• 沒有找到結果。

鎂鋰合金的高比強度與優秀的延展性勢必將使其成為未來輕金屬中的主流,

此研究對 LZ91 的腐蝕進行了一系列的探討,然而若想更深入了解鎂鋰合金的腐蝕 行為則以下是兩點可行的方向:

1. 測試不同雜質或合金元素對鎂鋰合金腐蝕的影響,特別是於本研究之 LZ91 腐

蝕產物中包含的一些雜質/合金元素(如鐵、錳、鈣等)。

2. 確認是否雙相效應不明顯的情況為大部分鎂鋰合金中的共通現象,並可以理論、

計算等方式輔助驗證,若此結果為真則可以許多純鎂研究中的結果來解釋、預 測鎂鋰合金的腐蝕表現。

防蝕處理方面,鈦酸鹽化成為一較少被討論的化成系統,然而經本研究證實其 可有效延緩 LZ91 的腐蝕,加上經長時間的嚴苛浸泡腐蝕後證實二氧化鈦/二氧化 矽層仍存在於 LZ91 表面,故以二氧化鈦的高穩定性嘗試鈍化鎂合金乃一可行之 道。然而此鈦酸鹽化成系統仍存在許多問題,若想進一步增進防蝕能力、推廣此系 統則可以下列出的三點方向思考:

1. 四氯化鈦溶液易揮發反應,穩定性不佳,若能更換產生二氧化鈦的反應物則可 解決此一問題。

2. 防止氫氧化鎂的生成,使用非水溶液系統或許是一個方向,然若如此則必須考 慮六氟矽酸與四氯化鈦於非水溶液中的反應問題,另外化成液溫度、反應物濃 度等控制變因也可能略為改善脫水裂紋。

3. 氟化鎂並非不可或缺的,鈦酸鹽化成膜中主要的抗蝕能力來自二氧化鈦/二 氧化矽,故可考慮不使用含氟的反應物以增加化成液的安全性、環保性。

參考文獻

1.H. E. Friedrich, and B. L. Mordlike, Magnesium Technology - Metallurgy, Design Data, Applications, Springer Verlag GmbH, Germany (2006)

2.Material Properties Handbook. Volume 3. Magnesium Nickel and Titanium Alloys, Advisory Group for Aeronautical Research and Development, Paris (1967)

3.K. U. Kainer, Magnesium Alloys and their Applications, Wiley-VCH Verlag GmbH, Germany, (2000)

4.F. Witte, The history of biodegradable magnesium implants: a review, Acta Biomaterialia, 1680-1692, 6 (2010)

5.B. L. Mordike, and T. Ebert, Magnesium Properties - applications – potential, Materials Science and Engineering, 37-45, 302 (2001)

6.H. Watarai, Trend of research and development for magnesium alloys - reducing the weight of structural materials in motor vehicles, Science & Technology, 87-97, 7, (2006)

7.H. Haferkamp, M. Niemeyer, R. Boehm, U. Holzkamp, C. Jaschik, and V. Kaese, Development, Processing and Applications Range of Magnesium Lithium Alloys, Materials Science Forum, 31-42, 350-351 (2000)

8.W. Xu, N. Birbilis, G. Sha, Y. Wang, J. E. Daniels, Y. Xiao, and M. Ferry, A high-specific-strength and corrosion-resistant magnesium alloy, Nature Materials, 1229-1235, 14 (2015)

9.M. Tsujikawa, S. Adachi, Y. Abe, S. Oki, K. Nakata, and M. Kamita, Corrosion protection of Mg-Li alloy by plasma thermal spraying of aluminum, Plasma

Processes and Polymers, 5593-5596, 4 (2007)

10.R. Wu, Y. Yan, G. Wang, L. E. Murr, W. Han, Z. Zhang, and M. Zhang, Recent progress in magnesium–lithium alloys, International Materials Reviews, 65-100, 60 (2015) 11.G. Wang, N. Cao, and Y. Wang, Characteristics and corrosion studies of zinc–

manganese phosphate coatings on magnesium–lithium alloy, Royal Society of Chemistry Advances, 59772-59778, 4 (2014)

12.J.E. Gray, and B. Luan, Protective coatings on magnesium and its alloys — a critical review, Journal of Alloys and Compounds, 88-113, 336 (2002)

