我們將比較在一系列不同金屬改變溫度，及氧氣含量對催化劑的影響及趨勢。
在活性測試前要先在還原箱中以氫氣還原，並且將其架上反應槽後確認樣品粉末 有沒有堵塞，由於我們樣品為粉末，粉末碰到蒸氣加上氣流會被擠再一起，故我 們要先確認氣體能不能從產物出口流出，避免之後實驗進行到一半，發生實驗裝 製被產物累積的大壓力衝開，造成危險。
接下來我們會比較溫度，在這邊我們所選的溫度範圍有兩個點(600℃、500
℃)，在這邊我們所選擇的溫度範圍對催化活性較好，方便我們做任何比較。再 來比較我們通入的氧氣含量，氧氣流速我們們從(5 sccm 到 40 sccm)，以每 5sccm 作為一個測試點，來探討其對於催化劑的影響。最後我們在比較兩種不同支撐物 對乙醇蒸氣重組反應之間的差異。
開始測試後，我們每個測試點都是經過反應穩定後，再反覆確認 3 次，進而 平均我們的數據。下面我們所呈現的表格是所有的數據，分別有不同溫度、不同 氧氣含量、不同催化劑在乙醇蒸氣重組反應中的產物分佈表。之後我們會把這些 數據拿來做成圖以方便分析。而經由一系列條件測試完之後，我們會在回頭確認 測試點，來確認其數據的穩定性，是否有因為反應時間的關係，而有很大的差距。
而結果也確認，我們的催化劑，並沒有因為時間的差異而造成不同的效果。
表 3-2-1 H2 十種金屬在 BZDy 上(M/BZDy)的氫氣產率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 63.79% 59.56% 51.77% 43.48% 42.72% 53.12% 22.31% 30.71% 26.85% 33.06%
600 165 35 55.92% 63.89% 53.14% 45.71% 44.97% 49.72% 25.64% 23.73% 30.46% 37.68%
600 170 30 55.05% 61.41% 50.03% 47.76% 37.21% 48.29% 20.19% 15.40% 27.61% 39.07%
600 175 25 48.25% 60.42% 39.01% 35.42% 24.87% 32.68% 12.76% 11.42% 20.35% 24.12%
600 180 20 32.01% 50.87% 25.14% 24.33% 21.20% 19.68% 7.66% 11.91% 12.78% 14.19%
600 185 15 20.60% 25.12% 15.71% 14.97% 17.19% 13.29% 4.44% 6.64% 7.77% 9.24%
600 190 10 13.96% 14.82% 10.12% 10.56% 9.41% 8.83% 1.92% 3.41% 4.73% 7.46%
600 195 5 4.96% 9.94% 5.57% 7.53% 7.56% 5.60% 0.81% 2.24% 3.17% 4.32%
500 160 40 43.55% 51.88% 37.55% 43.04% 29.93% 35.26% 21.46% 28.74% 30.61% 35.20%
500 165 35 48.09% 56.29% 36.05% 39.04% 30.20% 40.91% 15.15% 24.36% 31.94% 34.02%
500 170 30 47.44% 53.69% 29.65% 29.76% 24.51% 34.84% 11.63% 15.53% 23.06% 20.22%
500 175 25 222
22
33.65% 37.25% 18.86% 17.08% 19.34% 24.68% 5.13% 12.46% 19.65% 12.82%
500 180 20 20.44% 20.24% 12.21% 11.54% 17.54% 15.25% 1.26% 10.48% 15.42% 6.28%
500 185 15 9.29% 13.06% 7.19% 9.88% 13.08% 9.73% 0.39% 5.85% 9.04% 3.82%
500 190 10 4.95% 7.30% 4.27% 5.88% 9.56% 4.22% 0.16% 2.65% 3.97% 2.43%
500 195 5 2.82% 3.47% 2.15% 3.25% 7.17% 1.81% 0.13% 1.16% 1.47% 1.64%
表 3-2-2 CH4 十種金屬在 BZDy 上(M/BZDy)的甲烷選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 8.22% 6.76% 5.81% 9.14% 10.85% 12.32% 2.30% 12.39% 17.20% 15.34%
600 165 35 8.27% 6.66% 7.66% 6.91% 8.05% 9.42% 4.73% 11.43% 15.54% 14.32%
600 170 30 9.91% 7.59% 9.66% 8.30% 9.19% 8.14% 2.57% 10.12% 14.54% 9.06%
600 175 25 10.94% 8.52% 11.18% 8.81% 10.74% 8.77% 1.35% 4.52% 9.17% 6.31%
600 180 20 10.55% 11.11% 8.39% 8.06% 12.51% 7.70% 0.00% 3.79% 7.95% 5.39%
600 185 15 10.09% 9.41% 10.22% 8.47% 13.40% 7.00% 0.00% 1.04% 7.10% 1.73%
600 190 10 10.80% 9.64% 9.81% 7.98% 8.00% 0.00% 0.00% 0.00% 2.44% 1.86%
600 195 5 12.62% 9.17% 0.00% 1.83% 6.02% 0.00% 0.00% 0.00% 0.00% 2.01%
500 160 40 5.05% 4.26% 8.25% 7.89% 10.48% 14.49% 4.66% 10.98% 14.56% 12.71%
500 165 35 6.48% 5.32% 9.06% 6.86% 17.08% 9.94% 1.98% 7.82% 12.23% 9.14%
