結論 - 胞外聚合物對生物重金屬溶出程序之影響

1. 理論上硫片添加量越多，污泥酸化速度越快，但添加量高達 4% 時由於硫片過多並且有一定的重量，所以會堵塞住氣流孔動，使的ORP 無法迅速上升，pH 無法快速下降，所以導致重金屬溶出效率沒有預期中來的高。

2. 固體物濃度對重金屬溶出效果有一定的影響力，因為固體物濃度高低就等於有機物含量高低，然而重金屬容易與有機物結合形成錯合物，所以在高固體物濃度時會導致重金屬溶出效果不佳。除了TS=5.0%，S=2.3%

及TS=4.34%，S=1.0%之外，其餘實驗後污泥中重金屬含量皆符合各國標準。

3. 重金屬在不同處理條件下之溶出效率以鋅、錳及鎳較佳，而鉛和鉻的溶出效果不佳，應另尋其他萃取方法，針對鉛和鉻處理。以污泥中重金屬含量較高的銅、鋅和鎳為指標，將固體物濃度控制在 0.5-2.0% 且硫片添加量在 0.5-2.0% 之間時，鎳的溶出率即可達到 95% 以上。

4. 生物溶出程序對於有機物的降解具有一定的作用，SS 去除率約為 30~65%，VSS 去除率約為 15~62%，均較一般活性污泥法來的好。

5. 由 AFM 及 SEM 實驗結果顯示，EPS 具有吸附及酵素的作用，有助於幫助硫氧化菌快速產酸的能力，所以 EPS 在 bioleaching 程序重扮演一重要的角色。

6. 由各重金屬溶出結果可知，在 pH 值快速下降至 2.5 時，可有效始重金屬溶出，而已氣提示反應槽來處理畜牧業污泥，可縮短時間為 14 天左右，及在 14 天後重金屬就可達到高溶出結果。

7. 隨著 pH 值得降低，T. thioparus 所佔的百分比漸漸減少，也證明 bioleaching 前段的酸化作用為此株菌所造成，當 pH 值降到 4 以下 時，T. thioparus 所佔的百分比降至 2% 以下；而 T. Thiooxidans 和 T.

ferrooxidans 所佔的百分比卻漸漸增加，證明 bioleaching 後段酸化作用

為此兩株菌所造成的，並且成為優勢菌種。

8. pH

值的高低對微生物總量有一定的影響力

，pH 值 (＜2.5)越低所能生存的微生物量越少，也越適合硫氧化菌的生存，可有效提高硫氧化菌的數量，但此時產生EPS 量會較少，所以與重金屬溶出效果成反比。

9. 重金屬溶出效率和 EPS 產率為完全相反的趨勢，也就是重金屬溶出效率越佳 EPS 產率反而越低，其原因為：當重金屬溶出效率越佳時，反應溶液中含有大量的重金屬及硫酸根離子，導致濃度環境之突變，微生物會大量分泌胞外聚合物，保持菌體的完整性並且使的微生物可以生長在此環境條件之下。

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附錄一反應槽操作對照表

發生情況解決方法 (處理及應變步驟) 改善後恢復情形

反應槽內氣流曝氣停

止轉動檢查空壓機是否當機攪拌器正常運轉

恆溫水槽停止流動檢查馬達是否孔轉或燒壞 (緊急連

絡維護廠商) 恆溫水槽繼續流動

恆溫水槽水位無法上

升檢查水量是否不足恆溫水槽水位上升

附錄二 EC/ SO₄^2-之相關係數 Code Value

Std Order X1 X2

Sludge conc. (%)

Addition of Sulfur (%)

Correl. Coefficient (%)

4 1 1 4.34 3.5 84.02

6 1.414 0 5 2.3 97.47

9 0 0 2.75 2.3 99.22

11 0 0 2.75 2.3 99.22

1 -1 -1 1.16 1 78.96

8 0 1.414 2.75 4 88.38 5 -1.414 0 0.5 2.3 95.21 7 0 -1.414 2.75 0.5 91.57

3 -1 1 1.16 3.5 90.45

10 0 0 2.75 2.3 99.22

2 1 -1 4.34 1 61.98

附錄三各重金屬之溶出率

Cu solubilization (%)

