• 沒有找到結果。

In this dissertation, we mainly focus on the some possible solutions for the multi-gate MOSFET and multi-multi-gate flash memory. In the first part, the influence by the existed Schottky barriers on a multi-gate MOSFET and a novel extraction method of the series resistance in MSB S/D MOSFET are also described. In the second part, a nano-scale multi-gate nanocrystal memory has been demonstrated as a promising candidate for the NAND flash memory application.

In the first chapter of this dissertation, some overviews of the CMOS revolution and its challenges will be mentioned. Non-planar device structure, such as multi-gate structure, is highly considered for the future application on the logic CMOS transistors and the Flash memory. The advantage and the shortcoming for using multi-gate are also described. For CMOS devices, multi-multi-gate structure and metal S/D are forecasted for the further scaling. Modified Schottky barrier S/D junction is one possible solution for the future S/D engineering. For flash memory, multi-gate

structure is also a candidate. Moreover, the possible enhancement of the charge storage element and its revolution are also reviewed.

In chapter 2, current transport mechanisms of SB S/D MOSFETs and MSB S/D MOSFETs are investigated by measuring the temperature effect on current-voltage characteristics. The current transport mechanism varied while different gate voltage was biased. Moreover, the SB height would impact the transport mechanism largely in different gate bias conditions.

In chapter 3, we provide a novel method for extracting gate voltage dependent source injection resistance of MSB MOSFETs. The relationship between the injection resistance and the gate bias will be discussed. Furthermore, this method provides a good indicator to evaluate the efficiency of the MSB junction directly.

In chapter 4, the fabrication and the electrical characteristics of a nano-scale n-channel tri-gate TiN nanocrystal non-volatile memory has been demonstrated. The Al2O3 high-k blocking layer and the P+ high work function gate electrode were used to obtain low operation voltage and suppress the back-side injection effect, respectively. TiN nanocrystals were formed by annealing the TiN/Al2O3 nano-laminates which were deposited by an atomic layer deposition system. Moreover, the charge-trapping layer has engineered with different TiN wetting layer thickness, post deposition annealing time, and blocking oxide thickness. The size of the nanocrystal affects the performance largely. Moreover, the memory characteristics and the reliability performance of these samples have been demonstrated.

In chapter 5, we demonstrate an interesting resistive switching phenomenon in the turn-off state in the naon-scale multi-gate TiN nanocrystal memory. This electric-bias-induced reproducible change of reverse read current are observed after pulsing at the conditions of CHE and BTBHH, normally utilizing for the NOR flash operations.

This abnormal leakage current will be investigated and possible mechanism will be discussed.

Finally, in chapter 6, we will give some important conclusions. Moreover, some further works which are worthy for further study will be suggested.

References

[1] L. Risch, “Pushing CMOS beyond the roadmap,” Solid-state Electron., vol. 50, no. 4, pp. 527-535, 2006.

[2] Process Integration, Devices and Structures in International Technology Roadmap for Semiconductors 2009 edition, pp. 1-10, 2009.

[3] L. Chang, Y.-K. Choi, J. Kedzierski, N. Lindert, P. Xuan, J. Bokor, C. Hu, and T.-J. King, “Moore’s Law Lives on,” IEEE Circuits and Devices Mag., vol. 19, no. 1, pp. 35-42, 2003.

[4] Y.-K. Choi, K. Asano, N. Lindert, V. Subramanian, T.-J. King, J. Bokor, and C.

Hu, “Ultrathin-Body SOI MOSFET for Deep-Sub-Tenth Micron Era,” IEEE Electron Devices Lett., vol. 21, no. 5, pp. 254-255, 2000.

[5] K. Uchida, J. Koga, R. Ohba, T. Numata, and S. Takagi, “Experimental Evidences of Quantum-Mechanical Effects on Low-field Mobility, Gate-channel Capacitance, and Threshold Voltage of Ultrathin Body SO1 MOSFETs,” in IEDM Tech. Dig., 2001, pp. 633-636.

