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Electrical and Optical Properties

Chapter 6  A novel Silicon-Nitride based Light-Emitting Transistor (SiNLET)

6.3  Electrical and Optical Properties

6.2.3 Light Spectrum and CCD Image 

Fig.6.4  (a)  and  (b)  show  the  light  spectrum  and  CCD  image  of  SiNLET,  respectively.  SiNLET  shows  peak  intensity  at  the  wavelength  of  around  700nm  (~1.8eV),  and  its  light  spectrum  contains  infrared  ray  and  visible  ray  (1100nm  ~  400nm).  To  further  investigate  the  detail  of  SiNLET,  the  light  spectrums  of  several  bias  conditions  and  device  structures  are compared.  As  shown  in  Fig.6.4,  if  we  just  apply  a  negative  bias  on  the  poly  with  FN-E  supply  only,  no  light  emission  is  observed.  Similar  result  is  obtained  as  we  only  supply  BTBT  HH  without  electron  injection. When a MOS structure without nitride traps is used to replace the SONOS  structure, we still donít observe light emission (see Fig.6.4 (a) and (c)). 

Fig.6.5  compares  the  light  spectrums  of  a  reverse-biased  junction  and  a  forward-biased  junction.  In  the  reverse-biased  junction,  a  shorter  wavelength  and  lower current consumption are  obtained, which  results from  the  scattering,  trapping,  and recombination of high energetic electrons and holes via nitride traps. In contrast,  the  forward-biased  junction  functions  as  a  pure  p-n-junction  LED,  and  shows  peak  intensity  at  around  1000nm.  The  photon  energy  is  around  1.2eV,  which  should  be  caused  by  the  electron/hole  pair  recombination  in  the  bulk  substrate  via  silicon  band-gap.  Table  5.1  summarizes  the  results  of  light  emission  in  various  bias  conditions and device structures. High energetic electrons, hot holes and nitride traps  (quantum  dots  for  carrier  scattering,  trapping  and  recombination)  are  essential  for  SiNLET to emit high energetic photons. 

 

6.3 Electrical and Optical Properties 

Fig.6.6  (a)  and  Fig.6.7  (a)  show  the  light  spectrum  of  SiNLET  operated  in  different Ve and  Vh.  Higher  Ve  or  Vh  shows larger  output  light  intensity  due to  the  increased input vertical and lateral electrical field. Fig.6.6 (b) and Fig.6.7 (b) show the  supply  current  from  the  n+  junction  to  the  p-well  (Ih=-Ic),  which  is  induced  by  band-to-band tunneling. In the normal operation condition, the current from the poly 

SiNLET  can  function  as  a  three-terminal  light-emitting  transistor  as  shown  in  Fig.6.8.  The  poly  (Ve)  and  n+  junction  (Vh)  serves  as  the  Source  and  the  Drain  to  supply  electrons  and  holes,  respectively.  The  control  voltage  (Vc)  in  the  p-well  can  control the lateral electrical field to modulate the output light intensity, which serves  as  the  Gate.  Fig.6.9  shows  the  output  light  intensity  versus  the  supply  current,  and  they  have  nearly  linearly  dependence.  Fig.6.10  shows  the  output  light  intensity  as  a  function of Vc. Fig.6.11 demonstrates the characteristics of output light intensity as a  function  of  input  Ve  and  Vh.  The  threshold  voltage  of  Vc  is  around  2V  to  switch  SiNLET.  Fig.6.12  shows  the  voltage  stress  effect  on  SiNLET.  After  continuously  stress  for  10  hours,  a  little  degradation  of  light  intensity  is  observed,  which  should  result from the stress induced deterioration of the ONO film. The wavelength of peak  intensity after electrical stress is still 700nm. 

 

6.4 Conclusion 

We  have  reported  a novel SiNLET  with  high  light emission efficiency and  low  current consumption (<10-7A/µm) in a small device area (~0.616µm2), and its process  is compatible to standard CMOS. SiNLET shows peak intensity at around 700nm, and  its light spectrum contains infrared and visible light. SiNLET can modulate the output  light  intensity  by  controlling  the  input  voltages,  and  functions  as  a  light-emitting  transistor. SiNLET can be integrated with CMOS devices easily as shown in Fig.6.13  and has demonstrated its high feasibility for the application of optical interconnects in  ULSI. 