Time (d)

Cd solubilization (%)

Time (d)

0 5 10 15 20

Cr solubilization (%)

Time (d)

Pb solubilization (%)

Time (d)

0 5 10 15 20

Zn solubilization (%)

Time (d)

Ni solubilization (%)

Time (d)

0 5 10 15 20 0

20 40 60 80 100

Mn solubilization (%)

Time (d)

TS/S: 0.5/2.3 TS/S: 1.16/1.0 TS/S: 2.75/2.3 TS/S: 2.75/0.5 TS/S: 5.0/2.3 TS/S: 1.16/3.5 TS/S: 4.34/1.0 TS/S: 4.34/3.5 TS/S: 2.75/4.0

附錄四各pH 與 EPS 之反應曲面及等高線圖

-2 0 2 4 6 8 10 12 14 16 18 20 22

-2 0 2 4 6 8 10 12 14 16 18 20 22 2

4 6 8

Time (d)

1500 2000 2500 3000 3500 4000 4500 5000 5500 6000

EPS (mg/L)

TS/S: 2.75/4.0

附錄五原始數據

1 TS/S: 0.5/2.3 7 TS/S: 4.34/1.0

2 TS/S: 1.16/1.0 8 TS/S: 4.34/3.5

3 TS/S: 2.75/2.3 9 TS/S: 2.75/4.0

4 TS/S: 2.75/0.5 10 TS/S: 2.75/2.3

5 TS/S: 5.0/2.3 11 TS/S: 2.75/2.3

6 TS/S: 1.16/3.5

1. pH 之原始數據:

1 2 3 4 5 6 7 8 9 10 11

0 7.17 8.31 8.56 8.54 8.89 8.34 7.58 7.67 7.91 8.34 8.66 2 2.72 7.64 8.19 8.17 8.97 8.41 8.77 8.06 5.89 8.21 8.17 4 2.65 3.56 4.56 4.88 8.56 3.63 8.2 6.77 4.94 4.54 4.58 6 2.34 2.83 4.46 4.76 8.45 3 7.62 5.07 4.77 4.44 4.48 8 1.85 2.36 3.47 4.59 7.77 2.96 6.49 4.45 4.17 3.46 3.48 10 1.49 1.52 2.56 4.33 7.61 2.48 6.28 3.96 3.63 2.56 2.57 12 1.27 1.33 2.45 3.56 7.23 1.65 6.15 2.4 3.55 2.39 2.51 14 1.33 1.14 1.96 2.89 6.35 1.4 6.18 2.01 2.96 2.01 1.91 16 1.25 1.18 1.89 1.32 5.38 1.28 5.78 1.81 2.89 1.88 1.91 18 1.22 1.2 1.62 1.48 4.03 1.27 5.75 1.63 2.62 1.62 1.62 20 1.15 1.25 1.59 1.42 3.21 1.27 5.82 1.57 2.59 1.58 1.6

2.ORP 之原始數據 (mv):

1 2 3 4 5 6 7 8 9 10 11

0 -0.55 -82 -184 -162 -254 -84 -210 -199 -184 -181 -185 2 246 237 -95 -77 -166 166 12 -45 -95 -99 -91

4 368 339 15 18 37 242 51 -13 99 16 15

6 468 436 128 79 126 308 194 72 198 128 129 8 489 455 296 249 154 329 241 155 267 297 295 10 493 467 313 320 197 356 374 319 289 313 312 12 502 471 384 351 278 451 392 439 331 383 384 14 511 488 478 427 295 480 391 499 385 478 478 16 513 483 468 457 349 513 388 509 395 474 473 18 522 485 471 474 379 533 381 495 450 471 469 20 526 491 473 469 407 548 401 523 455 472 473