[6] B. Yu, L. Chang, S. Ahmed, H. Wang, S. Bell, C.-Y. Yang, C. Tabery, C. Ho, Q.

Xiang, T.-J. King, J. Bokor, C. Hu, M.-R. Lin, and D. Kyser, “FinFET scaling to 10 nm gate length,” in IEDM Tech. Dig., 2002, pp. 251-254.

[7] N. Lindert, L. Chang, Y.-K. Choi, E. H. Anderson, W.-C. Lee, T.-J. King, J.

Bokor, and C. Hu,“Sub-60-nm Quasi-Planar FinFETs Fabricated Using a Simplified Process,” IEEE Electron Devices Lett., vol. 22, no. 10, pp. 487-489, 2001.

[8] R. H. Yuan, A. Ourmazd, and K. Lee, “Scaling the Si MOSFET: from bulk to SOI to bulk,” IEEE Trans. Electron Devices, vol. 39, no. 7, pp. 1704-1710, 1992.

[9] J. Chen, R. Solomon, T.-Y. Chan, P. K. KO, and C. Hu, “Threshold Voltage and C-V Characteristics of SO1 MOSFET’s Related to Si Film Thickness Variation on SIMOX Wafers,” IEEE Trans. Electron Devices, vol. 39, no. 10, pp. 2346-2353, 1992.

[10] B.-Y. Tsui, C.-P. Lin, “A novel 25-nm modified schottky-barrier FinFET with high performance,” IEEE Electron Device Lett., vol. 25, no. 6, pp. 430-432, 2004.

[11] A. Kaneko, A. Yagishita, K. Yahashi, T. Kubota, M. Omura, K. Matsuo, I.

Mizushima, K. Okano, H. Kawasaki, T. Izumida, T. Kanemura, N. Aoki, A.

Kinoshita, J. Koga, S. Inaba, K. Ishimaru, Y. Toyoshima, H. Ishiuchi, K. Suguro, K. Eguchi, Y. Tsunashima, “High-Performance FinFET with Dopant-Segregated Schottky Source/Drain,” in IEDM Tech. Dig., 2006, pp. 893-896.

[12] K. H. Yeo, S. D. Suk, M. Li, Y. Yeoh, K. H. Cho, K.-H. Hong, S. Yun, M. S.

Lee, N. Cho, K. Lee, D. Hwang, B. Park, D.-W. Kim, D. Park, and B.-I. Ryu,

“Gate-All-Around (GAA) Twin Silicon Nanowire MOSFET (TSNWFET) with 15 nm Length Gate and 4 nm Radius Nanowires,” in IEDM Tech. Dig., 2006, pp.

539-542.

[13] N. Singh, A. Agarwal, L. K. Bera, T. Y. Liow, R. Yang, S. C. Rustagi, C. H.

Tung, R. Kumar, G. Q. Lo, N. Balasubramanian, and D.-L. Kwong, “High-Performance Fully Depleted Silicon Nanowire (Diameter ≤ 5 nm) Gate-All-Around CMOS Devices,” IEEE Electron Device Lett., vol. 27, no. 5, pp. 383-386, 2006.

[14] J. W. Peng, S. J. Lee, G. C. A. Liang, N. Singh, S. Y. Zhu, G. Q. Lo, and D. L.

Kwong, “Improved carrier injection in gate-all-around Schottky barrier silicon nanowire field-effect transistors,” App. Phys. Lett., vol. 93, no. 7, p. 073503, 2008.

[15] A. Dixit, A. Kottantharayil, N. Collaert, M. Goodwin, M. Jurczak, and K. De Meyer, “Analysis of the parasitic S/D Resistance in Multiple-Gate FETs,” IEEE Trans. Electron Devices, vol. 52, no. 6, pp. 1132-1140, 2005.