                         

 

h

υ

Electron

Hole

h

υ

Electron

Hole

                                                                     

Poly

h

υ

Oxide Nitride Oxide n+

Electron Hole

BTBT-HH FN-E

Fig.6.3 Schematic representation of the band diagram of SiNLET in the  operation condition of light emission. 

                     

Fig.6.4  (a)  Light  spectrum  of  various  bias  conditions  and  device  structures.

Squares represent the spectrum of the normal operation condition of SiNLET.

Circles  and  up-triangles  represent  the  spectrum  with  FN-E  supply  only  and  BTBT-HH  supply  only  in  SONOS  structure,  respectively.  Down-triangles  represent  the  spectrum  of  the  normal  operation  condition  in  MOS  structure (oxide thickness is 18nm). (b) CCD image of SiNLET in the normal operation  condition. (c) CCD image of MOS structure in the normal operation condition (Vc/Ve/Vh=0/-16/5.8). 

(a) 

200 400 600 800 1000 1200 -500

0 500 1000 1500 2000 2500 3000

 

 

Intensity (a.u.)

Wave Length (nm)

SONOS structure

 Ve=-16, Vh=5.8 (normal condition)  Ve=-23, Vh=0 (FN-E only)

 Ve=0, Vh=5.8 (BTBT-HH only) MOS structure  Ve=-16, Vh=5.8 (without nitride traps)

(b)  (c)

   

                 

Fig.6.5  Light  spectrum  of  SiNLET  in  the  operation  condition  of forward-biased  junction  (circles)  and  reverse-biased  junction  (squares).

Reverse-biased junction shows shorter wavelength and higher photon energy, and the supply current is 3 orders less than the forward-biased junction. 

200 400 600 800 1000 1200 0

500 1000 1500 2000 2500 3000 3500

 

 

Inte ns it (a .u .)

Wave Length (nm)

 Vh=-0.85, Ve=0

current supply ~3x10

-5

A/ µ m  Vh=5.8, Ve=-16

current supply ~7.5x10

-8

A/ µ m

 

Table  6.1  Summary  of  various  test-bias  conditions  and  test-device  structures in Fig.5.4 and Fig.5.5. 

O X

X X

Photon  O Emission

Photon  O Emission

           

Fig.6.6 (a) Light spectrum of SiNLET in various Ve (Vh=5.8V). Higher Ve shows larger intensity. The peak intensity is at 700~800nm in all conditions.

(b) The supply current (Ih) versus the operation voltage of poly (Ve) with a constant Vh of 5.8V. In all bias conditions, the current at n+junction is equal  to p-well (Ih=Ic) and the current at the poly (Ie) is negligible. 

(a) 

(b) 

200 400 600 800 1000 1200 0

500 1000 1500 2000 2500

 

In tens ity  (a.u.)

Wave Length (nm)

 Ve=-13  Ve=-14  Ve=-15  Ve=-16

-17 -16 -15 -14 -13 -12

0.0 2.0x10-8 4.0x10-8 6.0x10-8 8.0x10-8 1.0x10-7

 

 

Ih  (A/

µ

m)

Ve (V)

 Vh=5.8

             

(a) 

Fig.6.7 (a) Light spectrum of SiNLET in various Vh (Ve=-16V). Higher Vh  shows larger intensity. The peak intensity is at 600~700nm in all conditions.

(b) The supply current (Ih) versus the operation voltage of n+ junction (Vh)  with a constant Ve of -16V. In all bias conditions, the current at n+ junction  is equal to p-well (Ih=Ic) and the current at the poly (Ie) is negligible. 

200 400 600 800 1000 1200 0

500 1000 1500 2000 2500 3000

 

 

In te ns it (a .u .)