3. EC 之原始數據 (ms/cm):

1 2 3 4 5 6 7 8 9 10 11

0 2.23 3.17 4.45 4.23 4.03 2.16 4.74 6.93 3.83 4.44 4.45 2 5.72 7.82 4.71 5.19 3.46 2.54 5.85 7.21 8.42 4.69 4.73 4 10.07 10.87 5.67 5.34 3.75 4.46 6.26 8.82 10.18 5.63 5.69 6 18.42 12.86 6.84 5.74 4.4 9.45 6.4 10.82 10.36 6.81 6.87 8 23.8 15.72 5.28 6.76 4.03 14.78 7.69 12.12 10.58 5.27 5.28 10 40.6 18.68 10.54 8.19 4.66 19.44 8.01 14.82 12.78 10.53 10.54 12 42.5 42.8 16.54 11.29 6.04 67.5 8.14 25.5 15.54 16.55 16.54 14 47.4 57.4 22.5 14.51 6.24 95 7.98 47.9 16.99 22.25 23.5 16 50.3 68.8 34.5 23.5 8.72 105 7.9 58.1 18.32 34.5 35.5 18 56.8 61.3 39.5 32.8 8.87 117.5 7.13 77.8 25.78 38.5 39.5 20 57.1 74.2 41.5 35.5 9.59 118 6.79 91 30.55 41.2 41.5

4. SO₄^2-之原始數據 (mg/L)

1 2 3 4 5 6 7 8 9 10 11

0 36.29 193.67 2202 2916 899.3 212.275 55.29 975.85 2198 2192 2213 2 3179 4592.65 3132.75 3388.5 1305 740.25 1688 2800 2432.75 3150 3100 4 5180 4383.67 4247 3659.25 1465.25 3284.5 2634.5 3990.25 3247 4100 4300 6 7641 6825.51 4317.5 3932 1728 3384.5 3056.5 14235 3717.5 4350 4295 8 10670 6626.53 4501 4135.5 2088.5 4611 2650.5 17476.5 4015 4490 4560 10 10430 5783.67 5820 4641.5 2143 6369.25 2897.5 17713.5 4820 5850 5795 12 11950 6100 8195 5172 2424.75 7452.5 3382.75 18289.5 5795 8215 8175 14 14198 7234.67 9379.5 5975 2709 9707.5 3481 24430 6237 9400 9365 16 14112 7991.83 17490 6378 5455 12065 5418 27737.5 6549 17500 17480 18 14134 8522.44 18460 6659 5760 17943 4677.5 27995 6646 18500 18430 20 14256 9812.24 20265 6845 6071 23980 5542.5 28355 6678 20255 20278

5. SS 去除率之原始數據 (*1000 mg/L):

1 2 3 4 5 6 7 8 9 10 11

0 2.981 9.349 24.965 25.783 41.362 11.576 37.337 43.917 28.03 24.995 24.955 2 2.697 8.893 24.514 22.655 40.199 10.012 37.019 42.278 27.432 24.641 24.641 4 2.102 8.499 22.883 24.33 40.194 9.617 36.991 41.767 23.748 23.158 23.668 6 1.859 7.848 22.425 22.411 39.68 9.118 33.189 37.231 23.19 22.554 22.341 8 1.777 6.531 21.477 22.225 39.11 8.522 32.47 33.952 22.904 21.547 21.378 10 1.541 6.375 20.319 20.202 38.955 7.862 31.776 29.046 22.714 20.413 20.013 12 1.357 5.773 18.099 18.976 36.01 6.708 28.53 25.228 19.564 19.883 19.001 14 1.299 5.528 17.007 18.032 34.378 6.566 28.118 18.104 18.91 17.175 17.023 16 1.108 5.207 16.034 17.768 31.194 6.346 27.509 17.336 17.31 16.013 16.012 18 1.06 4.818 15.872 16.635 29.034 5.855 26.123 15.859 17.21 15.567 15.325 20 1.081 4.544 13.838 16.508 28.829 5.435 25.817 15.287 16.01 13.983 13.786

