1. Zwinkels, M. F. M., Eloise Heginuz, G. M., Gregertsen, B. H., Sjöström, K., and Järås, S. G., 1997, “Catalytic Combustion of Gasified Biomass over Pt/Al2O3,”
Applied Catalysis A: General, Vol. 148 pp. 325-341.
2. Schlegel, A., Benz, P., Griffin, T., Weisenstein W., and Bockhorn, H., 1996,
“Catalytic Stabilization of Lean Premixed Combustion: Method for Improving NOx Emissions,” Combustion and Flame, Vol. 105 pp. 332-340.
3. Maxwell, I. E., Naber, J. E., de Jong, K. P., 1994, “The pivotal role of catalysis in energy related environmental technology,” Applied Catalysis A: General, Vol. 113 pp. 153-173.
4. Pfefferle, W. C., and Pfefferle, L. D., 1986, “Catalytically Stabilized Combustion,”
Prog. Energy Combust. Sci., Vol. 12 pp. 25-41.
5. Eguchi, K. and Arai, H., 1996, “Recent advances in high temperature catalytic combustion,” Catalysis Today Vol. 29 pp. 379-386.
6. Carroni, R., Griffin, T., Mantzaras, J., and Reinke, M., 2003, “High-pressure experiments and modeling of methane/air catalytic combustion for power-generation applications,” Catalysis Today, Vol. 83 pp.157–170.
7. 謝維昇 2003 “觸媒氣渦輪引擎原型之發展, Development of a proto-type catalytic gas turbine engine” 國立成功大學航空太空工程學系碩士班論文. 8. 張仲翔, 陳志鵬, 趙怡欽、陳冠邦，2005，"高壓觸媒燃燒之研究"，中華民國
航空太空學會學刊 (submitted)
9. 趙怡欽、謝維昇、張仲翔，2003，” 觸媒氣渦輪引擎於分散式發電系統之應 用”，中華民國
2003
航太/
民航學會學術聯合會議，12 月 19 日，台南市台灣 10. 陳冠良 2004 “重質油氣化合成氣觸媒氣渦輪引擎之研發, Development of aGasified Heavy-oil Syn-gas Catalytic Gas Turbine” 國立成功大學航空太空工程 學系碩士班論文
.
11. Hessley, R.K., Reasoner, J.W. and Riley, J.T., 1986, Coal Science, John Wiley &
Sons, New York.
12. Raje, Ajoy; Inga, Juan R.; Davis, Burtron H., 1997, “Fischer-Tropsch synthesis:
Process Considerations Based on Performance of Iron-Based Catalysts,” Fuel, Vol.
76 pp. 273-280.
13. Armor, J., 1999, “The Multiple Roles for Catalysis in the Production of H2,”
Applied Catalysis A, Vol. 176 pp.159-176.
14. Collot, A.G., “Prospects for Hydrogen from Coal,” The Clean Coal Centre, IEA Coal Research, March 2004.
15. Tonkovich, A.Y., Zilka, J.L., LaMont, M.J., Wang, Y. and Wegeng, R.S.,
“Microchannel Reactors for Fuel Processing Applications. I. Water Gas Shift Reactor,” Chemical Engineering Science, Vol. 54 pp.2947-2951, 1999.
16. Sattereld, C.N., Heterogeneous Catalysis in Industrial Practice. New York, McGraw-Hill Inc., 1991.
17. Souza, J.M.T. and Rangel, M.C., “Catalytic Activity of Aluminium-Rich Hematite in the Water Gas Shift Reaction,” Reaction Kinetics and Catalysis Letters, Vol. 83, pp.93-98, 2004.
18. Basinska, A., Klimkiewicz, R. and Telerycz, H., “Catalysts of Alcohol Condensation Tested in Water-Gas in Water Gas Shift Reaction,” Reaction
Kinetics and Catalysis Letters, Vol. 82, pp.271-277, 2004.
19. Saito, M. and Murata, K., “Development of High Performance Cu/ZnO Catalysts for Methanol Synthesis and the Water-Gas in Water Gas Shift Reaction,” Catalysis
Surveys from Asia, Vol. 8, pp.285-294, 2004.
