結論 - 增塑劑與奈米添加劑對聚碳酸酯結晶行為之影響

摻合系統為50/50 有較好之結晶能力，且 Avrami equation 分析獲得參數k，與 Neat PC 比較發現明顯提昇 PC 結晶之能力，其中以 PC/Epoxy 摻合系統為50/50 有最快的結晶速率。

3.> PC/MWCNT 混成材料系統各組成比例於 POM 下觀察發現 MWCNT 之添加成功地誘導 PC 產生結晶，且結晶型態為馬爾它十字結晶與Neat PC 相同，表示 MWCNT 只具有成核劑之作用，對 PC 無

結晶結構變化之影響，且由WAXD 與 DSC 分析發現，添加 MWCNT 含量為 3 wt% 有最佳之誘導效果，而隨溫度降低所需成核劑之含量相對提高，確實提昇PC 之結晶能力。Avrami equation 分析獲得參數 n 與 k，與 Neat PC 比較證明提昇 PC 結晶之能力，且與 Neat PC 具有相同之 n 值，表示 MWCNT 之添加只具有成核之效用，對結晶結構無影響。利用Hoffman–Lauritzen Secondary Nucleation Theory 計算 Kg

值，發現MWCNT 含量為 3 wt% 有最低之活化能。仍比Neat PC 有較好之結晶能力。利用 Hoffman–Lauritzen Secondary Nucleation Theory 計算 Kg值，發現OVMT 含量為 10 wt% 有最低之活化能。

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在文檔中增塑劑與奈米添加劑對聚碳酸酯結晶行為之影響 (頁 181-195)