6. VSS 去除率之原始數據 (*1000 mg/L):

1 2 3 4 5 6 7 8 9 10 11

0 3.60 8.12 18.74 18.64 27.72 8.42 25.96 29.42 18.19 18.69 18.77 2 3.14 7.89 17.32 18.00 27.68 8.03 25.57 28.16 17.29 17.46 17.99 4 2.83 7.59 16.39 16.94 26.91 8.31 24.73 26.24 17.08 16.55 16.59 6 2.64 6.96 15.80 16.54 26.61 7.31 22.65 25.75 16.91 15.03 15.78 8 2.32 6.36 15.66 15.14 25.98 6.23 21.92 21.19 16.11 14.78 15.00 10 1.98 5.96 14.21 14.43 25.35 6.06 21.07 19.69 15.96 14.02 14.53 12 1.96 5.53 13.39 14.53 25.26 5.75 20.75 17.57 15.94 13.55 13.70 14 1.91 5.24 12.21 13.78 24.23 5.52 20.30 15.65 15.86 12.02 12.34 16 1.88 5.17 12.13 13.29 24.42 5.33 19.81 13.74 15.32 11.08 11.93 18 1.85 4.93 11.12 12.64 24.03 4.74 19.79 12.05 14.88 10.60 11.54 20 1.81 4.57 10.77 12.20 23.30 4.53 19.66 10.96 12.21 10.53 10.89

7. 銅溶出率之原始數據 (mg/L):

1 2 3 4 5 6 7 8 9 10 11

0 8 14 0 20 16 11 1.74 1.37 0.25 0.01 0

2 1380 1002 5 0 10 120 41 4.2 25.32 4.5 3.5

4 1860 2194 12 675 6 960 146 21 255.5 10 13.5 6 2280 2146 1325 1375 12 1380 157 357 673 1300 1280 8 3300 2620 2550 835 18 1500 393 1407 721 2560 2400 10 3360 2780 2950 1670 104 1560 887.5 1190 1430 2750 2850 12 3340 3080 2750 1750 10 2010 912.5 1722 1210 2000 2750 14 3320 3380 3050 1925 550 2250 1075 1862 1850 3100 3150 16 3380 3300 3150 2175 890 2670 912.5 1757 2150 3050 3250 18 3450 3340 2950 2750 1100 3090 1050 2079 2550 3050 3100 20 3460 3350 3320 2825 1218 3390 1025 2660 2670 3250 3300

8. 鎘溶出率之原始數據 (mg/L):

1 2 3 4 5 6 7 8 9 10 11

0 0 0 0 0 0 0 0 0.03 0 0 0

2 7 1 0 0 0 12 0.73 3 0 0.02 0

4 60 5 1 2 1 21.5 0.74 12 5 0.95 1.02

6 26 25.5 2 0 0.5 41.5 0.73 5 1.25 2.5 1.99

8 48 49.5 6.5 1 2.5 38.5 3.65 10.5 6.25 7.5 7.7 10 66.5 63.5 36.5 9.5 2 65.5 12.5 14 12.25 38.5 35.5 12 60.5 50.5 46 20.5 4.5 62 7.5 24.5 25.5 44.5 44.8 14 77.5 56 45.5 37.5 7.5 68 16.25 37 40.5 42.5 45.5 16 75.5 71 40.5 35.5 13 72.5 18.25 45.9 38.5 51.5 52.5 18 78.5 81 65.5 59.8 19.5 78.5 19.5 38.5 44.8 58.5 61.5 20 83.5 81 72.5 67.9 21 80.1 20 60.7 52.5 69.5 70.5

9. 鉻溶出率之原始數據 (mg/L):

