• 沒有找到結果。

5-1 前驅物之影響

1. 從 FTIR 結果可得知,以不加入醋酸反應之前驅物具有 W-O-O 鍵 結,導致水解不完全,使得薄膜表面有較大顆粒存在,影響薄膜品 質。加入醋酸之前驅物使用白金除去未反應之過氧化氫方式,反應 結束後,仍有殘餘之過氧化氫存在,故以迴流方式在一固定溫度下 進行反應,能讓前驅粉體反應更趨完全。

2. 觀察AFM與SEM圖,以Mz+製備出之氧化鎢鍍膜具有明顯顆粒,這 是因為縮合反應較水解反應速度快造成之結果。而薄膜表面孔洞大 小以用白金片去除過氧化氫之金屬烷氧化合物,製備之氧化鎢鍍膜 最大,以Mz+製備出之氧化鎢鍍膜最小。

3. UV-VIS-NIR光譜實驗結果,反應較完全之前驅物三號,具有較佳的 穿透率改變為60%,最差為以Mz+製備出之氧化鎢鍍膜,著-去色穿 透率差為43%。

4. 電化學檢測中,循環伏安法結果以迴流方式去除過氧化氫之金屬烷 氧化合物,製備之氧化鎢鍍膜之峰值電流最大。著-去色響應時間以 用白金片去除過氧化氫之金屬烷氧化合物,製備之氧化鎢鍍膜速度 最快。

5-2 退火環境之影響

5. 從 AFM 與 SEM 影像觀察,可以發現經過退火之氧化鎢薄膜,比初 鍍之氧化鎢薄膜具有較高的緻密度,微孔與晶粒大小皆以真空狀態 時最大,緻密度以大氣退火為佳。

6. 由 XRD 結構分析結果,說明了經過退火處理薄膜表面出現微弱的

結晶情形,而以真空退火之訊號峰最大。

7. 紫外光-近紅外光光譜實驗結果,以氧氣氛退火之氧化鎢薄膜在可見 光區透明度最高,而經過真空退火之氧化鎢薄膜可見度最差,與其 氧化鎢薄膜氧缺陷多寡有關。實驗結果以氧氣氛退火之氧化鎢薄膜 效率最佳,具有約22%之著-去色穿透率差,真空退火製備之氧化 鎢薄膜效率最差,著-去色穿透率差為 16%。

8. 電化學檢測中,循環伏安法實驗結果顯示,氧化鎢薄膜著-去色響應 時間以未退火速度最快,經過大氣退火處理之氧化鎢薄膜所需時間 最久。

5-3 未來展望

1. 實驗中添加檸檬酸為蟄和劑,未來實驗可藉由調整酸之比例,達到 最適之水解參數,進而控制薄膜品質。

2. 添加其他元素合成(Ti、Zn、Ni 等等),研究其光學性質、結構效 應、表面型態對於電致色變之影響。

3. 在本實驗中未對塗佈之薄膜進行壽命耐久性之測試,但考量到將來 應用,使用次數為其重要考量,未來應對製備薄膜做壽命之評估測 試,增加利用價值。

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