500 170 30 10.42% 3.89% 10.89% 7.61% 18.55% 7.98% 1.38% 8.29% 8.41% 5.93%
500 175 25 222
22
7.13% 7.93% 7.95% 7.69% 18.82% 6.73% 0.00% 6.37% 7.32% 2.92%
500 180 20 6.98% 8.27% 7.13% 8.30% 19.73% 6.83% 0.00% 3.83% 7.21% 0.00%
500 185 15 8.35% 7.68% 8.10% 4.29% 17.07% 3.68% 0.00% 0.00% 8.25% 0.00%
500 190 10 6.63% 5.28% 9.18% 1.59% 19.32% 0.00% 0.00% 0.00% 1.95% 0.00%
500 195 5 2.32% 2.63% 2.10% 0.00% 20.16% 0.00% 0.00% 0.00% 0.00% 0.00%
表 3-2-3 CO 十種金屬在 BZDy 上(M/BZDy)的一氧化碳選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 50.16% 44.73% 50.91% 44.69% 45.22% 32.03% 28.79% 32.74% 32.02% 39.21%
600 165 35 48.92% 42.09% 52.25% 53.47% 46.33% 46.56% 29.62% 28.99% 34.95% 42.75%
600 170 30 48.62% 43.71% 52.73% 53.98% 40.30% 42.76% 25.03% 20.19% 34.02% 41.74%
600 175 25 51.58% 41.53% 53.94% 50.04% 35.79% 38.76% 17.40% 16.97% 22.00% 28.71%
600 180 20 47.49% 42.86% 45.28% 40.19% 31.32% 28.74% 14.34% 15.26% 16.27% 20.07%
600 185 15 41.04% 37.51% 41.73% 29.19% 28.59% 21.09% 9.49% 12.87% 12.03% 15.10%
600 190 10 33.36% 29.05% 28.11% 21.14% 24.16% 17.28% 7.02% 8.11% 11.43% 14.08%
600 195 5 21.43% 20.33% 19.24% 15.82% 24.56% 19.75% 0.00% 3.93% 5.69% 10.53%
500 160 40 48.90% 45.57% 50.52% 50.35% 39.86% 36.99% 27.40% 31.41% 37.83% 39.42%
500 165 35 47.95% 44.52% 50.47% 51.45% 33.36% 45.44% 25.59% 30.38% 38.23% 39.31%
500 170 30 49.90% 47.01% 49.44% 47.96% 30.88% 47.89% 21.99% 24.85% 27.48% 26.54%
500 175 25 222
22
42.25% 45.97% 42.10% 34.73% 28.50% 39.65% 13.93% 28.47% 25.29% 17.08%
500 180 20 32.40% 38.05% 29.87% 28.11% 27.08% 25.07% 7.29% 21.63% 19.32% 9.39%
500 185 15 23.78% 27.00% 21.94% 22.45% 21.28% 18.14% 0.00% 16.26% 14.20% 4.94%
500 190 10 17.95% 15.47% 19.12% 16.70% 21.91% 10.84% 0.00% 6.94% 8.89% 0.00%
500 195 5 15.09% 14.18% 12.40% 16.07% 21.66% 7.15% 0.00% 0.00% 3.85% 0.00%
表 3-2-3 CO2 十種金屬在 BZDy 上(M/BZDy)的二氧化碳選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 40.05% 48.51% 42.81% 43.83% 35.15% 52.14% 40.18% 32.20% 36.62% 36.31%
600 165 35 40.39% 51.25% 38.86% 34.14% 34.45% 41.25% 44.23% 38.72% 34.84% 36.32%
600 170 30 37.68% 48.65% 35.97% 32.50% 34.05% 43.70% 44.53% 35.03% 31.75% 37.79%
600 175 25 33.18% 49.29% 30.11% 23.51% 34.77% 38.28% 41.15% 32.66% 32.85% 30.15%
600 180 20 25.79% 39.68% 24.74% 19.07% 33.04% 34.56% 38.09% 27.85% 29.34% 27.63%
600 185 15 22.02% 22.19% 24.79% 18.34% 30.57% 30.54% 28.49% 25.49% 21.70% 25.22%
600 190 10 21.26% 15.02% 19.23% 15.93% 31.07% 31.26% 28.05% 15.55% 21.84% 24.41%
600 195 5 23.28% 11.10% 16.88% 12.18% 28.66% 38.91% 21.91% 9.02% 11.60% 12.66%
500 160 40 41.35% 50.16% 35.28% 35.48% 39.57% 35.96% 47.54% 38.15% 38.92% 40.65%
500 165 35 41.15% 49.81% 34.43% 32.80% 38.59% 35.68% 44.23% 36.85% 36.16% 40.32%