1 2 3 4 5 6 7 8 9 10 11

0 0 0 9.5 0 0 0.02 0 0 0 0 1.1

2 2 2 10 4 0 0 0 0.04 0.04 0.05 0

4 50 4.5 13 25 0 0.05 0.08 0.74 0.5 0.95 8.5

6 52.5 20.5 17.5 1 0 8 0.12 0.78 1.25 18.5 15.5 8 16 42.5 19 27.5 0.5 6 4.8 5.04 11.55 5.8 25.5 10 15 13.5 39.5 31.5 3 18 8.8 0 5.25 26.5 27.5 12 49 45.2 21 51 4.5 13 6 10.36 15.25 29.5 22.5 14 51 27.5 23 65.5 2.5 38 10 10.64 23.45 35.5 18.5 16 78.8 75.2 48.5 34.5 11 33.5 11 18.48 21.25 36.5 33.5 18 90.5 89.6 35.5 27.5 13 55.2 8 27.05 24.55 35.5 34.5 20 95.5 94.2 37 32.5 14 72.5 12 35.09 25 36.5 35.5

10. 鉛溶出率之原始數據 (mg/L):

1 2 3 4 5 6 7 8 9 10 11

0 0 0 2.5 2.5 4 0 0 0.12 0 0 1.1

2 0.5 0 4 2.5 3 0.02 0 0 0.25 0.85 2.3

4 10 0 2.5 7 5.5 0.01 0.65 0.56 0 5.5 0.95

6 10 0 4 0 5 0.03 0 1.63 0.17 1.5 5.5

8 2.5 77.5 1 3 22.5 15 6.35 4.95 0.12 0.5 12.5

10 10 0 50 3 5 25 15.75 23.66 5.25 23.5 28.5

12 32.5 75.5 2.5 51 36 35 31 24.22 25.55 2.5 33.5 14 87.5 10 25 4.5 41 62.5 36 24.08 32.5 44.5 45.5 16 91.5 79.5 60 59 40 77.5 31.5 5.19 19.25 58.5 52.5 18 92.5 80.5 65.5 65.8 41 80 31 48.44 55.55 61.5 61.5 20 92.5 81.2 69.1 67.5 42 82.5 31.5 49.84 59 66.5 67.5

11. 鋅溶出率之原始數據 (mg/L):

1 2 3 4 5 6 7 8 9 10 11

0 17 18.5 0 28 2 11 0.82 1.73 0.25 1.1 0

2 1755 1325 285 265 67 440 18 26.74 65 265 128 4 4375 2750 347 191 66 1520 21.6 102 125 335 285 6 3075 2780 38 998 59 2000 3.6 1484 550 538 458 8 3375 2900 1052 2655 145 2650 540 1764 2160 998 935 10 4245 3350 2159 3058 512 2160 1175 2002 2570 2012 1980 12 4375 3850 3670 4155 882 3280 1440 2268 3550 3458 3150 14 4450 4120 4155 3955 1705 4150 1640 3339 3880 4050 3990 16 4550 3950 4245 4250 2152 3880 2000 2779 3950 4150 4180 18 4410 4320 4195 4055 1735 4340 1800 3325 3955 4250 4200 20 4430 4350 4340 4200 2450 4440 1880 4053 4000 4300 4280

12. 鎳溶出率之原始數據 (mg/L):

1 2 3 4 5 6 7 8 9 10 11

0 36 39 12 21 12 15 0.39 2.24 1.25 9.5 10.5

2 258 213 243 159 84 45 0.46 79.8 32 198 223 4 705 294 360 471 75 -0.01 21.5 93.1 112 289 355 6 795 393 588 564 96 585 105 264.6 278 532 575 8 885 543 768 837 87 645 230 338.1 425 670 665 10 903 459 726 792 72 585 442.5 592.9 575 725 750 12 895 795 840 759 165 675 510 681.1 655 835 820 14 905 861 858 867 171 705 495 602.7 690 840 845 16 900 885 831 849 372 735 495 744.8 775 812 825 18 897 894 870 843 621 870 472.5 798.7 795 865 855 20 900 895 876 855 630 900 494 788.9 800 870 868

13. 錳溶出率之原始數據 (mg/L):