Wave Length (nm)

Ve=-16

 Vh=4.6  Vh=5  Vh=5.4  Vh=5.8

4.5 5.0 5.5 6.0

0.0 2.0x10-8 4.0x10-8 6.0x10-8 8.0x10-8 1.0x10-7

 

 

Ih  (A /

µ

m)

Vh (V)

 Ve=-16

   

                             

Fig.6.8  Schematic  illustration  of  SiNLET  to  function  as  a  three-terminal  transistor.  The  poly  supplying  electrons  serves  as  the  Drain.  The  n+  junction  supplying  holes  serves  as  the  Source.  The  p-well  controlling  the  lateral  field  serves as the Gate. The nitride traps serve as quantum dots for carrier trapping and recombination. 

       

                       

Fig.6.9 The supply current density versus output light intensity. The data are  extracted from Fig.5.6 and Fig.5.7. 

0.0 2.0x10

-8

4.0x10

-8

6.0x10

-8

8.0x10

-8

0

2000 4000 6000 8000 10000

 

 

Intensity  (a.u .)

Ih (A/ µ m)

     

                     

Fig.6.10 The light intensity as a function of Vc (Vh=5.8V, Ve=-16V). The    threshold voltage of Vc is around 2V to switch SiNLET. 

0 1 2 3 4

0 2000 4000 6000 8000 10000

 

 

Intensi ty  ( a.u .)

Vc (V)

 Vh=5.8, Ve=-16

       

                       

Fig.6.11 The light intensity as a function of Ve and Vh (Vc=0V).   

4.5 0 5.0 5.5 6.0

2000 4000 6000 8000 10000

 

 

In tens ity  ( a.u.)

Vh (V)

 Ve=-16

 Ve=-15

 Ve=-14

 Ve=-13

                   

Fig.6.12  The  light  spectrum  before  and  after  stress.  The  stress condition  and  light  emission  measurement  condition  are  both Vc/Ve/Vh=0/-16/5.8V. 

200 400 600 800 1000 1200 0

500 1000 1500 2000 2500 3000

 

 

Intensity  (a. u .)

Wave Length (nm)

Ve=-16, Vh=5.8  Stress time=0

 Stress time=1 hours

 Stress time=10 hours

           

 

CMOS

h ν

SiNLET

Fig.6.13 Illustration of integration of CMOS and SiNLET devices. 

Conclusion   

 

We investigated a novel flash memory cell named PHINES (Programming by hot  Hole Injection Nitride Electron Storage). PHINES uses a nitride trapping storage cell  structure. Channel FN erasing is performed to raise Vt while programming is done by  lowering  local  Vt  through  band-to-band  hot-hole  injection.  PHINES  uses  backward  read  scheme with  low  power program/erase  operation,  and  physically  2-bits-per-cell  storage  is  achieved.  PHINES  cell  also  shows  good  retention  and  cell  reliability  and  can be arranged in both NOR-type and NAND-type array architectures for code flash  and data flash applications. 

However, PHINES cell suffers the issue of 2-bit interaction due to the backward  read  scheme.  Two-bit  interaction  effect  caused  by  the  local  storage  carriers  and  the  DIBL  will  result  in  the  reduction  of  the  Vt  operation  window.  The  effects  of  the  charge  profile  on  the  Vt  operation  window  are  also  studied  and  characterized. 

Although  a  narrower  electron  distribution,  higher  electron  storage  density,  better  program/erase algorithms, and a lower read-Vd can be used to increase the operation  window, 2-bit interaction effect can not be eliminated completely and will get worse  in  a scaled device. To  overcome  this issue, a  novel BTB  sensing  scheme and a  new  modified  NAND-type  array  are  introduced  in  chapter  3.  Since  BTB  current  is  generated  locally  between  the  drain  (or  source)  and  P-well,  the  sensing  currents  of  two bits are independent and will not affect each other. BTB-PHINES eliminates the  2-bit interaction effect and a large operation window can be obtained by BTB sensing  scheme.  We  also  construct  a  novel  modified  NAND-type  array  to  realize  2-bits-per-cell  operation  and  high-density  storage.  BTB-PHINES  memory  cell  demonstrates  a  fast  cell  programming  speed  (≦60µs)  with  a  low  programming  current (≦100nA/cell), and a high programming throughput can be achieved. Besides,  the sensing current shows weak temperature dependence, and good cell reliability is  demonstrated. 