500 170 30 35.96% 46.14% 30.26% 30.17% 34.47% 30.92% 42.82% 38.86% 36.97% 32.87%
500 175 25 222
22
34.64% 34.04% 27.83% 26.16% 31.20% 30.98% 37.07% 42.04% 37.25% 28.17%
500 180 20 24.56% 22.59% 23.90% 26.74% 29.33% 30.94% 31.72% 41.04% 34.03% 23.20%
500 185 15 19.29% 16.65% 21.07% 22.77% 22.99% 29.45% 16.96% 39.50% 25.06% 15.82%
500 190 10 13.08% 10.91% 19.72% 20.04% 23.23% 23.17% 10.74% 19.61% 18.81% 6.36%
500 195 5 11.77% 7.62% 13.15% 19.34% 24.40% 18.80% 11.43% 10.33% 10.28% 4.42%
表 3-2-4 C2H4 十種金屬在 BZDy 上(M/BZDy)的乙烯選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 0.00% 0.00% 0.00% 2.27% 3.78% 3.40% 6.54% 10.37% 14.08% 6.82%
600 165 35 0.00% 0.00% 0.00% 4.26% 2.70% 2.02% 7.04% 9.13% 14.02% 4.74%
600 170 30 0.88% 0.00% 0.00% 3.76% 2.75% 2.31% 5.53% 7.13% 17.20% 5.60%
600 175 25 1.29% 0.00% 1.82% 10.17% 4.27% 5.23% 4.64% 5.72% 23.62% 9.98%
600 180 20 2.68% 3.27% 2.20% 14.25% 5.57% 7.19% 3.63% 5.69% 20.04% 11.87%
600 185 15 3.61% 12.87% 3.19% 18.51% 5.47% 5.63% 3.28% 5.55% 11.53% 10.62%
600 190 10 4.71% 21.79% 2.58% 21.83% 3.68% 5.36% 0.00% 4.66% 13.71% 25.35%
600 195 5 16.23% 27.52% 3.00% 22.00% 5.01% 10.52% 0.00% 6.21% 10.58% 28.64%
500 160 40 1.20% 0.00% 1.98% 2.00% 3.27% 9.90% 4.48% 12.68% 5.96% 5.27%
500 165 35 0.84% 0.00% 1.86% 1.95% 0.00% 4.54% 4.36% 12.24% 8.13% 6.89%
500 170 30 0.00% 0.00% 2.11% 3.52% 0.00% 3.87% 4.83% 8.56% 11.46% 6.19%
500 175 25 222
22
1.28% 1.75% 5.35% 3.79% 1.14% 5.97% 3.25% 9.82% 6.55% 4.30%
500 180 20 1.20% 3.57% 4.54% 3.65% 0.00% 4.81% 0.00% 10.36% 3.22% 1.83%
500 185 15 0.00% 5.42% 2.06% 3.49% 0.00% 3.45% 0.00% 9.71% 2.75% 0.00%
500 190 10 2.54% 5.24% 2.58% 4.45% 0.00% 5.72% 0.00% 4.87% 0.00% 0.00%
500 195 5 2.61% 6.64% 0.00% 6.43% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
表 3-2-5 CHO 十種金屬在 BZDy 上(M/BZDy)的乙醛選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 1.58% 0.00% 0.47% 0.07% 5.00% 0.10% 21.06% 11.85% 0.08% 2.31%
600 165 35 2.42% 0.00% 1.23% 1.23% 8.47% 0.75% 14.38% 11.73% 0.65% 1.87%
600 170 30 2.92% 0.04% 1.64% 1.46% 13.71% 3.08% 22.35% 27.52% 2.49% 5.80%
600 175 25 3.01% 0.66% 2.96% 7.46% 14.44% 8.96% 34.07% 38.49% 12.35% 24.06%
600 180 20 13.48% 3.07% 19.39% 18.43% 17.55% 21.03% 41.01% 44.71% 24.71% 32.42%
600 185 15 23.25% 18.02% 20.06% 25.49% 21.96% 25.98% 31.76% 52.32% 45.08% 45.47%
600 190 10 29.87% 24.50% 40.26% 30.19% 33.09% 43.42% 35.37% 68.94% 46.55% 34.30%
600 195 5 39.06% 30.07% 60.88% 46.27% 35.75% 30.82% 44.97% 76.83% 69.52% 42.79%
500 160 40 3.49% 0.00% 3.96% 4.28% 6.82% 2.66% 15.92% 6.78% 2.72% 1.96%
500 165 35 3.57% 0.34% 4.19% 6.95% 10.97% 4.40% 23.84% 12.71% 5.25% 4.34%
500 170 30 3.72% 2.96% 7.29% 10.73% 16.11% 9.33% 26.44% 19.44% 15.68% 26.57%
500 175 25 222
22
