本論文主要合成各種不同的聚醯亞胺/聚苯胺奈米高分子複合材料，探討 高分子添加奈米陶瓷及碳管對其機械性質、熱性質、電性及其顯微結構等的 影響。
1. 本研究成功合成 PI/Silica、PI/MWNTs、PANI/TiO2、三種奈米複合材 料。依據實驗結果，奈米添加粒子的分散性對於材料的相關特性有極 大的影響。
2. 對 PI/Silica 系統而言，奈米 Silica 對於 PI 的介電性質有降低的功效，
若加上微量含氟的單體來對Silica 表面作改質，則可達到 2.55 介電常 數的範圍。比傳統低介電PI 需用含氟單體進行合成要經濟得多。
3. 不同的含氟單體對奈米 Silica 表面改質的效果也不一樣。其中 6FBPA 對於粒子分散及介電常數的降低效果，比BISAF 單體更為顯著，主 要的原因是6FBPA 也是一個 amide 的單體，其兩端的官能機就是很 好的反應機構，可以與Silica 產生鍵結，反觀 BISAF 的兩端就只有 OH 基，無法提供鍵結的條件。
4. PI/MWNTs 系統中，MWNTs 的添加達 15%wt 時可使 PI 的儲存模數 比純PI 提高 9 倍之多，達 28.457GPa。MWNTs 添加達 7%wt 時其拉 伸強度約為純PI 的兩倍。
5. MWNTs 的分散性對於 PI 的性質有絕對的影響，我們成功使用強酸來
增加MWNTs 的表面官能基並除去表面的雜質，使 MWNTs 與 PI 有 更好的鍵結，並達到更均勻的分散性。
6. 一系列的 PANI/TiO2 奈米高分子複合材料之合成及備製已完成。由 XRD 及 TEM 的分析結果，TiO2已成功地混合於PANI 之中
7. 在 1~5wt%TiO2的添加量下，介電常數及介電損失都隨著TiO2 的增 加而增加，導電度也隨著TiO2 （1~5wt%）的增加而增加。
8. 不同 Size 的 TiO2 與PANI 所形成的奈米複合材料，其 SEM 的 morphology 有相當大的差異，P-25 的 TiO2 Size（50nm） 較大分散 較均勻，PANI 就將其包覆成顆粒狀。Hombikat 的 TiO2 其 Size（25nm）
較小凝聚嚴重，PANI 就形成連續的片狀。
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