In  chapter  4,  we  compare  the  scaling  challenges  of  PHINES  and  floating  gate  technologies. PHINES technology can achieve compatible performance and bit size to  floating gate technologies for most data flash memory applications. According to our  evaluations,  1-bit  PHINES  suffers  the  scaling  challenges  of  few  storage  carriers,  inter-WL  leakage/breakdown,  and  cell  punch  beyond  15nm  CMOS  generation. 

Two-bit  PHINES  suffers  scaling challenges  of  the  distribution  of a  programmed  bit, 

scalability,  and  15nm  generation  for  1-bit-per-cell  storage  and  30nm  generation  for  2-bits-per-cell storage are feasible in NAND-type array architecture. 

In  chapter  5,  a  novel  non-volatile  memory  cell  named  PREM  (Programmable  Resistor  with  Erase-less  Memory)  is  constructed  for  SOC  and  embedded  flash  memory  applications.  Instead  of  the  conventional  ì eraseî   operation,  PREM  adjusts  the  reference  level  to  reset  the  data.  By  utilizing  the  progressive  breakdown  of  ultra-thin  oxide  and  the  new  ì Erase-lessî   operation,  PREM  can  realize  MTP  and/or  MLC.  Only  one  extra  or  none  mask  is  needed  with  CMOS  standard  process.  No  degradation  of  cell  retention,  no  program  disturbance,  and  no  read  disturbance  are  observed, and the cell  reliability is guaranteed. PREMís  low  voltage  operation,  high  scalability and simple process are superior for SOC or very low cost and high-density  storage applications. 

In chapter 6, we reported a novel SiNLET (Silicon-Nitride based Light-Emitting  Transistor)  with  high  light  emission  efficiency  and  low  current  consumption  (<10-7A/µm)  in  a  small  device  area  (~0.616µm2).  This  three-terminal  electroluminescence  device  uses  a  SONOS-type  device  structure,  and  its  process  is  compatible  to  standard  CMOS  devices.  Photons  are  generated  by  Fowler-Nordheim  electron  tunnel-injection,  band-to-band  tunneling  induced  hot-hole  injection,  and  carrier  scattering/trapping/recombination  via  nitride  traps.  SiNLET  shows  peak  intensity at around 700nm, and its light spectrum contains infrared and visible light. 

SiNLET can modulate the output light intensity by controlling the input voltages, and  functions as a light-emitting transistor. SiNLET has demonstrated its high feasibility  for the application of optical interconnects in ULSI. 

 

Chapter 1

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Chou, C.H. Chen, Tahui Wang, Wenchi Ting, Sam Pan, and C.Y. Lu, ”Novel Operation Schemes to Improve Device Reliability in a Localized Trapping Storage SONOS-type Flash Memory,” IEEE IEDM Tech. Dig., pp. 7.5.1-7.5.4, 2003

[2.10] W.J. Tsai, S.H.Gu, N.K. Zous, C.C. Yeh, C.C. Liu, C.H. Chen, Tahui Wang, Sam Pan, and C.Y. Lu, ” Cause of Data Retention Loss in a Nitride-Based Localized Trapping Storage Flash Memory Cell,” Proc. Int. Reliab, Phys.

Symp., pp. 34-38, 2001

Flash Memory using Al2O3 as Charge Trapping Layer,” Non-Volatile Semiconductor Memory Workshop, pp. 60-61, 2003.

[2.12] C.H. Lee, K.I. Choi, M.K. Cho, Y.H. Song, K.C. Park, and K. Kim, “A Novel SONOS Structure of SiO2/SiN/Al2O3 with TaN Metal Gate for Multi-Giga Bit Flash Memories”, IEEE IEDM Tech. Dig., pp. 26.5.1-26.5.4, 2003 [2.13] J. Bu, and M. H. White, ”Effects of Two-step High Temperature Deuterium Anneals on SONOS Nonvolatile Memory Devices”, IEEE Electron Device Lett., vol. 22, pp. 17-19, Jan. 2001

[2.14] W.J. Tsai, C.C. Yeh, C.C. Liu, C.J. Hwang, Y.C. Chen, Thomas Liang, Anderson Liu, R.B. Chang, N.K. Zous, M.I. Liu, Tahui Wang, Wenchi Ting, Joseph Ku, and Chih-Yuan Lu, “Novel PHINES flash EEPROM with 0.046µm2 bit size for giga-bit era application,” Non-Volatile Semiconductor Memory Workshop, pp. 79-82, 2004.