20. Panagiotopoulou P. and Kondarides D. I.; Journal of Catalysis 225(2004), 327-336.
21. Goerke O., Pfeifer P. and Schubert K.; Applied catalysis A, 263(2004), 11-18.
22. Lee J. K., Ko J. B. and Kim D. H.; Applied catalysis A, 278(2004), 25-35.
23. Kamarudin S. K. et., 2004, Chemical Engineering Journal, Vol. 104 pp. 7-17.
24. Czuppon, T.A., Knez, S.A. and Newsome, 1995, “Hydrogen.” In Encyclopedia of
Chemical Technology, Kirk, R.E., and D.F. Othmer (eds), 4
th edition, Vol. 13 pp.838-894.
25. Felipe, B.L., 2004, “The high-temperature, high-pressure homogeneous water-gas shift reaction in a membrane reactor,” Ph.D. Thesis, University of Pittsburgh.
26. Atwood J. A., Barbour J.L., and Jerga A.; 2004, Angew. Chem. Int. Ed. Vol. 43 pp.
2948-2950.
27. Ackley M.W., Rege S.U. and Saxena H., 2003, Micriporous and mesoporous
materials Vol. 61 pp. 25-42.
28. Zhang D., Kodama A., Goto M. and Hirose T., 2004, Separation and purification
technology Vol. 35 pp. 105-112.
29. Sheth, A., Yeboah, Y.D., Godavarty A., Xu, Y. and Agrawal, P.K., 2003, “Catalytic Gasification of Coal Using Eutectic Salts: Reaction Kinetics with Binary and Ternary Eutectic Catalysts,” Fuel, Vol. 82 pp. 305-317,.
30. Ruixing L., Yukishige Y., Shu Y., Qing T. and Tsugio S., 2004, Solid State Ionics Vol. 172 pp. 235-238.
Journal of Catalysis Vol. 180 pp. 225-233.
32. Li, M. W., Xu, G. H., Tian, Y. L., Chen, L. and Fu, H. F.; 2004, J. Phys. Chem. A Vol. 108 pp. 1687-1693.
33. Paglieri, S.N. and Way, J.D., 2002, “Innovation in Palladium Membrane Research,” Separation and Purification Methods, Vol. 31 pp. 1-170.
34. Knapton, A.G., 1977, “Palladium Alloys for Hydrogen Diffusion Membranes － A Review of High Permeability Materials,” Platinum Metals Review, Vol.21 pp.
44-55.
35. Grashoff, G.L., Pilkington, C.E., and Corti, C.W., 1983, “The Purification of Hydrogen － A Review of the Technology Emphasizing the Current Status of Palladium Membrane Diffusion,” Platinum Metals Review, Vol.27 pp.157-165.
36. Kikuchi, E., Uemiya, S., Sato, N., Inoue, H. Ando, H. and Matsuda, T.,
“Membrane Reactor Using Microporous Glass-Supported Thin Film of Palladium.
1) Application to the Water-Gas Shift reaction,” Chemistry Letters, p.489, 1989.
37. Uemiya, S., Sato, N., Ando, H. and Kikuchi, E., “The Water-Gas Shift Reaction Assisted by a Palladium Membrane Reactor,” Industrial and Engineering
Chemistry Research, Vol. 30, pp.585-589, 1991.
38. Basile, A., Chiappetta, G., Tosti, S. and Violante, V., “Experimental and Simulation of Both Pd and Pd/Ag for a Water-Gas Shift Membrane Reactor,”
Separation and Purification Technology, Vol. 25, pp. 549-571, 2001.
39. Damle, A., Ganwal S. and Venkataram, V., 1994, “A Simple Model for a Water-Gas Shift Membrane Reactor,” Gas Separation and Purification, Vol. 8 pp.
101-106.
40. McBridge, R.B. and Mckinley, D.L., 1965, “A New Hydrogen Recovery Route,”
Chemical Engineering Progress, Vol. 61 pp.81-86.
41. Antonizaai, A.B., Haasz, A.A., and Strangeby, P.C., 1989, “The Effect of Adsorbed Carbon and Sulphur on Hydrogen Permeation through Palladium,”
Journal of Nuclear Materials, Vol. 162 pp.1065-1070.