13.F. Cao, G. Song, and A. Atrens, Corrosion and passivation of magnesium alloys, Corrosion Science, 835-845, 111 (2016)

14.A. Atrens, G. Song, M. Liu, Z. Shi, F. Cao, and M. S. Dargusch, Review of recent developments in the field of magnesium corrosion, Advanced Engineering Materials, 400-453, 4 (2015)

15.C. Liu, Y. Xin, X. Tian, and P. K. Chu, Corrosion behavior of AZ91 magnesium alloy treated by plasma immersion ion implantation and deposition in artificial physiological fluids, Thin Solid Films, 422-427, 516 (2007)

16.Y. Xin, C. Liu, W. Zhang, J. Jiang, G. Tang, X. Tian, and P. K. Chu, Electrochemical behavior Al2O3/Al coated surgical AZ91 magnesium alloy in simulated body fluids, Journal of the Electrochemical Society, C178-C182, 155 (2008)

17.Y. Sakai, H. Norimatsu, Y. Saito, H. Inomata, and T. Mazuno, Silica coating on plastics by liquid phase deposition (LPD) method, Thin Solid Films, 294-298, 392 (2001) 18.P. Schneider, R. Sigel, M. M. Lange, F. Beier, F. U. Renner, and A. Erbe, Activation

and fluoride-assisted phosphating of aluminum-silicon-coated steel, ACS applied materials & interfaces, 4224-4232, 5 (2013)

19.M. Mosiałek, G. Mordarski, P. Nowak, W. Simka, G. Nawrat, M. Hanke, R. P. Socha,

and J. Michalska, Phosphate–permanganate conversion coatings on the AZ81 magnesium alloy: SEM,EIS and XPS studies, Surface & Coatings Technology, 51-62, 206 (2011)

20.C. E. Barchiche, E. Rocca, C. Juers, J. Hazan, and J. Steinmetz, Corrosion resistance of plasma-anodized AZ91D magnesium alloy by electrochemical methods, Electrochimica Acta, 417-425, 53 (2007)

21.Y. Xin, C. Liu, W. Zhang, K. Huo, G. Tang, X. Tian, and P. K. Chu, Corrosion resistance of ZrO2–Zr-coated biodegradable surgical magnesium alloy, Journal of Materials Research, 312-319, 23 (2008)

22.Y. Zhang, C. Yan, F. Wang, and W. Li, Electrochemical behavior of anodized Mg alloy AZ91D in chloride containing aqueous solution, Corrosion Science, 2816-2831, 47 (2005)

23.H. Duan, K. Du, C. Yan, and F. Wang, Electrochemical corrosion behavior of composite coatings of sealed MAO film on magnesium alloy AZ91D, Electrochimica Acta, 2898-2908, 51 (2006)

24.C. S. Lin, H. C. Lin, K. M. Lin, and W. C. Lai, Formation and properties of stannate conversion coatings on AZ61 magnesium alloys, Corrosion Science, 93-109, 48 (2006)

25.C. S. Lin, and S. K. Fang, Formation of cerium conversion coatings on AZ31 magnesium alloys, Journal of The Electrochemical Society, B54-B59, 152 (2005) 26.C. S. Lin, C. Y. Lee, W. C. Li, Y. S. Chen, and G. N. Fang, Formation of

phosphate/permanganate conversion coating on AZ31 magnesium alloy, Journal of The Electrochemical Society, B90-B96, 153 (2006)

27.C. S. Lin, and Y. C. Fu, Characterization of anodic films on AZ31 magnesium alloys in alkaline solutions containing fluoride and phosphate anions, Journal of The

Electrochemical Society, B417-B424, 153 (2006)

28.Y. L. Lee, Y. R. Chu, W. C. Li, and C. S. Lin, Effect of permanganate concentration on the formation and properties of phosphate/permanganate conversion coating on AZ31 magnesium alloy, Corrosion Science, 74-81, 70 (2013)

29.Y. C. Yang, C. Y. Tsai, Y. H. Huang, and C. S. Lin, Formation mechanism and properties of titanate conversion coating on AZ31 magnesium alloy, Journal of The Electrochemical Society, C226-C232, 159 (2012)