1 2 3 4 5 6 7 8 9 10 11

0 15 79 90 35.3 9.5 45 0.73 0.82 23.5 55 85

2 955 875 582 826 41 836 5.1 15.68 125 545 553 4 1178 1350 1376 1065 57 1188 35 46.34 565 1250 1125 6 1200 1925 2109 1134 74 1276 65 448 345 1400 1780 8 1983 1735 1855 1784 99.5 1924 150 1316 955 1855 1950 10 1575 2155 2014 1555 215.5 1188 350 1379 1245 1995 2010 12 2121 2355 2385 1898 178.5 1836 240 1246 1785 2015 2350 14 2256 2255 1845 2095 272.5 1985 360 1467 2045 1785 1985 16 2415 2315 2285 2115 470 2242 480 1674 2155 2150 2250 18 2430 2440 2345 1958 757.5 2046 480 1914 1890 2250 2350 20 2445 2440 2380 2240 839.5 2266 600 2042 2155 2350 2350

14. EPS 產率之原始數據 (mg/L):

1 2 3 4 5 6 7 8 9 10 11

0 220 420 4100 3990 4550 280 3280 2170 4050 4050 4150 2 110 220 4520 2520 1480 60 540 1500 2750 4450 4750 4 60 170 3760 1980 1220 630 1300 4580 1880 3650 3670 6 70 20 4200 2320 1190 430 540 4810 1980 3150 4150 8 210 330 2260 2790 4410 480 2150 7910 2250 2570 2250 10 100 320 9200 3070 3470 520 2240 6030 3780 9150 9250 12 230 330 8880 5940 3810 600 2060 4580 4850 8950 8750 14 220 310 6210 3420 4690 480 3140 3770 5500 6570 6450 16 230 300 6070 5440 4450 450 5420 4360 4210 6150 5950 18 240 250 5380 5570 8990 660 1220 4380 3990 5250 5540 20 210 180 4210 4600 4690 770 1940 3880 4300 4320 4250

14. 蛋白質產率之原始數據 (µg/mL):

1 2 3 4 5 6 7 8 9 10 11

0 0.32 3.51 11.94 12.39 12.04 13.18 86.85 29.14 12.24 12.00 11.89 2 0.32 0.21 23.10 24.72 26.11 6.49 36.39 12.43 20.78 23.13 23.10 4 0.32 5.19 39.89 43.27 47.28 6.67 72.40 35.34 39.27 38.05 39.87 6 0.32 3.20 75.53 82.65 92.23 11.03 33.79 23.03 78.55 75.00 75.36 8 0.32 3.08 77.35 82.89 89.65 10.34 127.43 5.99 80.88 77.55 77.55 10 0.32 1.35 73.49 80.39 106.47 7.21 85.80 4.73 83.38 73.98 73.89 12 0.32 3.69 86.83 85.99 48.07 13.52 47.89 10.11 83.99 89.00 88.98 14 0.32 10.32 18.12 93.34 23.48 25.25 84.51 19.50 69.45 18.13 20.90 16 0.32 9.65 18.51 95.12 19.84 14.47 76.82 28.49 59.12 18.00 18.99 18 0.31 3.58 16.98 19.22 20.33 59.89 52.73 28.83 21.22 17.00 17.87 20 0.32 9.87 14.82 19.65 15.68 25.25 58.48 15.35 15.56 14.90 15.01

附錄六 FISH 原始數據

TS/S: 0.5/2.3 (L/S)

Time (d) DAPI (L) Thio820 (L) Thiopa 0511 (L) DAPI (S) Thio820 (S) Thiopa 0511 (S)

0 100% 3.6% 3.9% 100% 1.8% 3.2%

2 100% 2.8% 2.3% 100% 3.3% 1.7%

4 100% 12.9% 1.6% 100% 5.9% 1.3%

6 100% 30.0% 1.6% 100% 7.7% 1.2%

8 100% 33.5% 1.7% 100% 9.3% 0.9%

10 100% 29.4% 1.0% 100% 13.5% 0.7%

12 100% 38.6% 1.1% 100% 15.8% 0.5%

14 100% 39.1% 0.9% 100% 17.9% 0.5%

16 100% 40.1% 0.5% 100% 20.5% 0.4%

18 100% 40.5% 0.4% 100% 18.8% 0.6%

20 100% 40.4% 0.2% 100% 21.5% 0.2%

TS/S: 1.16/1.0 (L/S)