[16] J. Kedzierski, M. Ieong, E. Nowak, T. S. Kanarsky, Y. Zhang, R. Roy, D. Boyd, D. Fried, and H.-S. P. Wong, “Extension and source/drain design for high-performance FinFET devices,” IEEE Trans. Electron Devices, vol. 50, no. 4, pp.

952-958, 2003.

[17] J. Kedziersk, P. Xuan, E. H. Andersonf, J. Bokor, T.-J. King, C. Hu,

“Complementary silicide source/drain thin-body MOSFETs for the 20nm gate length regime,” in IEDM Tech. Dig., 2000, pp. 57-60.

[18] S. Zhu, H. Y. Yu, S. J. Whang, J. H. Chen, C. Shen, C. Zhu, S. J. Lee, M. F. Li, D. S. H. Chan, W. J. Yoo, A. Du, C. H. Tung, J. Singh, A. Chin, and D. L.

Kwong, “Schottky-Barrier S/D MOSFETs With High-K Gate Dielectrics and Metal-Gate Electrode,” IEEE Electron Device Lett., vol. 25, no. 5, pp. 268-270, 2004.

[19] M. Jang, Y.Kim, J. Shin, S. Lee, and K. Park, “ A 50-nm-gate-length erbium-silicided n-type Schottky barrier metal-oxide-semiconductor field-effect transistor,” App. Phys. Lett., vol. 84, no. 5, pp. 741-743, 2004.

[20] R. T. P. Lee, A. E.-J. Lim, K.-M. Tan, T.-Y. Liow, G.-Q. Lo, G. S. Samudra, D.

Z. Chi, and Y.-C. Yeo, “N-channel FinFETs With 25-nm Gate Length and Schottky-Barrier Source and Drain Featuring Ytterbium Silicide.” IEEE Electron Device Lett., vol. 28, no. 2, pp. 164-167, 2004.

[21] J. Knoch, M. Zhang, Q. T. Zhao, St. Lenk, S. Mantl, and J. Appenzeller,

“Effective Schottky barrier lowering in silicon-on-insulator Schottky-barrier metal-oxide-semiconductor field-effect transistors using dopant segregation,”

App. Phys. Lett., vol. 87, no. 26, p. 263505, 2005.

[22] J. Knoch and J. Appenzeller, “Impact of the channel thickness on the performance of Schottky barrier metal–oxide–semiconductor field-effect transistors,” Appl. Phys. Lett., vol. 81, no. 16, pp. 3082-3084, 2002.

[23] S. Xiong, T.-J. King, and J. Bokor, “A Comparison Study of Symmetric Ultrathin-Body Double-Gate Devices With Metal Source/Drain and Doped Source/Drain,” IEEE Trans. Electron Devices, vol. 52, no. 8, pp. 1859-1867, 2005.

[24] A. Kinoshita, T. Kinoshita, Y. Nishi, K. Uchida, S. Toriyama, R. Hasumi, and J.

Koga, “Comprehensive Study on Injection Velocity Enhancement in Dopant-Segregated Schottky MOSFETs,” in IEDM Tech. Dig., 2006, pp. 79-82.

[25] M. Zhang, J. Knoch, Q.T. Zhao, A. Fox, St. Lenk, and S. Mantl, “Low temperature measurements of Schottky-barrier SOI-MOSFETs with dopant segregation,” Electronics Letters, vol. 41, no. 19, pp. 1085-1086, 2005.

[26] R. Bez, and A. Pirovano, “Non-volatile memory technologies: emerging concepts and new materials,” Materials Science in Semiconductor Processing, vol. 7, no. 4-6, pp. 349-355, 2004.

[27] D. Kahng and S. M Sze, “A floating gate and its application to memory devices,”

IEEE Trans. Electron Devices, vol. 14, no. 9, p. 629, 1967.

[28] Process Integration, Devices and Structures in International Technology Roadmap for Semiconductors 2009 edition, pp. 13-20, 2009.