30.S. Y. Jian, Y. R. Chu, and C. S. Lin, Permanganate conversion coating on AZ31 magnesium alloys with enhanced corrosion resistance, Corrosion Science, 301-309, 93 (2015)

31.Y. L. Lee, F. J. Chen, and C. S. Lin, Corrosion resistance studies of cerium conversion coating with a fluoride-free pretreatment on AZ91D magnesium alloy, Journal of The Electrochemical Society, C28-C35, 160 (2013)

32.Y. L. Lee, Y. R. Chu, F. J. Chen, and C. S. Lin, Mechanism of the formation of stannate and cerium conversion coatings on AZ91D magnesium alloys, Applied Surface Science, 578-585, 276 (2013)

33.H. Hoche, H. Scheerer, D. Probst, E. Broszeit, and C. Berger, Development of a plasma surface treatment for magnesium alloys to ensure sufficient wear and corrosion resistance, Surface & Coatings Technology, 1018-1023, 174-175 (2003)

34.F. Hollstein, R. Wiedemann, and J. Scholz, Characteristics of PVD-coatings on AZ31hp magnesium alloys, Surface & Coatings Technology, 261-268, 162 (2003) 35.T. Ishizaki, J. Hieda, N. Saito, N. Saito, and O. Takai, Corrosion resistance and

chemical stability of super-hydrophobic film deposited on magnesium alloy AZ31 by microwave plasma-enhanced chemical vapor deposition, Electrochimica Acta, 7094-7101, 55 (2010)

36.C. Blawert, W. Dietzel, E. Ghali, and G. Song, Anodizing treatments for magnesium alloys and their effect on corrosion resistance in various environments, Advanced Engineering Materials, 511-533, 8 (2006)

37.P. Shi, W. F. Ng, M. H. Wong, and F. T. Cheng, Improvement of corrosion resistance of pure magnesium in Hanks’ solution by microarc oxidation with sol–gel TiO2

sealing, Journal of Alloys and Compounds, 286-292, 469 (2009)

38.H. F. Guo, and M. Z. An, Growth of ceramic coatings on AZ91D magnesium alloys by micro-arc oxidation in aluminate–fluoride solutions and evaluation of corrosion resistance, Applied Surface Science,229-238, 246 (2005)

39.T. M. Yue, Y. P. Su, and H. O. Yang, Laser cladding of Zr65Al7.5Ni10Cu17.5 amorphous alloy on magnesium, Materials Letters, 209-212, 61 (2007)

40.S. Ignat, P. Sallamand, D. Grevey, and M. Lambertin, Magnesium alloys laser (Nd:YAG) cladding and alloying with side injection of aluminium powder, Applied Surface Science, 214-134, 225 (2004)

41.S. A. Katz, and H. Salem, The toxicology of chromium with respect to its chemical speciation: a review, Journal of Applied Toxicology, 217-224, 13 (1993)

42.J. H. Duffus, Chemical speciation terminology: chromium chemistry and cancer, Mineralogical Magazine, 557-562, 69 (2005)

43.E. McCafferty, Introduction to corrosion science, Springer, New York (2010)

44.M. Pourbaix, Atlas of Electrochemical Equilibria In Aqueous Solutions 2nd edition, National Association of Corrosion, Texas (1974)

45.C. Vargel, Corrosion of Aluminium 1st edition, Elsevier Science, UK (2004)

46.T. H. Nguyen, and R. T. Foley, The chemical nature of aluminum corrosion III. the dissolution mechanism of aluminum oxide and aluminum powder in various electrolytes, Journal of the Electrochemical Society, 2563-2566, 127 (1980)

47.J. Pouilleau, D. Devilliers, F. Garrido, S. Durand-Vidal, and E. Mache, Structure and composition of passive titanium oxide films, Materials Science and Engineering: B, 235-243, 47 (1997)

48.E. J. Kelly, Electrochemical Behavior of Titanium, Modern Aspects of Electrochemistry No. 14, 319-424, Springer US, New York (1982)

49.G. Song, and A. Atrens, Understanding magnesium corrosion a framework for improved alloy performance, Advanced Engineering Materials, 837-858, 5 (2003) 50.G. Song, A. Atrens, D. St. John, X. Wu, and J. Nairn, The anodic dissolution of

magnesium in chloride and sulphate solutions, Corrosion Science, 1981-2004, 39 (1997)