42. Li, A., Liang, W., and Hughes, R., 2000, “The Effect of Carbon Monoxide and Stream on the Hydrogen Permeability of a Pd/Stainless Steel Membrane,” Journal
of Membrane Science, Vol. 165 pp.135-141.
43. Amano, M., Nishimura, C., and Komaki, M., 1990, “Effect of High Concentration of CO and CO2 on Hydrogen Permeation through the Palladium Membrane,”
Materials Transactions JIM, Vol.31 p.404.
44. 張蕙芳， “二十一世紀的發電技術-燃料電池,”能源季刊，第二十三卷 第四 期，pp. 64~78，民國 82 年。
45. S. E. Veyo, L. A. Shockling, J. T. Dederer, J. E. Gillett and W. L. Lundberg,
“Tubular Solid Oxide Fuel Cell/Gas Turbine Hybrid Cycle Power Systems:
Status” Journal of Engineering for Gas Turbine Power, Vol. 124, October 2002.
46. N. Minh, “SECA Solid Oxide Fuel Cell Program,” presented at Solid State Energy Conversion Alliance 3rd Annual Work Shop Proceedings, March 2001.
47. P. Costamanga, L. Magistri and A. F. Massardo, “Design and Part-load performance of a hybrid system based on a solid oxide fuel cell reactor and a micro gas turbine,” Journal of Power Sources, November 2000.
48. 黃玉枝、陳君豪、洪振益，“外部重整固態氧化物燃料電池/小型氣渦輪機複 合系統之熱力學分析,” 第二十屆機械工程研討會論文集，台北市，2003 年 12 月。
49. Kenneth K. Kuo, Grant A. Risha, Brian J. Evans, and Eric Boyer, 2003, Potential Usage of Energetic Nano-Sized Powders for Combustion and Rocket Propulsion, Characterization and Properties of Energetic/Reactive Nanomaterials, Material Research Society, editors: Wilson, W., et al., Pittsburgh, PA, Invited paper, December 2003.
50. Hessley, R.K., Reasoner, J.W. and Riley, J.T. Coal Science, John Wiley & Sons, New York, 1986.
51. Armor, J., “The Multiple Roles for Catalysis in the Production of H2,” Applied Catalysis A, Vol. 176, pp.159-176, 1999.
52. Collot, A.G., “Prospects for Hydrogen from Coal,” The Clean Coal Centre, IEA Coal Research, March 2004.
53. Souza, J.M.T. and Rangel, M.C., “Catalytic Activity of Aluminium-Rich Hematite in the Water Gas Shift Reaction,” Reaction Kinetics and Catalysis Letters, Vol. 83, pp.93-98, 2004.
54. Basinska, A., Klimkiewicz, R. and Telerycz, H., “Catalysts of Alcohol Condensation Tested in Water-Gas in Water Gas Shift Reaction,” Reaction Kinetics and Catalysis Letters, Vol. 82, pp.271-277, 2004.
55. Saito, M. and Murata, K., “Development of High Performance Cu/ZnO Catalysts for Methanol Synthesis and the Water-Gas in Water Gas Shift Reaction,” Catalysis Surveys from Asia, Vol. 8, pp.285-294, 2004.
56. P. Chiesa, S. Consonni, T. Kreutz, R. Williams, “Co-production of hydrogen, electricity and CO2 from coal with commercially ready technology. Part A:
Performance and emissions”, International Journal of Hydrogen Energy 30, 747-767, 2005.
57. Y. Inui, T. Matsumae, H. Koga, K. Nishiura, “High performance SOFC/GT
method”, Energy Conversion and Management 46, 1837-1847, 2005.
58. Y. Li, Q. Fu. M. F. Stephanopoulos, “Low-temperature water-gas shift reaction over Cu- and Ni-loaded cerium oxide catalysts”, Applied Catalysis B:
Environmental 27, 179-191, 2000.
59. G. Jacobs, L. Williams, U. Graham, G. A. Thomas, D. E. Sparks, B. H. Davis,
“Low temperature water-gas shift: in situ DRIFTS-reaction study of ceria surface area on the evolution of formats on Pt/CeO2 fuel processing catalysts for fuel cell application”, Applied Catalysis A: General 252, 107-118, 2003.