Time (d) DAPI (L) Thio820 (L) Thiopa 0511 (L) DAPI (S) Thio820 (S) Thiopa 0511 (S)

0 100% 1.5% 4.1% 100% 1.5% 4.5%

2 100% 1.6% 5.7% 100% 1.6% 2.3%

4 100% 2.0% 3.7% 100% 4.6% 2.6%

6 100% 3.2% 2.2% 100% 7.8% 2.2%

8 100% 10.6% 1.8% 100% 14.9% 1.8%

10 100% 23.9% 1.3% 100% 9.3% 1.2%

12 100% 24.6% 2.1% 100% 15.2% 1.5%

14 100% 25.1% 2.6% 100% 16.3% 1.1%

16 100% 29.1% 1.3% 100% 13.2% 1.3%

18 100% 30.3% 1.5% 100% 20.8% 0.5%

20 100% 31.7% 1.1% 100% 18.3% 0.5%

TS/S: 2.75/2.3 (L/S)

Time (d) DAPI (L) Thio820 (L) Thiopa 0511 (L) DAPI (S) Thio820 (S) Thiopa 0511 (S)

0 100% 1.3% 7.1% 100% 3.1% 8.0%

2 100% 3.7% 6.3% 100% 3.7% 6.2%

4 100% 4.8% 4.9% 100% 4.8% 6.2%

6 100% 7.9% 4.1% 100% 7.9% 4.5%

8 100% 4.9% 3.6% 100% 4.9% 9.8%

10 100% 10.3% 1.3% 100% 10.3% 8.5%

12 100% 14.9% 2.1% 100% 4.9% 5.9%

14 100% 8.5% 2.6% 100% 8.5% 4.1%

16 100% 17.1% 1.7% 100% 13.1% 4.5%

18 100% 21.7% 1.5% 100% 13.7% 2.3%

20 100% 23.5% 1.3% 100% 13.5% 2.6%

TS/S: 2.75/0.5 (L/S)

Time (d) DAPI (L) Thio820 (L) Thiopa 0511 (L) DAPI (S) Thio820 (S) Thiopa 0511 (S)

0 100% 2.8% 12.6% 100% 1.6% 8.1%

2 100% 2.9% 11.4% 100% 2.5% 6.7%

4 100% 4.2% 9.9% 100% 2.7% 7.7%

6 100% 5.9% 4.2% 100% 3.8% 7.6%

8 100% 7.9% 9.8% 100% 4.9% 7.4%

10 100% 12.1% 7.9% 100% 5.3% 8.8%

12 100% 15.9% 8.8% 100% 8.2% 5.9%

14 100% 17.6% 7.9% 100% 9.5% 4.1%

16 100% 21.5% 4.4% 100% 11.5% 3.3%

18 100% 20.9% 6.5% 100% 10.1% 3.1%

20 100% 21.9% 6.3% 100% 10.5% 3.7%

TS/S: 5.0/2.3 (L/S)

Time (d) DAPI (L) Thio820 (L) Thiopa 0511 (L) DAPI (S) Thio820 (S) Thiopa 0511 (S)

0 100% 1.1% 12.5% 100% 1.2% 8.9%

2 100% 2.1% 11.8% 100% 1.8% 8.8%

4 100% 2.3% 9.3% 100% 3.2% 7.4%

6 100% 5.3% 7.8% 100% 2.7% 7.7%

8 100% 4.9% 9.2% 100% 4.9% 6.1%

10 100% 6.1% 8.6% 100% 5.2% 6.8%

12 100% 6.9% 7.4% 100% 4.9% 5.2%

14 100% 7.6% 7.7% 100% 5.8% 4.9%

16 100% 10.5% 7.9% 100% 6.3% 4.5%

18 100% 9.9% 7.5% 100% 6.7% 4.4%

20 100% 10.1% 7.7% 100% 6.5% 4.3%

TS/S: 1.16/3.5 (L/S)