[2.15] C. Chen, and T.P. Ma, “Direct Lateral Profiling of Hot-carrier induced Oxide Charge and Interface Traps in Thin MOSFET’s,” IEEE Trans. on Elect. Dev., vol.45, pp.512-520, 1998

[2.16] C.C. Yeh,W.J. Tsai, T.C. Lu, S.K. Cho, Tahui Wang, Sam Pan and Chih-Yuan Lu, “A Modified Read Scheme to Improve Read Disturb and Second Bit Effect in a Scaled MXVAND Flash Memory Cell,” Non-Volatile Semiconductor Memory Workshop, pp.44-45, 2003

[2.17] J.Z. Peng, S. Haddad, H. Fang, C. Chang, S. Longoor, B. Ho, Y. Sun, D. Liu, Y.

Tang, J. Hsu, S. Luan, and J. Lien, “ Flash EPROM Endurance Simulation using Physics-based Models,” IEEE IEDM Tech. Dig., pp.295-298, 1994

[2.18] T. Wang, L.P. Chiang, N.K. Zous, T.E. Chang, and C. Huang,

“Characterization of Various Stress-Induced Oxide Traps in MOSFET’s by using a Subthreshold Transient Current Technique,” IEEE Trans. on Elect.

Dev., vol. 45, pp.1791-1796, 1998.

[2.19] W.J. Tsai, C.C. Yeh, N.K. Zous, C.C. Liu, S.K. Cho, T. Wang, Sam Pan, and C.Y. Lu, “Positive Oxide Charge-Enhanced Read Disturb in a Localized Trapping Storage Flash Memory Cell,” IEEE Trans. on Elect. Dev., vol.51, pp.434-439, 2004

[2.20] J. Chen, J. Hsu, S. Luan, Y. Tang, D. Liu, S. Haddad, C. Chang, S. Longcor, and J. Lien, “Short Channel Enhanced Degradation During Discharge of Flash EEPROM Memory Cell”, IEEE IEDM Tech. Digest, pp.331-334, 1995

[2.21] C.C. Yeh, Y.Y. Liao, W.J. Tsai, T.C. Lu, T.F. Ou, H.L. Kao, Tahui Wang*, WenChi Ting, Joseph Ku, and Chih-Yuan Lu, “Highly Scalable NAND-type PHINES Flash Memory for Data Flash Applications,” Non-Volatile

Chapter 3

[3.1] Y.S. Yim, K.S. Shin, S.H. Hur, J.D. Lee, I.G. Baik, H.S. Kim, S.J. Chai, E.Y.

Choi, M.C. Park, D.S. Eun, S.B. Lee, H.J. Lim, S.P. Youn, S.H. Lee, T.J. Kim, H.S. Kim, K.C. Park, and K.N. Kim, “70nm NAND Flash Technology with 0.025µm2 Cell Size for 4Gb Flash Memory,” IEEE IEDM Tech. Dig., 34-1, 2003

[3.2] J.D. Lee, S.H. Hur, and J.D. Choi, “Effects of Floating-Gate Interference on NAND Flash Memory Cell Operation,” IEEE Electron Device Lett., Vol. 23, pp. 264-266, May 2002

[3.3] Y.S. Shin, “Non-volatile Memory Technologies for Beyond 2010,” Symposium on VLSI Cir. Dig., pp.156-159, 2005

[3.4] C.H. Lee, S.H. Hur, Y.S. Shin, J.H. Choi, D.G. Park, and K. Kim, “A Novel Structure of SiO2/SiN/High-k Dielectrics, Al2O3 for SONOS Type Flash Memory,” Conf. Solid State Devices and Materials, pp. 162-163, 2002

[3.5] C.C. Yeh,W.J. Tsai, M.I. Liu, T.C. Lu, S.K. Cho, C.J. Lin, Tahui Wang, Sam Pan, and C.Y. Lu, “PHINES: a Novel Low Power Program/Erase, Small Pitch, 2-Bit per Cell Flash Memory,” IEEE IEDM Tech. Dig., pp. 37.4.1-37.4.4, 2002 [3.6] J.H. Park, S.H. Hur, J.H. Lee, J.T. Park, J.S. Sel, J.W. Kim, S.B. Song, J.Y.