60. Felipe, B.L. “The high-temperature, high-pressure homogeneous water-gas shift reaction in a membrane reactor,” Ph.D. Thesis, University of Pittsburgh, 2004.
61. Kaldis, S. P., Skodras, G., Sakellaropoulos, G. P., “Energy and capital cost analysis of CO2 capture in coal IGCC processes via gas separation membranes”, Fuel Processing Technology, 85, 337-346, 2004.
62. Paglieri, S.N. and Way, J.D., “Innovation in Palladium Membrane Research,”
Separation and Purification Methods, Vol. 31, pp. 1-170, 2002.
63. Kikuchi, E., Uemiya, S., Sato, N., Inoue, H. Ando, H. and Matsuda, T.,
“Membrane Reactor Using Microporous Glass-Supported Thin Film of Palladium.
1) Application to the Water-Gas Shift reaction,” Chemistry Letters, p.489, 1989.
64. Uemiya, S., Sato, N., Ando, H. and Kikuchi, E., “The Water-Gas Shift Reaction Assisted by a Palladium Membrane Reactor,” Industrial and Engineering Chemistry Research, Vol. 30, pp.585-589, 1991.
65. A. Basinska, R. Klimkiewicz, and H. Telerycz, “Catalysts of Alcohol Condensation Tested in Water-Gas in Water Gas Shift Reaction,” Reaction Kinetics and Catalysis Letters, Vol. 82, pp.271-277, 2004.
66. M. Saito, and K. Murata, “Development of High Performance Cu/ZnO Catalysts for Methanol Synthesis and the Water-Gas in Water Gas Shift Reaction,” Catalysis Surveys from Asia, Vol. 8, pp.285-294, 2004.
67. B.L. Felipe, The high-temperature, high-pressure homogeneous water-gas shift reaction in a membrane reactor, Ph.D. Thesis, University of Pittsburgh, 2004.
68. Kloetstra K.R., Bekkum H.V. and Jansen J.C.; Chemistry Communication (1997), 2281-2282
69. Law, C. K., and Law, H. K., 1979, “Thermal ignition analysis in boundary layer flows,” Journal of Fluid Mechanics, Vol. 92 pp. 97-108.
70. Law, C. K., and Law, H. K., 1981, “Flate plate ignition with reactant consumption,” Comb. Sci. and Tech., Vol. 25 pp. 1-8.
71. Lewis, B., and Von Elbe, G., 1961, Combustion Flames and Explosions in Gases Academic Press, N. Y.
72. Mori, Y., Miyauchi, T., and Hirano, M., 1977, “Catalytic Combustion of Premixed Hydrogen-Air,” Combustion and Flame, Vol. 30 pp. 193-205.
73. Ablow, C. M., Schechter, S. and Wise H., 1980, “Catalytic Combustion in a Stagnation Point Boundary Layer” Combustion Science and Technology, Vol. 22 pp. 107-117.
74. Lin, M. C., and Sheu, W. J., 1994, “Theoretical Criterion for Ignition of a Combustible Gas Flowing over a Wedge,” Combustion Science and Technology, Vol. 99 pp. 299-312.
75. Sheu, W. J. and Lin, M. C., 1995, “Gas-Phase Ignition of Accelerate Boundary-Layer Flows on Strongly Catalytic Surfaces,” Combustion and Flame, Vol. 103 pp. 161-170.
76. Pfefferle, L. D., Griffin, T. A., Winter, M., Crosley, D. R., and Dyer, M. J., 1989,
“The influence of catalytic activity on the ignition of boundary layer flows Part I:
Hydroxyl radical measurements,” Combustion and Flame, Vol. 76 pp. 325-338.
77. Pfefferle, L. D., Griffin, T. A., Dyer, M. J., and Crosley, D. R., 1989, “The influence of catalytic activity on the gas phase ignition of boundary layer flows Part II. Oxygen atom measurements,” Combustion and Flame, Vol. 76 pp.
339-349.
