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Chapter 1 Introduction

1.2 Organization of the Thesis

The thesis is divided into six chapters. Chapter 1 is the introduction. Chapter 2 describes the experiment setups and the ID-RTN mechanism. In chapters 3 and 4, we will first utilize the ID-RTN method to observe the process-induced RTN behavior of strained n-MOSFETs and p-MOSFETs respectively. The hot carrier stress would be applied on the strained CMOS devices. Then, we will discuss the strain induced degradation for n-MOSFETs and p-MOSFETs with different strained techniques. In chapter 5, the application to the SiC S/D device will be studied. Finally, a summary and conclusion will be included in Chapter 6.

Chapter 2 Random Telegraph Noise Mechanism

and Experimental Setup

2.1 Introduction

Recent developments in strained technology have heightened the need for the high performance CMOS devices. The charge pumping measurement can be used to measure the fast trap properties [2.1]. However, the charge pumping current becomes very small in the small area devices that would influence the experimental results for reliability. In order to discriminate the relationship between performance and reliability properties of the small size strained CMOS devices, we utilize the Drain Current Random Telegraph Noise (ID-RTN) measurement technique in this work. In this chapter, the measurement setup and the physics of the drain instability will be described.

This chapter is divided into two sections. First, we will illustrate the fundamental experimental setup to characterizing strained CMOS devices. Second, the ID-RTN technique used in this thesis will be introduced, and its fundamental theory will be described.

2.2 Experimental Setup

The experimental setup for the direct current I–V and the ID-RTN measurement of semiconductor devices is illustrated in Fig. 2.1 and Fig. 2.2, respectively. Through the PC controlled instrument environment, the complicated and long-term characterization

procedure for analyzing the intrinsic and degradation in MOSFETs can be easily verified.

As shown in Fig. 2.1, the characterization equipment, including semiconductor parameter analyzer (HP4156C), and cascade guarded thermal probe station, provides an adequate capability for measuring the device characteristics. In this method, the pulse generator is not included that would decreases the influence from the noise. In addition, the PC program used to control all the measurement process is HT-basic. The parameter analyzer is connected to the probe station directly without passing through the switch equipment.

At the room temperature, the sampling mode is chosen and the VGS, VDS bias is selected to make the trap’s energy level in the vicinity of the Fermi level. For the sampling rate, the minimum resolution is 1ms for the maximum 103 reading per second. If the interval time sets too larger than the capture and emission, the drain current fluctuation may not be observed. With sufficient fast sampling rates, we could detect the drain current fluctuation. Furthermore, ID-RTN happens only during local gate bias so it is better to detect varying tight gate voltage step while sampling. In addition, the RTN phenomenon would be detected easily as the devices scaling down but the magnitude of the drain current decreases.

In order to extract the capture time, emission time, and drain current amplitude, we use the program statistically to take a large amount data. For the two-level drain fluctuation, we select a current which lies in the middle of the high and low current state to discriminate trap capturing or emitting carriers automatically and sum up every period of the time which is then divided by the number of events. In this manner, we can get the mean capture time, emission time, and also drain current amplitude efficiently without wasting too much time. As a result, we can observe the trap properties.

2.3 Theory of Drain Current Telegraph Noise

Figure 2.3(a) is the schematic showing the carrier trapping and detrapping through the oxide trap. In small devices, only trap energy within a few kT from the Fermi level would make current fluctuation where k and T are the Boltzmann constant and equilibrium temperature, respectively. So far, the drain current fluctuation is generally influenced by two effects: the number fluctuation of free channel carriers ΔNs, and the mobility fluctuation Δμ described by [2.2][2.3].

(2.1)

in the strong inversion. Here Ns is the channel carriers per unit area andα is the scattering coefficient while the sign in front of the mobility fluctuation is determined by the type of the trap (repulsive or attractive scattering center). For an acceptor type trap, the high level corresponds to the neutral state (no captured carrier) while the low level corresponds to the charged state. When the traps in the dielectric are empty and their energy level maintain at a level which is equal to that of the channel carriers or below, traps will capture carriers from the channel. When the carriers are trapped, they will increase the nearby potential and lower the current.