51.J. H. Nordlien, S. Ono, and N. Masuko, Morphology and structure of oxide films formed on magnesium by exposure to air and water, Journal of The Electrochemical Society, 3320-3322, 142 (1995)

52.R. E. Bedworth, and N. B. Pilling, The oxidation of metals at high temperatures, Journal of the Institute of Metals, 529-582, 29 (1923)

53.N. J. Ricketts, and S. P. Cashion, Hydrofluorocarbons as a replacement for sulphur hexafluoride in magnesium processing, Magnesium Technology 2001, 31-36, The Minerals, Metals & Materials Society, Pennsylvania (2001)

54.J. Chen, J. Wang, E. Han, J. Dong, and W. Ke, AC impedance spectroscopy study of the corrosion behavior of an AZ91 magnesium alloy in 0.1M sodium sulfate solution, Electrochimica Acta, 3299-3309, 52 (2007)

55.A. A. Aal, Protective coating for magnesium alloy, Journal of Material Science, 2947-2954, 43 (2008)

56.F. Zucchi, A. Frignani, V. Grassi, G. Trabanelli, and C. Monticelli, Stannate and permanganate conversion coatings on AZ31 magnesium alloy, Corrosion Science,

4542-4552, 49 (2007)

57.R. Lindström, L. G. Johansson, G. E. Thompson, P. Skeldon, and J. E. Svensson, Corrosion of magnesium in humid air, Corrosion Science, 1141-1158, 46 (2004) 58.N. Cabrera, and N. F. Mott, Theory of the oxidation of metals, Reports on progress in

physics, 163-184, 12 (1949)

59.G. L. Makar, and J. Kruger, Corrosion of magnesium, International materials reviews, 138-153, 38 (1993)

60.S. Thomas, N. V. Medhekar, G. S. Frankel, and N. Birbilis, Corrosion mechanism and hydrogen evolution on Mg, Current Opinion in Solid State and Materials Science, 85-94, 19 (2015)

61.M. P. Staiger, A. M. Pietak, J. Huadmai, and G. Dias, Magnesium and its alloys as orthopedic biomaterials: a review, Biomaterials, 1728-1734, 27 (2006)

62.L. Tomcsanyi, K. Varga, I. Bartik, H. Horányi, and E. Maleczki, Electrochemical study of the pitting corrosion of aluminium and its alloys—II. Study of the interaction of chloride ions with a passive film on aluminium and initiation of pitting corrosion, Electrochimica Acta, 855-859, 34 (1989)

63.Y. Xin, K. Huo, H. Tao, G. Tang, and P. K. Chu, Influence of aggressive ions on the degradation behavior of biomedical magnesium alloy in physiological environment, Acta Biomaterialia, 2008-2015, 4 (2008)

64.L. Wang, T. Shinohara, B. P. Zhang, Influence of chloride, sulfate and bicarbonate anions on the corrosion behavior of AZ31 magnesium alloy, Journal of Alloys and Compounds, 500-507, 496 (2010)

65.G. Baril, G. Galicia, C. Deslouis, N. Pébère, B. Tribollet, and V. Vivier, An impedance investigation of the mechanism of pure magnesium corrosion in sodium sulfate solutions, Journal of The Electrochemical Society, C108-C113, 154 (2007)

66.G. Baril, and N. Pébère, The corrosion of pure magnesium in aerated and deaerated sodium sulphate solutions, Corrosion Science, 471-484, 43 (2001)

67.G. Song, and A. Atrens, Corrosion mechanisms of magnesium alloys, Advanced Engineering Materials, 11-33, 1 (1999)

68.W. Beetz, XXXIV. On the development of hydrogen from the anode, Philosophical Magazine Series 4, 269-278, 32 (1866)

69.W. J. James, M. E. Straumanis, B. K. Bhatia, and J. W. Johnson, The difference effect on magnesium dissolving in acids, Journal of the Electrochemical Society, 1117-1120, 110 (1963)

70.A. Atrens, and W. Dietzel, The negative difference effect and unipositive Mg+, Advanced Engineering Materials, 292, 9 (2007)

