本論文研究 LiCu2-xZnxO2 單晶樣品與 HoxMn1-xS 多晶樣品的變 溫拉曼散射光譜分析。LiCu2-xZnxO2 單晶樣品的光譜分析有以下幾點 結論：
第一，室溫拉曼散射光譜展現 7 個 Ag 對稱性與 3 個 B1g 對稱 性拉曼活性振動模。隨 Zn 離子摻雜的濃度增加，LiCu2O2 內部沿 ab 平面振動的 O 原子拉曼峰展現紅移且半高寬變寬，這是因為 Zn 離 子取代位於 ab 平面的 Cu 二價離子時，會導致導致 ab 軸晶格常 數變大，與 H. C. Hsu 等人[23] 量測 x 光繞射能譜的結果一致。
第二，我們於室溫觀察到 106 cm-1 特徵峰，認為此屬於拉曼活 性振動模，且隨著無磁矩的 Zn 離子濃度增加，此 106 cm-1 的峰值 強度略為下降，且 Zn 離子濃度為 7 % 時，此峰值變為較寬廣，推 測為一般聲子行為，與 K. Y. Choi 等人[20]所推測之 two-magnon continuum 不符。
第三，LiCu2O2 隨著 Zn 離子摻雜濃度的增加，磁性相轉變溫度 從 24 K 下降至 14 K。當溫度下降，摻雜 7 % Zn 離子的 LiCu2O2 在 磁性相轉溫度 14 K 以下，492 cm-1 拉曼峰展現微小紅移，此振動模
用。
HoxMn1-xS 多晶樣品的光譜分析顯示以下三點結論：
第一，室溫 HoxMn1-xS 多晶樣品拉曼散射光譜展現 4 個拉曼活 性振動模，其頻率位置約為 135 cm-1、227 cm-1、333 cm-1 及 585 cm-1，隨著摻雜 Ho3+ 離子濃度的增加，333 cm-1 與 585 cm-1 拉曼峰 展現紅移，且從 x 光繞射能譜可以看到隨著摻雜 Ho3+ 離子濃度的 增加，(002) 峰值往低角度移動，這是由於 Ho3+ 離子半徑為 0.90 Å ， 而 Mn2+ 離子的離子半徑為 0.83 Å ，當半徑較大的 Ho3+ 離子取代半 徑較小的 Mn2+ 離子所導致的現象。
第二，低溫下的 HoxMn1-xS 在摻雜濃度為 0.01 時，展現擴散式 電子響應的現象，當摻雜濃度為 0.1 時，擴散式電子響應消失，推 測強磁矩 Ho 離子摻雜的關係，電子較被侷限在晶格內，導致擴散 式電子響應不明顯，此與在低溫下摻雜濃度為 0.1 時電阻率高於摻 雜濃度為 0.01 的現象一致。
第三，HoxMn1-xS 在摻雜濃度為 x = 0.01 時，333 cm-1、585 cm-1 拉曼峰對應到其電阻率異常變化的溫度附近，其權重有明顯降低的現 象，且同溫度對應到晶格常數也有不連續的行為，推測此現象可能為 電子雲軌道有序性、或者電荷有序性有關。
拉曼散射光譜實驗，並進行第一原理的計算，以得知其內部原子振動 模式。另外，對於 HoxMn1-xS 多晶樣品，則希望進行高溫全頻反射 光譜實驗，探討高溫光學電導率，與高溫電阻率實驗結果進行比較，
並利用穿隧式電子顯微鏡進行電子繞射實驗、x 光散射實驗以及磁化 率隨溫度的變化，確認 HoxMn1-xS 多晶樣品於高溫時，電荷、軌道與 自旋有序性行為。
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