The three major parameters (capture time, emission time, and current amplitude) of the ID-RTN are defined in Fig. 2.3(b), capture time c is the average of the high time constants, emission time e is the average of the low time constant and current amplitude ΔID is the magnitude of the drain fluctuation. The current amplitude, capture and emission time are the critical parameters of random telegraph noise phenomenon which

1 ]

depend on the trap properties, such as trap depth into dielectrics, trap energy apart from conduction band (valance band if holes are captured and emitted).

Parameter Analyzer HP 4156C

PC

Probe Station

Fig. 2.1 The measurement setup using Analyzer HP 4156C to sampling as RTN processing. Notably there is not switch equipment HP 5250 here.

Fig. 2.2 The terminals setup for sampling by Analyzer HP4156C.

Poly-S i SiON O

Source Drain

Substrat e

+V G

+V D

trap

em ission captu re

S D

carrier

(a)

(b)

Fig. 2.3 (a) Carrier trapping and detrapping by the slow trap near the drain side. (b) Illustration of the three parameter of the RTN noise: capture time c, emission time e , and current amplitudeΔID.

D ra in C u rr en t

Time

 c

 e

Δ I D

Chapter 3 Random Telegraph Noise of Drain Current in

n-MOSFETs

3.1 Introduction

Recently, researches have shown an increasing interest in the strain technology.

Strained silicon technology is essential for the continuation for the scaling of MOSFET devices, owing to its high impact on carrier mobility and thus on drive current improvement [3.1]. When applied to the direction of the channel, tensile strain improves the performance of n-MOSFET devices, while compressive strain is beneficial for p-MOSFET devices. The local strain, such as capping layer, SiGe on S/D, and SiC on S/D are induced by the process. They are usually uniaxial strain. Compared to the global strain usually biaxial strain, the local strain has less dislocation issues.

As the devices being scaled, there are plenty of reliability issues in the strained devices. Besides, trapping of a single carrier charge in traps and related local modulation in carrier density and mobility will have a profound influence in the carrier density and mobility on the drain current. The drain current fluctuation will cause serious drawbacks on the small geometry devices.

In this chapter, the ID-RTN “Drain Current Random Telegraph Noise” for the exploration of strain-induced slow trap properties is presented in strained n-MOSFETs.

Single electron capture and emission could be observed. The analysis of the reliability will be introduced first in Section 3.3. Next, the analysis of drain current instability is

interpreted in Section 3.4. Based on the voltage dependence of single charge effect, the traps parameters are extracted and the strain process induced-effect will be also discussed.

3.2 Device Preparation

The devices were fabricated by the advanced 65nm CMOS technology at UMC.

The schematic cross section diagram of n-MOSFET splits is shown in Fig. 3-1. In this figure, Fig. 3-1(a) is the bulk-Si device, and Fig. 3-1(b) is the CESL (contact etching stopping layer) capped device (uniaxial-strained). Both n-MOSFETs are <100> channel on (100) substrate. All these test devices have 14Å EOT gate oxide with SiON process and with the same dimension (W/L= 0.2/0.12um).

3.3 The Analysis of Reliability in n-MOSFETs

3.3.1 Introduction

The strain technologies can enlarge the mobility to achieve the significant driving current enhancement [3.2] [3.3] [3.4]. However, many technologies have been developed to boost the drive current; the reliability issues have been rarely studied. It is necessary to consider the effects for device characteristics involving uniaxial and biaxial strained effects for CMOS devices.

A large mobility enhancement would adversely affect the device reliability [3.5].

For n-MOSFETs, the CESL device becomes the most promising technology and the better reliability, especially with process simplicity. In 2006, S. S. Chung et al. [3.6] first

published a paper, in which they demonstrated for n-MOSFETs, tensile cap stressor device is much better in terms of reliability and performance. Based on the important results, we will further analyze the reliability issues of strain n-MOSFETs and investigate them by the ID-RTN method after hot carrier stress. They are described in two parts. The first part is to investigate hot carrier degradation and the second part is to analyze the drain current instability after HC stress in bulk-Si and CESL devices. For hot carrier degradation, threshold voltage shift, drain current degradation and transconductance degradation would be observed by electric measurement. These stresses generate the interface trap and fixed oxide charges. For the drain current instability, the stress-induced traps’ properties and the relationship between the strain and the ID-RTN results would be studied.

