• 沒有找到結果。

第五章 結論與建議

5.2 建議

1. 氧化鈣的改質可以嘗試朝增加其孔隙度的方向進行,除了於改質 過程中加入水與氧化鈣接觸反應外,更可嘗試使用界面活性劑控 制其孔洞,提高其比表面積。

2. 建議可加大填充管柱的內徑以增加反應停留時間,在更大的參數 可變範圍下,可進一步了解其對去除效率的影響,並驗證回歸式 的準確度。

3. 為模擬燃煤發電場的煙道氣流,於管柱系統進行循環吸脫附測試 時,將進流氣體濃度調整為15 % CO2、6 % O2與79 % N2,然而煙 道氣流中尚有SOx與NOx等有毒氣體的存在,如能在實驗中亦將其 考慮進去,將可得到吸附劑更確實的劣化資訊。

4. 欲獲得高純度的二氧化碳,建議可嘗試用水蒸氣對吸附劑進行脫 附反應,其後藉由冷凝作用再將二氧化碳分離出來,如此對實際 應用時的經濟效益必能有所提升。

5. 使用有機鋁改質石灰石亦能有效減緩其於循環再生時的劣化問 題,惟其改質效果不如使用藥品級氧化鈣時來得好,然即使是吸 附表現最佳的CaAl(95)-O,其離0.786 g CO2/g CaO的理論吸附量仍 有一段差距,代表在氧化鈣的改質上仍有進步的空間。

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