• 沒有找到結果。

5-1 結論

本研究以稻殼作為生產纖維酒精之原料,又以完全利用稻殼為目的,

因此利用氫氟酸搭配鹼性過氧化氫前處理方法使稻殼結構鬆散化,以 提升葡萄糖產率且可將灰分回收再利用。綜合對於稻殼進行前處理的 各個條件,以及其所造成之成分變化分析和葡萄糖產率的探討比較後,

本研究獲致下列結論:

1. 本研究水解反應根據處理之目標物判斷無需加入纖維雙醣酵 素也可將稻殼水解為單醣。

2. 對稻殼做氫氟酸前處理之結果,在氫氟酸與二氧化矽莫耳比為 14 時,灰分去除達 90%以上,其葡萄糖產率僅約 6%,後續便 將莫耳比14 處理過的稻殼再以鹼性過氧化氫處理,以達去除 木質素使葡萄糖產率提升之目的。

3. 以處理後葡萄糖產率為前提使用鹼性過氧化氫添加量為 4 時,

木質素去除率高達80%,木質素對稻殼造成之束縛降為最低,

又其產率為99%,酵素幾乎能將此處理過之稻殼的纖維素及半 纖維素完全水解為醣類以供酵母醱酵;若以原始葡萄糖產率為 考慮時,其鹼性過氧化氫最佳添加量為3,約為 83%,過多添 加則為浪費。

4. 使用鹼性過氧化氫處理的稻殼其酵素水解醣產量明顯高於單 獨使用氫氧化鈉或過氧化氫,因過氧化氫在鹼性情況下行氧化 作用較為劇烈,推論能溶解較多的木質素與半纖維素,使纖維 素百分比與酵素水解醣產量提升。

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5. 由酵素水解不同過氧化氫與氫氧化鈉添加比例處理稻殼之醣 產量和葡萄糖產率結果得知,總醣產量於添加比例為4 時達到 最高,而葡萄糖產量卻隨比例增加而增加,木糖產量則趨於減 少,推論越多氫氧化鈉處理稻殼,越易去除半纖維素;然而葡 萄糖產率於添加比例為4 時達到最高,增加劑量添加比並不會 使產率提升,更造成纖維素流失及藥劑浪費。

6. 以氫氟酸萃取出的灰分經本實驗室回收後便能製成不同中孔 洞材料,以達完全回收再利用之目的。

7. 在探討氫氟酸搭配鹼性氫氧化鈉完全前處理中氫氟酸的貢獻 程度的研究中,若使用氫氟酸搭配鹼性過氧化氫處理稻殼後,

木質素及其他成分有更多的去除,使纖維素之單位百分比上升,

尤其木質素的去除率更是較無氫氟酸處理之從60%提升至 80%,而處理葡萄糖產率也從 86%提升至 99%。有氫氟酸先處 理過,能將灰分幾乎萃取出來進行回收,又使木質素有些許破 壞,鬆散了稻殼結構,令後續的鹼性氫氧化鈉前處理更易發揮 作用,溶解出更多的木質素。

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5-2 建議

1. 本研究使用鹼性過氧化氫處理過後之廢液為一鹼性溶液,為達 充分回收利用,可將此鹼性溶液重覆對稻殼作前處理。

2. 本研究使用鹼性過氧化氫處理過後之廢液富含木質素,而目前 已有一些研究能將木質素回收為許多用途(黃修志,2001;

Joiner 2005),如作為橡膠的補強劑、水泥的增塑劑、印染工業 的分散劑和染料助劑、油墨分散劑、礦石浮選劑、工業洗滌劑、

鍋爐清潔劑等,建議能將木質素回收以達到零排放之目的。

3. 本研究並未完成纖維酒精之完整程序,只著重於前處理改善酵 素水解之階段,惟因目前醱酵研究已趨於完整並已實廠化,且 其轉化效率也可達95%以上,並不是纖維酒精研究之重點,但 建議仍可參考實廠數據建立醱酵系統,完成纖維酒精生產。

4. 本研究只對農業廢棄物中之稻殼作探討,若要全面針對農業棄 物做完全回收再利用,需進一步探討其他農業廢棄物,例如稻 桿、蔗渣、玉米葉等,其因成分與形態不同,前處理之方法與 條件也需做調整。

5. 本研究所使用之氫氟酸可以台灣科技園區所使用之廢氫氟酸 來替代,可令處理成本大輻減少又達成廢棄物資源化之目的。

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