14.70% 10.31% 16.76% 27.09% 19.48% 16.66% 42.45% 13.31% 23.58% 45.52%
500 180 20 33.20% 26.04% 33.48% 32.30% 23.86% 32.36% 60.99% 21.12% 34.22% 62.12%
500 185 15 46.44% 40.74% 45.01% 45.88% 37.48% 42.29% 75.32% 34.53% 43.28% 74.81%
500 190 10 56.45% 57.63% 47.45% 54.28% 34.09% 54.77% 89.26% 61.77% 64.89% 90.03%
500 195 5 64.51% 65.55% 68.98% 58.16% 31.18% 67.07% 88.57% 79.63% 80.42% 89.01%
表 3-2-6 EtOH 十種金屬在 BZDy 上(M/BZDy)的乙醇轉換效率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 98.32% 99.91% 99.56% 97.25% 91.50% 99.72% 82.11% 95.45% 99.91% 91.84%
600 165 35 97.31% 99.91% 98.69% 99.15% 90.05% 98.03% 91.41% 95.62% 99.80% 99.13%
600 170 30 96.28% 99.88% 97.67% 98.93% 85.25% 95.41% 84.32% 87.84% 98.46% 98.53%
600 175 25 94.29% 99.20% 94.55% 94.85% 85.03% 90.08% 76.86% 85.62% 92.50% 90.57%
600 180 20 86.95% 97.12% 84.60% 87.49% 82.08% 79.44% 70.14% 77.46% 85.22% 79.52%
600 185 15 81.09% 86.55% 84.92% 83.88% 78.76% 78.42% 64.72% 80.87% 76.37% 75.49%
600 190 10 75.13% 81.06% 71.39% 79.04% 72.92% 67.34% 62.72% 65.14% 77.30% 92.38%
600 195 5 51.24% 68.04% 68.07% 71.53% 73.00% 74.56% 62.56% 69.75% 67.99% 68.69%
500 160 40 95.42% 100.00% 96.48% 89.24% 92.01% 96.48% 81.77% 93.71% 98.26% 98.46%
500 165 35 94.06% 97.86% 95.44% 92.84% 85.60% 94.51% 72.24% 90.14% 95.78% 93.26%
500 170 30 92.44% 92.94% 92.31% 90.12% 84.90% 90.10% 65.50% 90.59% 88.51% 85.33%
500 175 25 222
22
86.58% 84.17% 84.33% 83.76% 78.96% 85.50% 53.82% 91.41% 79.66% 80.66%
500 180 20 67.34% 75.37% 78.95% 79.30% 77.38% 77.27% 63.07% 81.59% 78.50% 77.00%
500 185 15 68.64% 69.38% 75.18% 76.90% 75.00% 73.29% 46.67% 81.36% 75.09% 71.60%
500 190 10 56.69% 54.03% 70.71% 70.69% 70.79% 64.41% 57.99% 68.24% 68.49% 69.88%
500 195 5 61.30% 65.19% 62.52% 75.65% 65.63% 60.04% 59.34% 56.93% 66.05% 53.44%
表 3-2-7 EA 十種金屬在 BZDy 上(M/BZDy)的乙酸乙酯選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 1.13% 0.46% 0.00% 0.00%
600 165 35 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
600 170 30 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
600 175 25 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 1.39% 1.64% 0.00% 0.79%
600 180 20 0.00% 0.00% 0.00% 0.00% 0.00% 0.79% 2.93% 2.70% 1.69% 2.62%
600 185 15 0.00% 0.00% 0.00% 0.00% 0.00% 9.74% 26.97% 2.72% 2.56% 1.86%
600 190 10 0.00% 0.00% 0.00% 2.92% 0.00% 2.68% 29.57% 2.74% 4.03% 0.00%
600 195 5 0.00% 1.82% 0.00% 1.90% 0.00% 0.00% 33.12% 4.02% 2.61% 3.37%
500 160 40 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
500 165 35 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
500 170 30 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 2.53% 0.00% 0.00% 1.90%
500 175 25 222
22
0.00% 0.00% 0.00% 0.54% 0.88% 0.00% 3.30% 0.00% 0.00% 2.02%