78. Ben-Yakar, A., and Hanson, R. K., 2001, “Cavity flame-holders for ignition and flame stabilization in scramjets: An overview,” Journal of Propulsion and Power, Vol. 17 pp. 869-877.
79. Perng, S. W., and Dolling, D. S., 1998, “Passive control of pressure oscillations in hypersonic cavity,” AIAA-96-0444.
80. Groppi, G., Belloli, A., Tronconi, E., and Forzatti, P., 1995, “Analysis of multidimensional models of monolith catalysts for hybrid combustors,” AIChE
Journal, Vol. 41 pp. 2250-2260.
81. Eguchi, K. and Arai, H., 1996, “Recent advances in high temperature catalytic combustion,” Catalysis Today Vol. 29 pp. 379-386.
82. Akita T., Tanaka, K, Okuma, K., Koyanagi, T., and Haruta M., 2002, “TEM and HAADF-STEM study of a Au catalyst supported on a TiO2 nano-rod,” Journal of
Electron Microscopy, Vol. 50 pp. 473-477.
83. Landon, P., Ferguson, J., Solsona, B. E., Garcia, T., Carley, A. F., Herzing, A. A., Kiely, C. J., Golunskic, S. E. and Hutchings, G. J., 2005, “Selective oxidation of CO in the presence of H2, H2O and CO2 via gold for use in fuel cells,” The Royal
Society of Chemistry, Chem. Commun. pp. 3385-3387.
84. Crisan1, O., Grenèche, J. M., Le Breton, J. M., Crisan, A. D., Labaye, Y., Berger, L., and Filoti1, G., 2003, “Magnetism of nanocrystalline Finemet alloy:
experiment and simulation,” Eur. Phys. J. B Vol. 34 pp. 155-162.
86. 陳夢萍等，燃氣引擎氣電共生系統工程規劃設計(五)，能源基金專案，1980.
87. Nakat, T., Sato, M, Niromiya, T., Yashine, T., and Yamada, M., “Effect of Pressure on Combustion Characteristics in LBG-Fueled 1300℃-Class Gas Turbine”，ASME J of Gas Turbines and Power, Vol.116.PP 554-558,1994.
88. Look,C. S. , Corman, J.C. , and Todd, D. M., “System Evaluation and LBTU Fuel Combustion Studies for IGCC Power Generation”，ASME J of English for Gas Turbines and Power ,Vol. 117.PP 673-677,1995.
89. Nakata, T., Sato, Mo , Ninomiya, J., and Hasegawa, T., “A Study on Low Nox Combustion in LBG-Fueled 1500℃-Class Gas Turbine”, ASME. J of Engineering for Gas Turbines and Power, Vol. 118.PP 534-540,1996.
90.Kelsall,G.J.,Smith, M A. and Cannon, M.F., ”Low Emissions Combustor Development for and Industrial Gas Turbine to unilize LCV Fuel Gas”. ASME J of Engineering for Gas Turbines and Power, Vol.117.PP 559-566,1994.
91.Domeracki,W.F., Dowdy, T.E., and Bachovchin, Dowdy, T.E., and Bachovchin, D.M., ”Topping Combustor stasus for Second-Generation Pressurized Fluidized Bed Cycle Application”，ASME J of Engineering for Gas Turbines and Power, Vol.119.PP 27-33,1997.
92. Chomiak, J., Longwell, J. P. and Starofim, A. F., “Combustion of Low calorific Value Gases；Problems and Prospects”，Prospects”，Prog Energy Combustion Sci., Vol.15 PP.109-129,1989.
93.Effendi, A., Hellgardt, K., Zhang, Z. and Yoshida, T., “Optimising H2 production from model biogas via combined steam reforming and CO shift reactions”, Fuel, 84, 869–874, 2005.
94.Killmeyer, R., Howard, B., Ciocco, M., Morreale, B., Enick, R.,Bustamante, F.,
“Water-Gas Shift Membrane Reactor Studies”, FY 2004 Progress Report, DOE Hydrogen Program, National Energy Technology Laboratory, 2004.
95.Y. Choi, H. G. Stenger, “Water gas shift reaction kinetics and reactor modeling for fuel cell grade hydrogen”, Journal of Power Sources 124, 432-439, 2003.