71.G. Song, A. Atrens, D. St. John, J. Nairn, and Y. Li, The electrochemical corrosion of pure magnesium in 1N NaCl, Corrosion Science, 855-875, 39 (1997)

72.J. W. Turrentine, Reversed Electrolysis, The Journal of Physical Chemistry, 448-467, 12 (1907)

73.R. L. Petty, A. W. Davidson, and J. Kleinberg, The anodic oxidation of magnesium metal: evidence for the existence of unipositive magnesium, Journal of the American Chemical Society, 363-366, 76 (1954)

74.G. R. Hoey, and M. Cohen, Corrosion of anodically and cathodically polarized magnesium in aqueous media, Journal of the Electrochemical Society, 245-250, 105 (1958)

75.G. L. Makar, and J. Kruger, Corrosion studies of rapidly solidified magnesium alloys, Journal of the Electrochemical Society, 414-421, 137 (1990)

76.M. E. Stroumanis, and B. K. Bhatia, Disintegration of magnesium while dissolving anodically in neutral and acidic solutions, Journal of the Electrochemical Society,

357-360, 110 (1963)

77.G. A. Marsh, and E. Schaschl, The difference effect and the chunk effect, Journal of The Electrochemical Society, 960-965, 107 (1960)

78.G. G. Perrault, Potentiostatic study of the magnesium electrode in aqueous solution, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 47-58, 27

(1970)

79.G. G. Perrault, The potential-pH diagram of the magnesium-water system, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 107-119, 51 (1974)

80.R. Tunold, H. Holtan, M. B. H. Berge, A. Lasson, and R. Steen-Hansen, The corrosion of magnesium in aqueous solution containing chloride ions, Corrosion Science, 353-365, 17 (1977)

81.J. L. Robinson, and P. F. King, Electrochemical behavior of the magnesium anode, Journal of the electrochemical society, 36-41, 108 (1961)

82.P. F. King, The role of the anion in the anodic dissolution of magnesium, Journal of the Electrochemical Society, 536-539, 113 (1966)

83.S. Bender, J. Goellner, A. Heyn, and S. Schmigalla, A new theory for the negative difference effect in magnesium corrosion, Materials and Corrosion, 707-712, 63 (2012)

84.G. Williams, and H. N. McMurray, Localized corrosion of magnesium in chloride-containing electrolyte studied by a scanning vibrating electrode technique, Journal of the electrochemical Society, C340-C349, 155 (2008)

85.J. Światowska, P. Volovitch, and K. Ogle, The anodic dissolution of Mg in NaCl and Na2SO4 electrolytes by atomic emission spectroelectrochemistry, Corrosion Science, 2372-2378, 52 (2010)

86.N. T. Kirkland, G. Williams, and N. Birbilis, Observations of the galvanostatic

dissolution of pure magnesium, Corrosion Science, 5-9, 65 (2012)

87.G. S. Frankel, A. Samaniego, and N. Birbilis, Evolution of hydrogen at dissolving magnesium surfaces, Corrosion Science, 104-111, 70 (2013)

88.S. Lebouil, A. Duboin, F. Monti, P. Tabeling, P. Volovitch, and K. Ogle, A novel approach to on-line measurement of gas evolution kinetics: Application to the negative difference effect of Mg in chloride solution, Electrochimica Acta, 176-182, 124 (2014)

89.N. Birbilis, A. D. King, S. Thomas, G. S. Frankel, and J. R. Scully, Evidence for enhanced catalytic activity of magnesium arising from anodic dissolution, Electrochimica Acta, 277-283, 132 (2014)

90.M. Taheri, J. R. Kish, N. Birbilis, M. Danaie, E. A. McNally, and J. R. McDermid, Towards a physical description for the origin of enhanced catalytic activity of corroding magnesium surfaces, Electrochimica Acta, 396-403, 116 (2014)

91.T. B. Massalski, J. L. Murray, L.H. Bennett, and H. Baker, Binary alloy phase diagrams, American Society for Metals, Ohio (1986)

92.G. Song, A. Atrens, and M. Dargusch, Influence of microstructure on the corrosion of diecast AZ91D, Corrosion science, 249-273, 41 (1998)