500 180 20 1.66% 1.48% 1.08% 0.90% 0.00% 0.00% 0.00% 2.02% 1.99% 3.46%
500 185 15 2.14% 2.51% 1.83% 1.12% 1.17% 2.99% 7.72% 0.00% 6.46% 4.43%
500 190 10 3.36% 5.47% 1.96% 2.93% 1.46% 5.49% 0.00% 6.81% 5.45% 3.61%
500 195 5 3.70% 3.38% 3.37% 0.00% 2.59% 6.98% 0.00% 10.04% 5.46% 6.57%
表 3-2-8 H2十種金屬在 CeO2上(M/CeO2)的氫氣產率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 59.25% 49.79% 30.98% 42.79% 14.87% 46.84% 15.00% 10.84% 16.01% 6.31%
600 165 35 56.35% 43.10% 28.26% 30.11% 12.99% 34.16% 15.89% 11.13% 12.75% 7.88%
600 170 30 45.01% 35.91% 5.62% 8.80% 9.89% 18.11% 12.42% 6.98% 7.44% 9.29%
600 175 25 32.30% 12.30% 8.38% 4.52% 6.28% 11.24% 8.56% 5.55% 4.79% 7.33%
600 180 20 22.99% 10.35% 9.48% 2.64% 5.37% 9.37% 6.32% 4.14% 4.16% 4.75%
600 185 15 16.59% 8.55% 6.82% 1.74% 4.63% 7.11% 5.01% 3.20% 5.35% 3.90%
600 190 10 12.77% 5.73% 1.66% 1.11% 3.40% 5.80% 4.05% 2.93% 5.32% 4.48%
600 195 5 8.12% 3.73% 0.83% 0.71% 2.07% 3.04% 3.35% 2.73% 3.79% 3.97%
500 160 40 56.35% 43.10% 28.26% 30.11% 12.99% 34.16% 15.89% 11.13% 12.75% 7.88%
500 165 35 45.01% 35.91% 5.62% 8.80% 9.89% 18.11% 12.42% 6.98% 7.44% 9.29%
500 170 30 32.30% 12.30% 8.38% 4.52% 6.28% 11.24% 8.56% 5.55% 4.79% 7.33%
500 175 25 222
22
22.99% 10.35% 9.48% 2.64% 5.37% 9.37% 6.32% 4.14% 4.16% 4.75%
500 180 20 16.59% 8.55% 6.82% 1.74% 4.63% 7.11% 5.01% 3.20% 5.35% 3.90%
500 185 15 12.77% 5.73% 1.66% 1.11% 3.40% 5.80% 4.05% 2.93% 5.32% 4.48%
500 190 10 8.12% 3.73% 0.83% 0.71% 2.07% 6.18% 3.35% 2.73% 3.79% 3.97%
500 195 5 2.12% 0.36% 0.00% 0.17% 0.93% 3.04% 3.61% 1.26% 1.39% 1.66%
表 3-2-9 CH4 十種金屬在 CeO2上(M/CeO2)的甲烷選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 6.05% 12.44% 7.09% 0.96% 4.63% 6.15% 4.59% 3.48% 4.23% 6.65%
600 165 35 7.40% 11.28% 6.91% 1.44% 3.80% 6.17% 2.90% 5.69% 3.20% 3.35%
600 170 30 7.65% 10.94% 0.00% 1.88% 3.35% 5.77% 2.69% 5.65% 2.39% 1.69%
600 175 25 11.04% 12.36% 0.00% 1.23% 3.13% 6.21% 2.05% 4.73% 1.69% 1.92%
600 180 20 10.28% 13.04% 0.00% 0.78% 2.95% 5.82% 1.22% 3.45% 1.11% 0.72%
600 185 15 11.24% 14.03% 0.00% 0.00% 1.31% 4.70% 0.62% 2.34% 0.67% 0.64%
600 190 10 11.05% 15.01% 0.00% 0.00% 0.82% 0.00% 0.00% 1.47% 0.34% 0.73%
600 195 5 12.01% 14.40% 0.00% 0.00% 0.59% 0.00% 0.00% 0.00% 0.00% 0.00%
500 160 40 11.15% 8.67% 0.00% 1.04% 3.61% 6.79% 2.38% 1.61% 3.50% 4.25%
500 165 35 13.67% 10.45% 0.00% 1.06% 3.25% 5.19% 1.97% 1.44% 2.97% 3.48%
500 170 30 14.97% 12.53% 0.00% 0.83% 3.98% 5.31% 0.60% 1.15% 1.42% 1.75%
500 175 25 222
22
16.35% 13.92% 0.00% 0.45% 4.67% 4.58% 0.52% 1.51% 0.87% 1.12%
500 180 20 19.58% 13.38% 0.00% 0.00% 4.84% 0.70% 0.51% 0.94% 0.58% 0.60%
500 185 15 21.76% 11.48% 0.00% 0.00% 5.54% 0.00% 0.00% 0.00% 0.00% 0.00%
500 190 10 15.21% 13.12% 0.00% 0.00% 6.69% 0.00% 0.00% 0.00% 0.00% 0.00%
