1. 利用奈米零價鐵金屬、零價鋁金屬、鐵鋁複合金屬加入低濃度甲醇，
測定在反應系統中甲醛生成量。以計算出不同金屬的氧化能力以及轉 化效率。
2. 利用鐵鋁複合金屬加入去離子水，測定在水體中溶氧濃度的變化。以 利得知水中溶氧的消耗，是為生成過氧化氫所致。並了解氧氣對於鐵 鋁複合金屬的氧化機制的重要性。
3. 利用 EPR 量測確定鐵鋁複合金屬在反應系統下自由基的生成種類，以 及改變反應參數去確認其生成的自由基是為甲基自由基，並了解其自 由其產生的途徑。並去定量其釋出自由基的強度。
4. 藉由偵測碳氫化合物的生成，了解鐵鋁複合金屬釋出的甲基自由基與 反應系統中二氧化碳的關聯性。並透過碳氫氧化合物生成種類及濃 度，確認其生成途徑與機制。
5. 管柱試驗方面須改變其操作條件，使其染整實場廢水在經過處理後能 達到環保署的放流水標準。並將廢棄鋁渣之鐵鋁複合金屬運用到實場 的廢水處理。
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附錄一 實驗數據
不同反應系統降解甲醇的總有機碳
0 hr 24 hr
Methanol 11.0333 10.8769
1 g Fe/Al 11.0333 10.6612
鐵鋁複合金屬(10 g/L)在 31.64 mg/L 甲醇生成甲醛
8 1325.0000 1325.0000 1200.0000
24 1525.0000 1875.0000 1675.0000
不同零價金屬(10 g/L)降解 60.39 mg/L 甲酸
不同零價金屬(10 g/L)在去離子水生成亞鐵離子
鐵鋁複合金屬(5 g)對於不同高濃度染料的 COD 降解變化
不同鐵鋁複合金屬配比(5 g)對於不同染料的 COD 降解變化
鐵鋁複合金屬對染料廢水真色色度去除效果
染料種類 0 hr ADMI 24 hr ADMI
分散性黑色 11778 550
分散性紅色 12904 326
反應性黑色 48298 225
反應性紅色 167268 219
酸性黑色 20819 488
酸性紅色 61635 664
鹽基性黑色 8289 705
廢棄鋁渣鐵鋁複合金屬(5 g)對於不同染料廢水的 COD 降解變化 染料種類 0 hr COD (mg/L) 24 hr COD (mg/L)
酸性黑色 404 60
酸性紅色 498 88
鹽基性黑色 375 96
2 種混合染料 338 74
3 種混合染料 538 66
原始廢水 1867.5 485
生物處理後廢水 360 170.67
附錄二 口試委員意見回覆
為 何做 不 同 濃度 的 甲 醇生
甲 醛測 定 是 使用 何 種 分析