93.Z. Yang, J. P. Li, J. X. Zhang, G. W. Lorimer, and J. Robson, Review on research and development of magnesium alloys, Acta Metallurgica Sinica (English Letters), 313-328, 21 (2008)

94.G. Mima, and Y. Tanaka, The main factors affecting the aging of magnesium-zinc alloys, Transactions of the Japan Institute of Metals, 76-81, 12 (1971)

95.K. Gusieva, C. H. J. Davies, J. R. Scully, and N. Birbilis, Corrosion of magnesium alloys: the role of alloying, International Materials Reviews, 169-194, 60 (2015) 96.S. Tekumalla, S. Seetharaman, A. Almajid, and M. Gupta, Mechanical properties of

magnesium-rare earth alloy systems: A review, Metals, 1-39, 5 (2014)

97.N. Hort, Y. Huang, D. Fechner, M. Störmer, C. Blawert, F. Witte, C. Vogt, H. Drucker, R. Willumeit, K. U. Kainer, and F. Feyerabend, Magnesium alloys as implant materials–principles of property design for Mg–RE alloys, Acta biomaterialia, 1714-1725, 6 (2010)

98.Y. F. Zheng, X. N. Gu, and F. Witte, Biodegradable metals, Materials Science and Engineering: R: Reports, 1-34, 77 (2014)

99.N. Birbilis, M. A. Easton, A. D. Sudholz, S. M. Zhu, and M. A. Gibson, On the corrosion of binary magnesium-rare earth alloys, Corrosion Science, 683-689, 51 (2009)

100.D. S. Gandel, M. A. Easton, M. A. Gibson, and N. Birbilis, Influence of Mn and Zr on the corrosion of Al-Free Mg alloys: Part 2—impact of Mn and Zr on Mg alloy electrochemistry and corrosion, Corrosion, 744-751, 69 (2013)

101.G. Song, Corrosion Prevention of Magnesium Alloys, Woodhead Publishing Limited, UK (2013)

102.A. K. Sharma, M. R. Suresh, H. Bhojraj, H. Narayanamurthy, and R. P. Sahu, Electroless nickel plating on magnesium alloy, Metal Finishing, 10-16, 96 (1998) 103.L. P. Wu, J. J. Zhao, Y. P. Xie, and Z. D. Yang, Progress of electroplating and

electroless plating on magnesium alloy, Transactions of Nonferrous Metals Society of China, s630-s637, 20 (2010)

104.L. Zhao, C. Cui, Q. Wang, and S. Bu, Growth characteristics and corrosion resistance of micro-arc oxidation coating on pure magnesium for biomedical applications, Corrosion Science, 2228-2234, 52 (2010)

105.J. Keir, Experiments and observations on the dissolution of metals in acids, and their precipitations; with an account of a new compound acid menstruum, useful in some

technical operations of parting metals. By James Keir, Esq. F. R. S., Philosophical Transactions of the Royal Society of London, 359-384, 80 (1790)

106.C. F. Schönbein, Ueber das Verhalten des Zinns und des Eisens gegen die Salpetersäure, Annalen der Physik, 390-399, 113 (1836)

107.H. H. Uhlig, Passivity in metals and alloys, Corrosion science, 777-791, 19 (1979) 108.N. Sato, and G. Okamoto, Electrochemical passivation of metals, Electrochemical

Materials Science, 193-245 ,Springer US, New York (1981)

109.Y. R. Chu, Citrate Conversion Coating on AZ31 Magnesium Alloys, Doctoral Dissertation, National Taiwan University, Taipei (2015)

110.L. E. Scriven, Physics and applications of dip coating and spin coating, Material Research Society proceedings, 717, 121 (1988)

111.P. L. Hagans, and C. M. Haas, Chromate Conversion Coatings, ASM Handbook Volume 5: Surface Engineering, ASM International, 405-411, USA (1994)

112.A. E. Hughes, R. J. Taylor, and B. R. W. Hinton, Chromate conversion coatings on 2024 Al alloy, Surface and interface analysis, 223-234, 25 (1997)

113.N. Zaki, Trivalent chrome conversion coating for zinc and zinc alloys, Metal Finishing, 425-435, 105 (2007)