附件一、研究成果照片及說明
圖 1-1 SOFC 的運作原理
圖 1-2 SOFC 的形式分管狀(左)與平板式(右)兩大類
圖 1-3 具 Ce0.8Gd0.2O1.9成分的SOFC 在 500℃時的性能曲線
圖1-4 Siemens Westinghouse 之 200 kW SOFC/Gas Turbine Hybrid System
20 30 40 50 60 70 80 LaNiO3 LaFeO3 LaCoO3 LaMnO3
Intensity
2- Theta (degree)
圖4-1. LaBO3（B = Mn﹐Ni﹐Fe﹐Co）觸媒之 X-ray 繞射圖
圖4-2. LaBO3（B = Mn﹐Ni﹐Fe﹐Co）觸媒之 TEM 圖
(a) LaMnO3
(b) LaCoO3
(c) LaFeO3
(d) LaNiO3 (a) LaMnO3
(b) LaCoO3
(c) LaFeO3
(d) LaNiO3
400 450 500 550 600 650
CH4 Conversion (%)
Temperature (oC)
圖4-3 以 LaBO3（B = Mn﹐Ni﹐Fe﹐Co）型式之波洛斯凱特型觸媒 進行甲烷燃燒反應之轉化率與反應溫度關係圖（觸媒重量
=0.25 g；WHSV = 9600 ml g-1 hr-1；甲烷濃度= 5000ppm）
400 450 500 550 600 650 0
CH4 Conversion (%)
Temperature (oC)
圖4-4 以 La0.7A0.3CoO3（A=Ag、Ce、Sr）型式之波洛斯凱特型觸媒 進行甲烷燃燒反應之轉化率與反應溫度關係圖（觸媒重量
=0.25 g；WHSV = 9600 ml g-1 hr-1；甲烷濃度= 5000 ppm）
400 450 500 550 600 650
CH4 Conversion (%)
Temperature (oC)
圖4-5 以 La0.7A0.3MnO3（A=Ag、Ce、Sr）型式之波洛斯凱特型觸媒 進行甲烷燃燒反應之轉化率與反應溫度關係圖（觸媒重量
=0.25 g；WHSV = 9600 ml g-1 hr-1；甲烷濃度= 5000 ppm）
400 450 500 550 600 650
0 CH4 Conversion (%)
Temperature (oC)
圖4-6 不同煅燒溫度對觸媒活性的影響（觸媒= La0.7Ag0.3MnO3； WHSV = 9600 ml g-1 hr-1；甲烷濃度= 5000 ppm）
圖4-7 不同煅燒溫度時 La0.7Ag0.3MnO3的SEM 圖
0 5 10 15 20 25
0 20 40 60 80 100
Temperature = 550 oC Temperature = 450 oC
CH
4Conversion (% )
On-Stream Time (hr)
圖 4-8 La0.7 Ag 0.3MnO3波洛斯凱特型觸媒的穩定性測試（反應時間=
22 hr；WHSV = 9600 ml g-1 hr-1；甲烷濃度= 5000 ppm）
600℃ 800℃
700℃ 900℃
400 450 500 550 600 650
0
CH4 Conversion (%)
Temperature (oC)
圖4-9 不同重量小時空間流速(WHSV)對甲烷燃燒效率之影響（觸媒
= La0.7Ag0.3MnO3；甲烷濃度= 5000 ppm）
400 450 500 550 600
0 CH4 Conversion (%)
Temperature (oC)
圖4-10 不同甲烷濃度對燃燒效率之影響（觸媒= La0.7Ag0.3MnO3；
10 20 30 40 50 60 70
Intensity
2 Theata
(440) (400)
(111)
(222)
(220)
(311)
圖4-11 以溶膠凝膠披覆法所製備之 γ-Al2O3之XRD 圖
圖 4-12 以溶膠凝膠披覆法製備 γ-氧化鋁(500℃煅燒)披覆於蜂巢狀 陶瓷之 SEM 照片
