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燃料處理系統最佳化控制系統設計 翁頂清、蔡渙良

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燃料處理系統最佳化控制系統設計 翁頂清、蔡渙良

E-mail: [email protected]

摘 要

本文利用線性高斯二次和迴路轉移函數回歸(LQG/LTR)控制架構,建立一個燃料處理系統(Fuel processing system, FPS)的最 佳控制系統,其中包含前饋控制器及狀態迴授控制器,此系統是針對一個以天然氣和大氣中的氧氣為燃料經由觸媒部分氧 化反應器(CPO),重組後所得到的合成氣體經由純化後,將所產生的氫氣供給質子交換膜燃料電池(PEMFC)堆。此控制系 統經由Matlb/Simulink製作成為數學模組,進行動態模擬以及分析系統效能。模擬結果顯示補償系統在時域與頻域都有良 好的性能響應。

關鍵詞 : 燃料處理系統 ; 觸媒不完全氧化反應器 ; 質子交換膜燃料池 ; Matlab/Simulink 目錄

授權書...iii 中文摘要...iv 英文摘要...v 誌 謝...vi 目錄...vii 圖目錄...x 表目

錄...xii 第一章 緒論...1 1.1前言...1 1.2研究動機與方 法...2 1.3文獻回顧...4 1.4論文架構...5 第二章 理論基礎與研究 方法.... ...6 2.1燃料處理系統動態模型...6 2.1.1鼓風機...8 2.1.2熱交換

器...9 2.1.3燃料供應以及脫硫器...10 2.1.4混合器...11 2.1.5觸媒部 分氧化(CPO)反應器...12 2.1.6 水煤氣轉移和優先氧化反應爐(WPO)...17 2.1.7燃料電池(PEMFC)陽 極...18 2.2研究方法...19 2.3最佳化控制法推導...21 2.3.1卡門濾波器設 計...23 2.3.2迴路轉移函數回歸...25 第三章 數學模型建立...31 3.1 以Matlab/Simulink建立數學模型流程...31 3.2以Simulink 建立受控體模型...32 3.2.1鼓風機模型建 立...32 3.2.2熱交換器模型建立...33 3.2.3燃料供應及脫硫器模組...34 3.2.4混 合器模組...35 3.2.5觸媒部分氧化(CPO)反應器模組...35 3.2.6水煤氣轉移和優先氧化反應 爐(WPO)模型建立...36 3.2.7燃料電池(PEMFC)模組...37 3.3以Simulink 建立控制器模型...38 3.3.1建立CPO_Based FPS數學模型...38 3.3.2建立前饋控制器模型...39 3.3.3建立狀態回授控制器數 學模型...40 3.3.4完整模型...40 3.4模擬結果...41 3.4.1系統抵抗雜訊能力 之分析...50 第四章 結論...55 4.1結論...55 4.2本文貢

獻...55 4.3未來展望...56 參考文獻...57 自傳以及就學期 間所發表的文獻...60

參考文獻

[1]A.L. Dicks, ‘‘Hydrogen generation from natural gas for the fuel cell systems of tomorrow,” Journal of Power Sources, vol. 61, [2]S. Ahmed and M. Krumpelt, “Hydrogen from hydrocarbon fuels for fuel cells,” International Journal of Hydrogen Energy, vol.

[3]L.F. Brown, “A comparative study of fuels for on-board hydrogen production for fuel-cell-powered automobiles,” International Journal of Hydrogen Energy, vol. 26, pp. 381-397, 2001.

[4]D. Megede, “Fuel processors for fuel cell vehicles,” J. Power Sources,vol. 106, pp. 35–41, 2002.

[5]T. Springer, R. Rockward, T. Zawodzinski, and S. Gottesfeld, “Modelfor polymer electrolyte fuel cell operation on reformate feed,”

J.Electrochem.Soc., vol. 148, pp. A11–A23, 2001.

[6]Chang H. S. and H. L. Tsai (2006) General LQG/LTR Control of Catalytic-Partial-Oxidation-Based Fuel Processing System. Proceedings of 2006 CACS Automatic Control Conference, Tamsui, Taiwan, 388-396.

[7]Dicks, A. L. (1996) Hydrogen generation from natural gas for the fuel cell systems of tomorrow. Journal of Power Sources, 61(1-2), 113-124.

[8]J. T. Pukrushpan, Modeling and control of fuel cell systems and fuel processors, Ph.D. dissertation, Univ. Michigan, Ann Arbor, MI, 2003.

[9]J. T. Pukrushpan, A. G. Stefanopoulou, S. Varigonda, L. M. Pedersen, S. Ghosh, and Huei Peng, “Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Applications”, Proceeding of the American Control Conference, Vol. 3, June 4-6, pp.

2030-2036, 2003.

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[10]J. T. Pukrushpan, A. G. Stefanopoulou, S. Varigonda, L. M.Pedersen, S. Ghosh, and Huei Peng, “Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Applications”, IEEE Transactions on Control System Technology, Vol. 13, No. 1, pp. 3-14, 2005.

[11]V. Recupero, L. Pino, R.D. Leonardo, M. Lagana, andG. Maggio, “Hydrogen generator, via catalytic partial oxidation of methane for fuel cells,” Journal of Power Sources, vol. 71, pp.

[12]J. Zhu, D. Zhang, and K.D. King, “Reforming of CH4 by partial oxidation: thermodynamic and kinetic analyses,” Fuel, vol.

[13]Tsai, H. L. and C. H. Wang (2007) Optimal Temperature Control for Hydrogen Reformer by Generalized Linear Quadratic Gaussian / Loop [14]J. C. Doyle and G. Stein, “Multivariable Feedback Design: Concepts for a Classical / Modern Synthesis,” IEEE Transaction on Automatic Control, Vol. AC-26, No. 1, pp. 4-16, 1981.

[15]G. Stein and M. Athan, “The LQG/LTR Procedure for Multivariable Feedback Control Design,” IEEE Transaction on Automatic Control, Vol. AC-32, No. 2, pp. 105-114, 1987.

[16]A. L. Larentis, N. S. Resende, V. M. Salim, and J. C. Pinto, “Modeling and optimization of the combined carbon dioxide reforming and partial oxidation of natural gas,” Appllied Catalysis A: General, Vol. 215, No. 1-2, pp. 211-224, 2001.

[17]K. Ledjeff-Hey, J. Rose, and R. Wolters, “CO2-scrubbing and methanation as purification system for PEFC,” Journal of Power Sources, Vol. 86, No. 1-2, pp. 556-561, 2000.

[18]M. Levent, “Water–gas shift reaction over porous catalyst: temperature and reactant concentration distribution,” International Journal of Hydrogen Energy, Vol. 26, No. 6, pp. 551-558, 2001.

[19]劉家合,“質子交換膜燃料系統控制”,台灣科技大學化學工程研究所碩士論 文,2005。

[20]陳泓政,“燃料電池用之甲醇重組器氫氣產生研究”,航空太空工程,2002。

[21]蔡武田,“質子交換膜燃料電池之非線性電路分析與控制”中興大學,2004。

[22]李書鋒,“質子交換膜燃料電池性能之理論探討”大葉大學,2004

參考文獻

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