500 195 5 12.61% 12.48% 0.00% 0.00% 5.98% 0.00% 0.00% 0.00% 0.00% 0.00%
表 3-2-10 CO 十種金屬在 CeO2上(M/CeO2)的一氧化碳選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 46.10% 38.75% 33.92% 37.77% 27.47% 31.87% 24.69% 27.14% 21.04% 18.50%
600 165 35 48.98% 37.94% 35.00% 31.29% 22.12% 29.24% 26.80% 23.80% 16.93% 18.91%
600 170 30 52.21% 39.54% 23.47% 22.72% 17.45% 19.90% 24.56% 20.52% 12.35% 19.70%
600 175 25 53.90% 41.19% 25.34% 17.33% 13.80% 16.83% 16.18% 15.54% 8.23% 15.76%
600 180 20 43.27% 40.78% 29.56% 9.50% 12.18% 14.95% 9.84% 10.29% 5.75% 10.81%
600 185 15 38.74% 38.10% 33.33% 6.93% 5.31% 8.97% 4.84% 6.10% 3.12% 7.78%
600 190 10 27.80% 29.34% 13.27% 5.39% 3.80% 4.88% 2.79% 4.01% 1.74% 5.49%
600 195 5 25.60% 21.29% 5.76% 3.75% 3.03% 3.24% 1.59% 1.18% 0.75% 2.99%
500 160 40 50.80% 37.71% 20.47% 27.98% 24.16% 29.76% 25.23% 14.36% 18.80% 19.70%
500 165 35 51.77% 41.60% 13.60% 21.33% 19.31% 22.46% 27.49% 18.14% 15.44% 21.14%
500 170 30 52.63% 41.87% 6.46% 16.34% 18.07% 17.59% 16.27% 18.24% 9.69% 19.81%
500 175 25 222
22
52.74% 43.75% 5.19% 11.69% 13.20% 11.22% 15.37% 22.06% 7.00% 13.81%
500 180 20 52.20% 37.88% 3.14% 8.60% 11.09% 9.23% 13.97% 17.05% 5.24% 9.22%
500 185 15 48.98% 26.19% 1.75% 6.02% 11.36% 6.19% 6.83% 11.61% 3.53% 6.20%
500 190 10 27.76% 22.02% 0.00% 3.43% 11.34% 4.04% 3.39% 4.61% 2.91% 3.30%
500 195 5 17.64% 14.19% 0.00% 2.41% 9.63% 2.13% 0.00% 0.00% 0.00% 0.00%
表 3-2-11 CO2 十種金屬在 CeO2上(M/CeO2)的二氧化碳選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 47.85% 45.38% 54.92% 53.22% 31.03% 51.39% 43.24% 33.01% 32.91% 51.13%
600 165 35 43.61% 43.20% 51.97% 43.84% 25.19% 44.37% 39.10% 33.26% 25.99% 44.26%
600 170 30 35.59% 33.67% 67.68% 21.37% 20.02% 33.66% 29.19% 24.86% 20.47% 33.57%
600 175 25 22.79% 12.24% 73.18% 19.35% 17.39% 25.81% 25.33% 20.43% 15.44% 26.03%
600 180 20 13.53% 13.24% 64.47% 18.00% 17.55% 25.26% 23.78% 17.58% 12.44% 20.51%
600 185 15 12.94% 11.43% 42.00% 17.53% 8.22% 22.19% 17.60% 8.99% 9.19% 16.40%
600 190 10 10.20% 10.33% 28.63% 15.65% 6.69% 16.99% 15.12% 7.78% 7.47% 15.04%
600 195 5 9.41% 7.14% 15.63% 12.23% 5.25% 16.19% 14.63% 3.24% 5.58% 12.20%
500 160 40 37.74% 51.60% 64.33% 57.76% 28.28% 50.85% 48.48% 57.69% 31.34% 52.98%
500 165 35 34.22% 44.79% 27.27% 37.89% 22.50% 39.44% 45.04% 44.53% 24.80% 43.42%
500 170 30 31.64% 36.47% 17.29% 32.45% 24.30% 29.39% 24.02% 39.67% 22.77% 34.98%
500 175 25 222
22
29.24% 20.68% 19.01% 30.94% 16.54% 20.57% 20.86% 52.08% 18.82% 27.49%
500 180 20 23.29% 11.32% 20.36% 32.17% 12.32% 27.20% 18.45% 38.00% 15.70% 23.99%
500 185 15 22.92% 8.23% 15.43% 27.33% 11.53% 23.32% 12.81% 35.41% 12.90% 20.32%
500 190 10 15.72% 7.72% 12.89% 19.58% 10.10% 15.35% 21.21% 25.77% 12.12% 15.69%