3.3.2 Drain Current Degradation

The procedure of following experiment is shown in Fig. 3.2. Firstly, in the ID-VG

step, the purpose is to get the basic semiconductor parameters and make sure the devices can work successfully .Then, the devices are subjected to the ID-RTN analysis, to ensure that there is no current fluctuation in the fresh devices (i.e., no process induced traps).

Then, we apply the hot carrier stress, to produce the oxide traps near the drain region which would show a two-level fluctuation of drain current. Subsequently, the ID-RTN measurement is applied to the stressed devices. Under hot carrier stress with injecting hot electrons to destruct gate dielectrics, we could prevent the effect of changing temperature and measure RTN at once. Traps generation for apparent two-level fluctuations is hard to say happening on specific time and its dependence with time on different stress voltage is also not regular. In our measurement, after HC stress (VGS= VDS= 2.5V for 300sec), we

obtain significant RTN appearance in the linear region and continued subsequent analysis.

We show the ID-RTN measurement results for stressed devices and discussed the induced slow traps properties in the coming sections.

Figures 3.3 (a) and (b) show the drain current degradations before and after the HC stress. The drain current degradation in CESL device is 27.16% and in bulk is 15.62%.

The CESL device shows large drain current degradation than bulk device, as result of its higher impact ionization rate (IB/ID) caused by the strain effect [3.7]. A large enhancement of the driving current will adversely degrade the device reliability.

3.4 The Analysis of I

D

-RTN in n-MOSFETs

3.4.1 Drain Current Waveform

The stress induced slow oxide trap near the drain side which would cause the drain current instability (ID-RTN) through the trapping and detrapping of channel carriers. The ID-RTN measurements were performed in linear operation at a constant drain voltage VDS= 0.05V for gate voltages VGS between 0.3 - 1 V, in steps of 20mV using HP4156C.

Fig. 3.4 and Fig. 3.5 show the different ID-RTN wave spectra for bulk-Si and CESL devices respectively. The drain current amplitude is about 50nA.

3.4.2 Capture and Emission Time

Fig. 3.6 and Fig. 3.7show the mean capture and emission time gathered statistics from Fig. 3.4 and Fig. 3.5. The decrease of c, as gate bias increases shows the acceptor type of the generated slow oxide trap [3.8]; and the capture time, c, of the slow oxide



trap in the CESL device is larger than bulk-Si device in Fig. 3.6, which implies that the trap is deeper in CESL device is larger than the bulk-Si device. The magnitudes of emission time e are both about 0.01~ 0.1 sec. While, the magnitudes of the emission time

e do not show much difference. From the dependency of e, versus gate bias, the carrier in bulk-Si device detraps via Frenkel-Poole emission while carrier in CESL device detraps via trap-assisted-tunneling to the silicon substrate. Due to the thermal emission for the carrier in the bulk-silicon’s trap, the emission time decreases as gate voltage increasing in Fig. 3.6. This implies that the bulk device’s trap is near the Si/SiO2 interface.

While the carrier detraps through thermally assist tunneling to the Si for CESL device, emission time increases as gate voltage increases in Fig. 3.7. Furthermore, the trapping and detrapping events happen more frequently in CESL devices so the capture time over the emission time increases more quickly in CESL than bulk device in Fig. 3.8. This also assures that the HC stress produces more damage at the Si/SiO2 for the CESL device and the trap is deeper in CESL device than bulk-Si device ones.

3.5 Discussion

According to the Shockley–Read–Hall statistics [3.9], the capture time c is sensitive to the channel carrier density n, the average carrier velocity v, and the capture cross-section as Eq. (3.1), where

Here,  is the capture cross section. Here, 0 is the cross-section prefactor, and EB is the thermal activation energy for capture. T and v are usually taken to be the equilibrium lattice temperature and average thermal velocity vth. This approximation is invalid at large lateral electric field, and electron heating occurs and affects the electron capture time. As the gate bias increasing, the capture time would be decreased due to the increased carrier density in the channel. Emission time e is given as Eq. (3.3) [3.10],

(3.3)

where g is the degeneracy factor. The term (EF-ET) represents the trap energy with respect to the Fermi energy. kB is the Boltzmann constant.

