第七章 結論與建議
7.2 建議與後續研究
由於應用範圍廣泛,期能與產業界配合,本研究成果可用於食、
衣、住、行和空氣清淨、水質淨化等相關產業,甚至可結合目前熱門 的太陽能電池 產業。以所 謂的染料敏 化奈米太陽能 (Dye sensitized solar cell,DSSC)電池為例,如圖 7.1 所示,其主要結構由三部份組 成:(1)染料敏化的二氧化鈦奈米薄膜工作電極(由含氟錫氧化物 FTO 導電玻璃、奈米 TiO2半導體薄膜和染料敏化劑組成)、(2)含有 I–/I3–的 電解質、(3)對電極 (Counter Electrode)。由此可知染料敏化太陽能電 池是由二氧化鈦所製成的,因為二氧化鈦只會吸收紫外線波段的光,
無法利用可見光來發電,所以利用染料來當收光介質也就是光敏劑,
用來吸收可見光,故稱之為染料敏化太陽能電池。是故,欲提升可見 光之利用率,本研究所製備之可見光型二氧化鈦將有助染料敏化太陽 能電池之效能提升,而玻璃並非必然的 DSSC 基材,其他具撓屈性透 明材料亦可使用,如果可撓式 DSSC 可以結合其它建材基底,未來的 生活空間不僅環保、節能甚至可儲能,將可提供許多創新發展的空 間,以改善吾人的生活環境品質。
圖 7.1 染料敏化太陽能電池工作原理示意圖
Light
Electrolyte ( S+/ S )
( S+/ S*)
( A / A-)
Load
Anchored dye
Counter electrode TCO
hν △V e
-e
-e
-e
-e -e
-cb
vb n-SC ( TiO2 )
-0.9
2.5 0.8 0.2 -0.7
V, vs SCE Pt-loaded CNT arrays
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