500 195 5 11.97% 4.12% 6.76% 14.69% 7.84% 11.39% 12.96% 16.31% 13.97% 11.03%
表 3-2-12 C2H4 十種金屬在 CeO2上(M/CeO2)的乙烯選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 0.00% 2.00% 2.65% 5.71% 27.17% 8.79% 20.60% 20.18% 36.67% 20.82%
600 165 35 0.00% 3.21% 5.02% 15.71% 35.72% 10.49% 22.22% 28.49% 45.58% 30.22%
600 170 30 0.94% 2.84% 8.31% 33.16% 44.08% 16.68% 26.57% 32.35% 52.08% 39.30%
600 175 25 3.34% 6.61% 0.87% 31.78% 44.17% 20.83% 29.01% 35.98% 54.74% 47.91%
600 180 20 4.09% 5.12% 3.46% 30.40% 40.52% 13.78% 34.26% 33.69% 45.26% 52.18%
600 185 15 5.55% 5.41% 21.93% 23.72% 31.20% 10.02% 31.33% 35.54% 34.61% 51.59%
600 190 10 5.83% 4.91% 50.40% 16.45% 30.98% 5.86% 40.05% 52.38% 28.30% 53.83%
600 195 5 7.58% 5.76% 60.28% 15.48% 29.81% 7.82% 49.24% 58.90% 27.35% 49.77%
500 160 40 0.00% 0.00% 0.00% 4.97% 25.25% 5.21% 11.31% 20.97% 37.81% 19.67%
500 165 35 0.00% 0.00% 9.59% 16.15% 31.38% 7.15% 11.72% 23.80% 39.70% 26.42%
500 170 30 0.00% 0.58% 5.11% 22.86% 31.87% 7.93% 10.61% 29.09% 33.95% 31.52%
500 175 25 222
22
0.39% 1.11% 10.28% 18.96% 17.99% 17.68% 8.78% 19.63% 28.95% 35.57%
500 180 20 1.47% 1.19% 8.22% 17.83% 14.24% 12.50% 5.18% 24.52% 25.07% 34.03%
500 185 15 2.37% 0.00% 5.52% 15.22% 12.24% 4.70% 4.73% 21.29% 21.08% 33.17%
500 190 10 2.19% 0.00% 0.00% 12.25% 8.90% 3.61% 9.83% 13.76% 18.83% 28.38%
500 195 5 1.78% 0.00% 0.00% 8.51% 4.73% 3.68% 7.55% 9.14% 19.12% 17.28%
表 3-2-13 CHO 十種金屬在 CeO2上(M/CeO2)的乙醛選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 0.00% 1.42% 1.42% 2.34% 9.15% 1.80% 6.87% 7.44% 5.15% 2.89%
600 165 35 0.02% 4.38% 1.11% 7.71% 12.41% 9.07% 8.98% 7.80% 8.29% 3.27%
600 170 30 3.61% 13.00% 0.54% 20.70% 13.69% 22.10% 16.98% 14.73% 12.71% 5.74%
600 175 25 8.93% 26.38% 0.62% 28.37% 18.44% 28.35% 25.46% 23.32% 19.89% 8.38%
600 180 20 28.83% 26.02% 2.51% 37.41% 18.71% 36.86% 29.19% 31.25% 25.33% 15.79%
600 185 15 29.70% 28.36% 2.74% 45.97% 24.43% 48.47% 41.14% 40.74% 22.71% 23.59%
600 190 10 42.84% 31.46% 7.70% 55.56% 26.21% 61.90% 38.14% 30.89% 19.83% 24.91%
600 195 5 43.02% 44.49% 18.32% 63.12% 28.58% 62.73% 30.14% 34.17% 17.10% 32.43%
500 160 40 0.31% 2.02% 15.20% 8.25% 18.71% 6.77% 12.60% 3.84% 8.56% 3.41%
500 165 35 0.34% 3.16% 27.66% 20.76% 23.56% 24.04% 12.27% 10.59% 17.08% 5.54%
500 170 30 0.76% 8.55% 30.04% 25.86% 21.77% 35.71% 23.42% 11.86% 32.17% 10.73%
500 175 25 222
22
1.28% 19.64% 36.10% 34.67% 43.57% 40.86% 24.29% 4.72% 44.36% 20.25%
500 180 20 3.47% 33.79% 61.70% 37.91% 51.72% 44.38% 28.03% 19.48% 44.20% 32.16%
500 185 15 3.98% 48.68% 66.76% 47.43% 53.10% 56.62% 36.00% 31.69% 49.74% 36.70%
500 190 10 37.41% 50.87% 75.73% 59.95% 56.14% 64.88% 39.68% 55.86% 53.81% 46.95%