3.5.1 Trap Depth

The relationship between the mean capture and emission times and trap parameters can be described as the following [3.11],

and VFB is the flat-band voltage. We can estimate Zeff, effective depth from substrate, from measurements of c/e by varying VG. The trap depth is extracted from the slope of ln(c/e) versus VG as shown in Eq. 3.5. Zeff is 1.09A for bulk device and 6.70A for CESL device shown in Fig. 3.10. The trap in CESL is deeper than the trap in bulk-Si. The characterized depth of generated traps in Fig. 3.10 shows that CESL device will cause more fluctuations, Fig. 3.5. This also assures that HC stress produces more damage in the Si/SiO2 for the CESL and the trap location is deeper is deeper in CESL than in bulk-Si, Fig. 3.10.

3.5.2 Normalized Drain Current Amplitude

Fig. 3.11 and Fig. 3.12 show the drain current amplitude gathered statistics from Fig.

3.4 and Fig. 3.5 divided by the drain current and take plots as function of gate bias. At very low drain voltages in the strong inversion, the mobility fluctuations term Δμ/μ plays a more dominant role than the number fluctuations Δ Ns / N [3.11], i.e.,

(3.6)

Furthermore, the variation of the RTN amplitude ΔID/ID is proportional to the normalized transconductance change gm/ID ratio[3.12]

(3.7)

carrier fluctuation Δ Ns nor by the mobility Δμ[3.11]. Since a screened Coulomb scatter with very similarαvalues for comparable channel electron densities [3.11][3.13] , the ΔID/ID roll-off quickly in CESL device reveals that an extra carrier scattering is induced.

This will give rise to an additional mobility degradation of the CESL device after the HC-stress.

Gate

n n

(a)

(b)

Fig. 3.1 The cross-section view of the experimental devices. (a) bulk-Si and (b) CESL (contact etching stopping layer) capped devices (uniaxial-strain). Both of them are <100> channel on (100) substrate.

Bulk

CESL

Capping Layer

Procedure

Hot Carrier Stress I

D

-V

G

I

D

RTN

I

D

RTN

Fig. 3.2 The operating procedure of the following analysis for the devices.

0 . 0 0 .2 0 . 4 0 . 6 0 .8 1 . 0 before and after the HC stress, (a) bulk-Si and (b) CESL devices.

0.5 1.0 1.5 2.0

Fig. 3.4 Drain current waveform of bulk-Si device, T=25℃

0.5 1.0 1.5 2.0

Fig. 3.5 Drain current waveform of CESL device, T=25℃

0.6 0.7 0.8 0.9 1.0 10

-3

10

-2

10

-1

10

0

10

1

Gate Voltage (V) C a p tu re T ime , c( se c)

10

-3

10

-2

10

-1

10

0

10

1

E mi ss io n T ime ,

e (s ec )

Tox=14A

W/L=0.2/0.12 m

Capture time Emission tim e

Bulk(n)

Fig. 3.6 Variation of capture time c (filled symbol) and emission time e (open symbol) as gate voltage increases for bulk-Si device.

0.4 0.5 0.6 10

-3

10

-2

10

-1

10

0

10

1

10

-3

10

-2

10

-1

10

0

10

1

C a pt u r e T im e , c (s ec )

Gate Voltage (V)

Tox=14A

W /L =0.2/0.12 m

Capture time Emission time

C ESL

E m is sio n T im e , e ( se c )

Fig. 3.7 Variation of capture time c (filled symbol) and emission time e (open symbol) as gate voltage increases for CESL device.

0.4 0.6 0.8 1.0 1

10 100

c / e

G a te V o ltag e (V )

B u lk (n ) C E S L Z eff=6.7A

Z eff=1.09A

Fig. 3.8 Capture time over emission time versus gate voltage plots for n-MOSFETs.

Fig. 3.9 Energy band diagram at the trap position in the channel.

Ec

Ev E

F

E

Cd

- E

T

Z

eff

 

E

Fg Cg

Trap

 

Channel Dielectric

Gate

φ 0

q Ψ

S

(a)

(b)

Fig. 3.10 The effective depth location for the two traps in, (a) bulk-Si and (b) CESL devices.