圖 4-13 高溫與低溫轉化反應器示意圖【93】
圖 4-14 氣化合成氣轉化後結合燃料電池之理論系統架構圖
高溫轉化反應 混合氣淨化 氣化合成氣
低溫型燃料電池 降低氣體溫度 低溫轉化反應 去除一氧化碳
高溫型燃料電池 SOFC 高溫轉化反應
混合氣淨化 氣化合成氣
低溫型燃料電池 降低氣體溫度 低溫轉化反應 去除一氧化碳
高溫型燃料電池
SOFC
圖4-15 薄膜反應器之運作原理示意圖【94】
圖4-16 初步設計之水氣轉化反應系統圖
0 10 20 30 40 50
I
2 Theta
Micropores Mesopores
MCM-41
ZSM-5
圖4-17 雙孔徑分子篩(DPMS)之 XRD 示意圖譜
圖4-18 雙孔徑分子篩(DPMS)之催化(CO shift)及富集 H2 之反應途 徑
圖4-19 整合 WGS/PSA/plasma 反應系統以提升 H2產量
2 4 6 8 10
2 Theta
圖 4-20 MCM-41 之 XRD 圖譜
圖4-21 MCM-41 之 TEM 圖譜
圖4-22 MCM-41 之 EDX 元素分析
NW40 KF NW16 KF
View Port Quartz
Copper Disk
½＂
To Vacuum View Port
IR Transmission Window
5"
Electrode Shelter
Electrical Feedthrouhgs
Packing Column
MKS Gauge
Catalyst
1"
圖4-23 電漿腔體結構圖
圖4-24 電漿系統流程圖
圖4-25 不同管道 cavity 型駐焰器內管道格點
圖4-26 不同下游壁面之 open cavity 型態
Stream line
v contour
u vector
u vector
圖4-27 不同下游壁面之 cavity 壓力分布圖
圖4-28 下游傾斜壁面 cavity 之低速流體流場 L/D=8
L/D=4.5 L/D=3.5 L/D=2.5 L/D=1
圖4-29 下游傾斜壁面 cavity 之低速流體壓力
圖 4-30 90°下游壁面與具 45°傾斜下游壁面之 cavity 流場與 壓力變化
L/D=1
L/D=2.5
L/D=3.5
L/D=4.5
L/D=8
圖4-31 流體流經大小不同管道所產生內部渦流與壓力改變的 現象
圖 4-32 外流場式駐焰器測試裝置設計圖
u vector Pressure
contour
圖4-33 產氣（ψ=0.15）與丙烷（ψ=0.30）氣相反應溫度分布
圖4-34 產氣（ψ=0.15）與丙烷（ψ=0.35）氣相反應溫度分布
圖4-35 產氣（ψ=0.20）與丙烷（ψ=0.30）氣相反應溫度分布
圖 4-36 產氣（ψ=0.20）與丙烷（ψ=0.35）氣相反應溫度分布
圖 4-37 駐焰器火焰產生
圖 4-38 微小粒子添加器設計圖
旁通氣流
粒子流
奈米粒子
圖4-39 實驗流程圖
圖4-40 水汽添加基本性能測試，溫度關係圖(水壓 12kg/cm2)
圖4-41 水汽/甲烷莫耳數比對轉速變化曲線圖
圖4-42 水汽添加流量與轉速變化曲線圖
表4-1 觸媒經 X 射線繞射儀（XRD）測得之結晶構造
表4-3 各種材料用於水氣轉化反應器的反應速率【95】
表4-4 實驗參數
流速（m/s） 產氣當量比 丙烷當量比 0.15
6 0.20 0.30 ~ 0.35 0.15
7 0.20 0.30 ~ 0.35 0.15
8 0.20 0.30 ~ 0.35
表4-5 工研院能資所煤炭氣化爐產氣成分表 壓力
bar 氧煤比 CO
%
CO2
%
H2
%
CH4
% 碳轉化率 0.5 0.172 7.5 11.0 9.7 1.1 0.45 1.0 0.175 6.6 10.1 6.4 0.4 0.44 1.5 0.222 8.8 12.0 10.8 0.9 0.56 2.0 0.236 11.2 12.2 12.1 0.3 0.73 2.0* 0.3 10.5 17.8 18.0 0.14 0.80