Lee, J.H. Lee, S.J. Son, Y.S. Kim, M.C. Park, S.J. Chai, J.D. Choi, U.I. Chung, J.T. Moon, K.T. Kim, K. Kim, and B.I. Ryu, “8Gb MLC (Multi-Level Cell) NAND Flash Memory using 63nm Process Technology,” IEEE IEDM Tech.

Dig., pp. 873-876, 2004

Chapter 4

[4.1] Y.S. Shin, “Non-volatile Memory Technologies for Beyond 2010,” Symposium on VLSI Cir. Dig., pp.156-159, 2005

[4.2] R. Koval, V. Bhachawat, C. Chang, M. Hajra, D. Kencke, Y. Kim, C. Kuo, T.

Parent, M. Wei, B.J. Woo, A. Fazio, “Flash ETOXTM Virtual Ground Architecture: A Future Scaling Direction,” Symposium on VLSI Tech. Dig., pp.204-205, 2005

[4.3] M. Tanaka, S. Saida, Y. Mitani, I. Mizushima, and Y. Tsunashima, “Highly Reliable MONOS Devices with Optimized Silicon Nitride Film Having Deuterium Terminated Charge Traps,” IEEE IEDM Tech. Dig., pp. 9.5.1-9.5.4, 2002

[4.4] S.J. Ahn, Y.J. Song, C.W. Jeong, J.M. Shin, Y. Fao, Y.N. Hwang, S.H. Lee,

Memory of 64Mb and Beyond,” IEEE IEDM Tech. Dig., pp. 907-910, 2004 [4.5] C.C. Hung, M.J. Kao, Y.S. Chen, Y.H. Wang, H.H. Hsu, C.M. Chen, Y.J. Lee,

W.C. Chen, J.Y. Lee, W.S. Chen, W.C. Lin, K.H. Shen, J.H. Wei, L.C. Wang, K.L. Chen, S. Chao, D.D. Tang, and M.J. Tsai, “High Density and Low Power Design of MRAM,” IEEE IEDM Tech. Dig., pp. 575-578, 2004

[4.6] J.H. Park, H.J. Joo, S.K. Kang, Y.M. Kang, H.S. Rhie, B.J. Koo, S.Y. Lee, B.J.

Bae, J.E. Lim, H.S. Jeong, and Kinam Kim, “Fully Logic Compatible (1.6V Vcc, 2 Additional FRAM Masks) Highly Reliable sub 10F2 Embedded FRAM with Advanced Firect Via Technology and Robust 100nm Thick MOCVD PZT Technology),” IEEE IEDM Tech. Dig., pp. 591-594, 2004

[4.7] C. Chen, and T.P. Ma, “Direct Lateral Profiling of Hot-carrier induced Oxide Charge and Interface Traps in Thin MOSFET’s,” IEEE Trans. on Elect. Dev., vol.45, pp.512-520, 1998

Chapter 5

[5.1] C. de Graaf, P.H. Woerlee, C.M. Hart, H. Lifka, P.W.H de Vreede, P.J.M.

Janssen, F.J. Sluijs, and G.M. Paulzen, “A Novel High-Density Low-Cost Diode Programmable Read Only Memory,” IEEE IEDM Tech. Dig., pp.189-192, 1996

[5.2] S.B. Herner, A. Bandyopadhyay, S.V. Dunton, V. Eckert, J. Gu, K.J. Hsia, S.

Hu, C. Jahn, D. Kidwell, M. Konevecki, M. Mahajani, K. Park, C. Petti, S.R.

Hu, C. Jahn, D. Kidwell, M. Konevecki, M. Mahajani, K. Park, C. Petti, S.R.

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