• 沒有找到結果。

由於熱電裝置需要低導熱性的半導體結構,但目前廣泛研究的超 晶格結構製程複雜,導致價格過高,使得熱電裝置推廣受限。而多孔 性奈米線能有效增加聲子阻抗、降低熱傳導係數,且製程較簡單、成 本低,希望能應用在熱電裝置上,提高其應用價值。

本文討論孔隙大小、散射面積及孔隙間距對多孔隙奈米線的熱傳 導係數影響,得到以下結論:

1. 尺寸效應使得孔隙邊界上存在能量密度較高的區域,降低熱傳導 係數。

2. 材料中增加絕熱孔隙使聲子碰撞邊界後發生散射,攔阻聲子運 動,使熱傳能力降低,孔隙尺寸越大,熱傳導係數越低。

3. 在同樣孔隙率的情況下,孔隙數越多,散射面積就越大,熱傳導 係數就越低。

4. 當尺寸效應發生時,產生局部高(低)溫區域會影響孔隙散射面積,

因此孔隙間距會對熱傳導係數產生影響。

對於未來研究方向有以下幾點建議:

1. 建立三維的物理模型,使模擬更接近真實的奈米結構。

2. 當尺寸小於 10nm 時,量子效應就會更明顯,因此希望能建立波 的模型,來描述更小尺寸的奈米結構。

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