114.X. Zhang, C. Van den Bos, W. G. Sloof, A. Hovestad, H. Terryn, and J. H. W. De Wit, Comparison of the morphology and corrosion performance of Cr (VI)-and Cr (III)-based conversion coatings on zinc, Surface and Coatings Technology, 92-104, 199 (2005)

115.T. S. Narayanan, Surface pretreatment by phosphate conversion coatings—a review, Reviews on Advanced Materials Science, 130-177, 9 (2005)

116.S. M. Hung, Microstructure and Corrosion Resistance of permanganate conversion coating on LZ91 magnesium alloy, Master’s Thesis, National Taiwan University,

Taipei (2016)

117.G. S. Frankel, Magnesium alloys: ready for the road, Nature materials, 1189-1190, 14 (2015)

118.R. Lindström, J. E. Svensson, and L. G. Johansson, The influence of carbon dioxide on the atmospheric corrosion of some magnesium alloys in the presence of NaCl, Journal of the Electrochemical Society, B103-B107, 149 (2002)

119.S. Feliu Jr, A. Samaniego, E. A. Bermudez, A. A. El-Hadad, I. Llorente, and J. C.

Galván, Effect of native oxide film on commercial magnesium alloys substrates and carbonate conversion coating growth and corrosion resistance, Materials, 2534-2560, 7 (2014)

120.Y. Liu, P. Visser, X. Zhou, S. B. Lyon, T. Hashimoto, M. Curioni, … and D. Graham, Protective film formation on AA2024-T3 aluminum alloy by leaching of lithium carbonate from an organic coating, Journal of The Electrochemical Society, C45-C53, 163 (2016)

121.D. Wang, and G. P. Bierwagen, Sol–gel coatings on metals for corrosion protection, Progress in organic coatings, 327-338, 64 (2009)

122.H. A. Clark, Pigment-free coating compositions, Patent No. US3986997 A (1976) 123.G. W. Jernstedt, Corrosion resistant coating for metal surfaces, Patent No. US

2322349 A (1943)

124.Ag. E. Merck, Process for coating titanium dioxide on solid materials, Patent No. US 3553001 A (1971)

125.P. Patnaik, Handbook of Inorganic Chemicals, McGraw-Hill, USA (2003)

126.W. Ha, and Y. J. Kim, Effects of cover gases on melt protection of Mg alloys, Journal of Alloys and Compounds, 208-213, 422 (2006)

127.J. R. Myers, H. B. Bomberger, and F. H. Froes, Corrosion behavior and use of

titanium and its alloys, The Journal of The Minerals, Metals & Materials Society, 50-60, 36 (1984)

128.A. M. Fekry, The influence of chloride and sulphate ions on the corrosion behavior of Ti and Ti-6Al-4V alloy in oxalic acid, Electrochimica Acta, 3480-3489, 54 (2009) 129.U. Diebold, The surface science of titanium dioxide, Surface science reports, 53-229,

48 (2003)

130.J. Pan, C. Leygraf, D. Thierry, and A. M. Ektessabi, Corrosion resistance for biomaterial applications of TiO2 films deposited on titanium and stainless steel by ion-beam-assisted sputtering, Journal of biomedical materials research, 309-318, 35 (1997)

131.Y. Fovet, J. Y. Gal, and F. Toumelin-Chemla, Influence of pH and fluoride concentration on titanium passivating layer: stability of titanium dioxide, Talanta, 1053-1063, 53 (2001)

132.A. Nazeri, P. P. Trzaskoma-Paulette, and D. Bauer, Synthesis and properties of cerium and titanium oxide thin coatings for corrosion protection of 304 stainless steel, Journal of Sol-Gel Science and Technology, 317-331, 10 (1997)

133.Y. Takahashi, and Y. Matsuoka, Dip-coating of TiO2 films using a sol derived from Ti(O-i-Pr)4-diethanolamine-H2O-i-PrOH system, Journal of Materials Science, 2259-2266, 23 (1988)

134.S. Nagarajan, and N. Rajendran, Surface characterisation and electrochemical behaviour of porous titanium dioxide coated 316L stainless steel for orthopaedic

134.S. Nagarajan, and N. Rajendran, Surface characterisation and electrochemical behaviour of porous titanium dioxide coated 316L stainless steel for orthopaedic

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