500 195 5 52.89% 60.36% 83.06% 69.73% 71.82% 67.65% 65.19% 66.15% 50.28% 64.41%
表 3-2-14 EtOH 十種金屬在 CeO2上(M/CeO2)的乙醇轉換效率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 99.96% 97.32% 98.31% 98.16% 93.24% 98.19% 96.68% 98.87% 97.71% 99.85%
600 165 35 99.11% 94.39% 97.87% 96.43% 92.78% 94.44% 96.11% 97.95% 96.41% 99.67%
600 170 30 98.39% 86.70% 99.74% 91.67% 91.81% 88.28% 94.46% 95.58% 94.92% 99.21%
600 175 25 94.87% 78.38% 99.75% 85.88% 88.42% 91.74% 89.98% 94.11% 91.24% 97.91%
600 180 20 79.69% 81.78% 99.11% 74.74% 88.29% 88.14% 90.20% 86.94% 86.61% 94.80%
600 185 15 75.14% 86.16% 98.56% 65.94% 66.99% 71.52% 80.63% 81.11% 69.80% 90.47%
600 190 10 61.92% 82.72% 95.94% 51.31% 57.25% 55.52% 71.43% 86.68% 62.00% 79.35%
600 195 5 55.90% 82.88% 99.88% 38.14% 44.80% 51.56% 79.42% 83.17% 56.72% 72.03%
500 160 40 98.01% 96.95% 93.64% 92.49% 85.11% 90.23% 91.26% 97.36% 95.50% 99.85%
500 165 35 98.10% 96.38% 83.19% 86.54% 75.53% 85.69% 90.53% 95.58% 88.34% 99.46%
500 170 30 93.98% 91.51% 69.45% 86.49% 85.41% 78.87% 84.22% 95.74% 70.19% 98.00%
500 175 25 222
22
88.89% 83.74% 63.70% 76.74% 54.01% 75.26% 89.07% 98.76% 58.60% 95.05%
500 180 20 78.18% 72.24% 48.72% 72.16% 44.68% 67.69% 87.08% 93.61% 51.91% 87.43%
500 185 15 73.35% 61.89% 47.79% 63.63% 53.06% 58.23% 68.04% 92.09% 33.13% 76.07%
500 190 10 55.83% 66.29% 50.07% 49.45% 48.82% 49.70% 72.98% 78.18% 32.28% 56.44%
500 195 5 50.25% 44.22% 55.41% 38.91% 53.29% 33.95% 40.62% 62.74% 60.65% 44.82%
表 3-2-15 EA 十種金屬在 CeO2上(M/CeO2)的乙酸乙酯選擇率
溫度℃ N2 O2 Rh Ru Ir Pt Pd Ni Co Cu Au Ag
600 160 40 0.00% 0.00% 0.00% 0.00% 0.55% 0.00% 0.00% 8.74% 0.00% 0.00%
600 165 35 0.00% 0.00% 0.00% 0.00% 0.76% 0.66% 0.00% 0.96% 0.00% 0.00%
600 170 30 0.00% 0.00% 0.00% 0.17% 1.41% 1.89% 0.00% 1.89% 0.00% 0.00%
600 175 25 0.00% 1.23% 0.00% 1.95% 3.07% 1.97% 1.97% 0.00% 0.00% 0.00%
600 180 20 0.00% 1.81% 0.00% 3.90% 8.09% 3.33% 1.71% 3.73% 10.11% 0.00%
600 185 15 1.83% 2.67% 0.00% 5.85% 29.53% 5.65% 4.48% 6.28% 29.69% 0.00%
600 190 10 2.27% 8.96% 0.00% 6.94% 31.49% 10.38% 3.89% 3.47% 42.33% 0.00%
600 195 5 2.38% 6.92% 0.00% 5.42% 32.74% 10.01% 4.39% 2.51% 49.23% 2.61%
500 160 40 0.00% 0.00% 0.00% 0.00% 0.00% 0.63% 0.00% 1.54% 0.00% 0.00%
500 165 35 0.00% 0.00% 21.87% 2.80% 0.00% 1.71% 1.51% 1.50% 0.00% 0.00%
500 170 30 0.00% 0.00% 41.10% 1.67% 0.00% 4.06% 25.08% 0.00% 0.00% 1.21%
500 175 25 222
22
0.00% 0.90% 29.43% 3.30% 4.03% 5.08% 30.18% 0.00% 0.00% 1.77%
500 180 20 0.00% 2.44% 6.58% 3.49% 5.79% 5.99% 33.86% 0.00% 9.20% 0.00%
500 185 15 0.00% 5.42% 10.54% 4.01% 6.24% 9.18% 39.62% 0.00% 12.75% 3.62%
500 190 10 1.70% 6.27% 11.38% 4.80% 6.84% 12.13% 25.90% 0.00% 12.34% 5.67%
500 195 5 3.12% 8.85% 10.18% 4.66% 0.00% 15.16% 14.30% 8.41% 16.63% 7.28%