6.7Α

 

Trap

Channel Dielectric

Gate

1.09Α

 

Trap

Channel Dielectric

Gate

0.6 0.7 0.8 0.9 1.0 0.00

0.02 0.04

Tox=14A W/L=0.2/0.12 m VDS=0.05V

Bulk(n)

I D

/I D g

m

/I

D

I

D

/I

D

Gate Voltage (V)

Fig. 3.11 Normalized RTN amplitude (filled symbol) and normalized conductance change (open symbol) versus gate voltage for bulk-Si device.

0.4 0.5 0.6 0.7

gm/ID

I D /I

D

T ox=14A

W /L =0.2/0.12 m V

DS

=0.05V

C E SL

I D

/I D

G ate V oltage (V )

Fig. 3.12 Normalized RTN amplitude (filled symbol) and normalized conductance change (open symbol) versus gate voltage for bulk-Si device.

Chapter 4 Random Telegraph Noise of Drain Current in

p-MOSFETs

4.1 Introduction

Mobility enhancement is a method to improve the CMOS devices performance with the scaling of the device size. The increase of carrier mobility is necessary to realize the high-speed CMOS devices. Recently, various strain technology have been utilized to enhance the drive current. It is necessary to understand the introduced uniaxial and biaxial strains in n-MOSFET or p-MOSFET devices. Initially, the typical mobility enhancement of n-type strained-Si is much larger than that of p-type devices. Several techniques have been further developed to enhance the p-MOSFET performance, i.e., SiGe on S/D device [4.1]. Materials with same crystal structure but different lattice are good candidates for strain engineering. The SiGe has been successfully incorporated in the source and drain of p-MOSFET devices to strain the channel compressively and increase the hole mobility. Furthermore, trapping of a single carrier charge in traps and related local modulation in carrier density and mobility exhibit a profound influence in the carrier density and mobility on the drain current. The drain current fluctuation will cause serious drawbacks on the small geometry devices.

In this chapter, the ID-RTN “Drain Current Random Telegraph Noise” for the exploration of strain-induced slow trap properties is presented. Single electron capture and emission could be observed in strained p-MOSFETs. The analysis of the reliability will be introduced first in Section 4.3. Next, the analysis of drain current instability is

interpreted in Section 4.4. Based on the voltage dependence of single charge effect, the traps parameters are extracted and the strain process induced-effect will also be explained.

4.2 Device Preparation

The schematic cross sections of p-MOSFET splits are shown in Fig. 4-1. In this figure, Fig. 4-1(a) is the bulk-Si device, and Fig. 4-1(b) is the SiGe on source/drain device (uniaxial-strain) with EDB (Embedded Diffusion Barrier). Both p-MOSFETs are

<110> channel on (100) substrate. All these test devices have 14Å EOT of SiON gate oxide and with the same dimensions, W/L = 0.2/0.12 μm. The ID-RTN was investigated in bulk and SiGe on S/D pMOSFET devices fabricated using a conventional CMOS process flow.

4.3 The Analysis of Reliability in p-MOSFETs

4.3.1 Introduction

For many strained approach to enhance the carrier mobility, the reliabilities are still a serious issue. The biaxial strained SiGe-channel device provides good drive current enhancement, it suffers from the Ge-outdiffusion such that exhibits worse reliability. The SiGe on S/D device is a promising structure for p-MOSFET design since it keeps at about the same reliability as the SiGe-channel ones while exhibits a much higher performance.

In contrast, SiGe-channel has a major concern with lattice misfit [4.2]. Besides, for p-MOSFET devices, the SiGe on S/D device with EDB [4.3] is the most promising in terms of performance and reliability.

In this section, we analyze the reliabilities of strained p-MOSFET devices and investigate them by the ID-RTN method after hot carrier stress. We divide the contents into two main sections. The first part is to investigate hot carrier degradation and the second part is to analyze the drain current instability for p-MOSFETs. In hot carrier degradation, threshold voltage shift, drain current degradation, and transconductance degradation would be observed by electric measurement. These stresses generate the interface trap and fixed oxide charges. For the drain current instability, the stress-induced traps’ properties and the relationship between the strain and the ID-RTN results would be understood. Finally, the comparison for the strained n- and p-MOSFETs would be discussed according to the previous result.

4.3.2 Drain Current Degradation

4.3.2 Drain Current Degradation

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