (s)

Apply voltage (V)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -2.0

Switching Current (a.u.)

Time (s)

III-D3Si1BA

Apply voltage (V)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -1.5

Switching Current (a.u.)

Time (s)

Apply voltage (V)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -4

Switching Current (a.u.)

Time (s)

V-D3Si1BA

Apply voltage (V)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004

Switching Current (a.u.)

Time (s)

V-D3SiBPA

Apply voltage (V)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -3

Switching Current (a.u.)

Time (s)

Apply voltage (V)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -4 V-D3SiNPA 100

Switching Current (a.u.)

Time (s)

Apply voltage (V)

-0.010 -0.005 0.000 0.005 0.010

-1.0 III-D3SiBPA 200

Switching Current (a.u.)

Time (s)

Apply voltage (V)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -2.0

Switching Current (a.u.)

Time (s)

II-D3SiBPA

Apply voltage (V)

附圖 55.具鐵電性質之偏光紋理圖(左)與三角波之光電量測圖(右)

III-D3Si1BA, 0Vpp,88^oC,200Hz III-D3Si1BA,5Vpp,88^oC,200Hz,5sec

III-D3Si1BA,5Vpp,88^oC,200Hz,10sec V-D3Si1BA,0Vpp,98^oC,200Hz

V-D3Si1BA,1Vpp,98^oC,200Hz,5sec V-D3Si1BA,1Vpp,98^oC,200Hz,10sec

附圖 56.具 Switching behavior 之偏光紋理圖

V-D2Si2BA 154(-10^o),154(0^o),154(+10^o) II-D2Si2BA 160 (-10^o),160 (0^o), 160 (+10^o)

III-D3SiBPA 75(-10^o),75(0^o),75(+10^o)

附圖 57.具 Chiral domain 之偏光紋理圖

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004

200Hz,106^OC II-D3Si1BA

-200

Apply voltage (V)

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -2.2

Apply voltage (V)

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -4.0

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -5.0 200Hz,84^oC

Switching Current (a.u.)

Time (s)

Apply voltage (V)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -5.0 200Hz,100^oC 4.5Vpp

1.5Vpp

Apply voltage (V)

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -4.5 200Hz,126^oC

Apply voltage (V)

Switching Current (a.u.)

Time (s) 6Vpp

1Vpp

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -10 200Hz,118^oC 6Vpp

1Vpp

Switching Current (a.u.)

Time (s)

Apply voltage (V)

附圖 58.電壓對 Ps 值關係圖

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004

6Vpp,106^OC II-D3Si1BA

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -2.5

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -4

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -4

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -3.0 5Vpp,126^OC

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -6

5Vpp,118^OC V-D3SiBPA

Switching Current (a.u.)

Time (s)

附圖 59. 頻率對 Ps 值關係圖

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 200Hz, 5Vpp 107^OC

77^OC

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -2.0

200Hz, 5Vpp III-D3Si1BA

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -4.0 200Hz, 5Vpp 71^oC

98^oC

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -3

200Hz, 5Vpp III-D3SiNPA 84^oC

63^oC

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -3.0 200Hz, 5Vpp

Switching Current (a.u.)

Time (s)

-0.008 -0.006 -0.004 -0.002 0.000 0.002 0.004 -6

Switching Current (a.u.)

Time (s)

附圖 60. 溫度對 Ps 值關係圖

在文檔中 含矽氧連結基之氫鍵香蕉型液晶雙體與主鏈型高分子之研究 (頁 64-125)