Time (d) DAPI (L) Thio820 (L) Thiopa 0511 (L) DAPI (S) Thio820 (S) Thiopa 0511 (S)

0 100% 3.2% 5.9% 100% 3.6% 3.4%

2 100% 5.6% 6.3% 100% 2.8% 6.3%

4 100% 6.9% 3.9% 100% 5.6% 3.9%

6 100% 7.7% 4.5% 100% 10.4% 2.3%

8 100% 19.4% 2.3% 100% 9.9% 1.6%

10 100% 23.9% 2.6% 100% 14.3% 1.2%

12 100% 29.2% 1.2% 100% 17.5% 0.8%

14 100% 26.3% 1.3% 100% 18.8% 0.4%

16 100% 31.2% 1.0% 100% 20.1% 0.2%

18 100% 30.8% 0.8% 100% 20.5% 0.5%

20 100% 33.8% 0.6% 100% 20.4% 0.2%

TS/S: 4.34/1.0 (L/S)

Time (d) DAPI (L) Thio820 (L) Thiopa 0511 (L) DAPI (S) Thio820 (S) Thiopa 0511 (S)

0 100% 1.2% 8.0% 100% 1.5% 10.3%

2 100% 1.9% 6.2% 100% 2.2% 9.2%

4 100% 2.3% 6.2% 100% 3.2% 7.3%

6 100% 4.3% 4.5% 100% 4.8% 6.9%

8 100% 5.9% 9.8% 100% 3.9% 4.1%

10 100% 6.5% 8.5% 100% 5.5% 5.9%

12 100% 6.1% 7.4% 100% 4.3% 4.8%

14 100% 7.6% 4.1% 100% 5.2% 4.2%

16 100% 7.5% 7.9% 100% 5.8% 3.8%

18 100% 7.9% 7.5% 100% 6.7% 5.2%

20 100% 8.8% 7.7% 100% 5.8% 5.5%

TS/S: 4.34/3.5 (L/S)

Time (d) DAPI (L) Thio820 (L) Thiopa 0511 (L) DAPI (S) Thio820 (S) Thiopa 0511 (S)

0 100% 1.8% 12.1% 100% 1.3% 7.8%

2 100% 2.7% 11.2% 100% 3.3% 5.9%

4 100% 3.2% 10.4% 100% 3.5% 6.3%

6 100% 9.9% 9.1% 100% 7.7% 5.4%

8 100% 6.9% 8.2% 100% 7.9% 8.8%

10 100% 10.3% 9.9% 100% 10.2% 7.3%

12 100% 11.9% 7.4% 100% 5.9% 6.1%

14 100% 18.5% 4.1% 100% 8.5% 4.5%

16 100% 21.1% 3.3% 100% 11.8% 2.8%

18 100% 21.3% 5.8% 100% 13.1% 3.3%

20 100% 22.5% 4.9% 100% 12.3% 3.2%

TS/S: 2.75/4.0 (L/S)

Time (d) DAPI (L) Thio820 (L) Thiopa 0511 (L) DAPI (S) Thio820 (S) Thiopa 0511 (S)

0 100% 1.2% 13.8% 100% 2.3% 9.2%

2 100% 2.1% 12.1% 100% 2.7% 8.9%

4 100% 3.2% 9.7% 100% 3.8% 8.1%

6 100% 5.9% 3.9% 100% 6.8% 8.2%

8 100% 4.9% 7.2% 100% 4.9% 7.9%

10 100% 10.1% 8.5% 100% 6.7% 7.1%

12 100% 13.9% 7.4% 100% 7.1% 6.3%

14 100% 13.6% 4.1% 100% 8.5% 5.2%

16 100% 14.5% 7.9% 100% 9.2% 4.5%

18 100% 19.9% 6.6% 100% 8.8% 3.3%

20 100% 15.9% 7.2% 100% 9.7% 4.1%

在文檔中胞外聚合物對生物重金屬溶出程序之影響 (頁 97-131)

結論

值的高低對微生物總量有一定的影響力

第六章 參考文獻

第六章參考文獻