[29] J. Fu, N. Singh, K. D. Buddharaju, S. H. G. Teo, C. Shen, Y. Jiang, C. X. Zhu, M.

B. Yu, G. Q. Lo, N. Balasubramanian, D. L. Kwong, E. Gnani, and G. Baccarani,

“Si-Nanowire Based Gate-All-Around Nonvolatile SONOS Memory Cell,” IEEE Electron Device Lett., vol. 29, no. 5, pp. 518-521, 2008.

[30] M. H. White, D. A. Adams, and J. Bu, “On the go with SONOS,” IEEE Circuits and Devices Magazine, vol. 16, no. 4, pp. 22-31, 2000.

[31] J. Bu, and M. H. White, “Effects of Two-step High Temperature Deuterium Anneals on SONOS Non-volatile Memory Devices,” IEEE Electron Device Lett., vol. 22, no. 1, pp. 17-19, 2001.

[32] H. T. Luo, S. Y. Wang, E. K. Lai, Y. H. Shih, S. C. Lai, L. W. Yang, K. C. Chen, J. Ku, K. Y. Hsieh, R. Liu, and C. Y. Lu, “BE-SONOS: A Bandgap Engineered SONOS with Excellent Performance and Reliability,” in IEDM Tech. Dig., 2005, pp. 547-550.

[33] C.-H. Lee, J. Choi, C. Kang, Y. Shin, J.-S. Lee, J. Sel, J. Sim, S. Jeon, B.-I. Choe, D. Bae, K. Park, and K. Kim, “Multi-Level NAND Flash Memory with 63 nm-node TANOS (Si-Oxide-SiN-Al2O3-TaN) Cell Structure,” in VLSI Symp. Tech.

Dig., 2006, pp. 21-22.

[34] Gowrishankar L. Chindalore, Member, IEEE, Craig T. Swift, and David Burnett, Member, IEEE, “A New Combination–Erase Technique for Erasing Nitride Based (SONOS) Nonvolatile Memories,” IEEE Electron Device Lett., vol. 24, no.

4, pp. 257-259, 2003.

[35] T. Sugizaki, M. Kohayashi, M. Ishidao, H. Minakata, M. Yamaguchi, Y. Tamura, Y. Sugiyama, T. Nakanishi, and H. Tanaka, “Novel Multi-bit SONOS Type Flash Memory Using a Highk Charge Trapping Layer,” in VLSI Symp. Tech.

Dig., 2003, pp. 27-28.

[36] Z. Liu, C. Lee, V. Narayanan, G. Pei, and E. C. Kan, “Metal Nanocrystal Memories—Part I: Device Design and Fabrication,” IEEE Trans. Electron Devices, vol. 49, no. 9, pp. 1606-1613, 2002.

[37] Z. Liu, C. Lee, V. Narayanan, G. Pei, and E. C. Kan, “Metal Nanocrystal

Memories—Part II: electrical characteristics,” IEEE Trans. Electron Devices, vol.

49, no. 9, pp. 1614-1622, 2002.

[38] M. She, and T.-J. King, “Impact of Crystal Size and Tunnel Dielectric on Semiconductor Nanocrystal Memory Performance,” IEEE Trans. Electron Devices, vol. 50, no. 9, pp. 1934-1940, 2003.

[39] J. J. Lee, and D. -L. Kwong, “Metal Nanocrystal Memory With High-k Tunneling Barrier for Improved Data Retention,” IEEE Trans. Electron Devices, vol.52, no. 4, pp. 507-511, 2005.

[40] S. Maikap, P. J. Tzeng, H. Y. Lee, C. C. Wang, T. C. Tien, L. S. Lee, and M. -J.

Tsai, “Physical and electrical characteristics of atomic layer deposited TiN nanocrystal memory capacitors,” Appl. Phys. Lett., vol. 91, no. 4, p. 043114, 2007.

[41] S. Choi, S. S. Kim, M. Chang, H. Hwang, S. Jeon, C Kim, “Highly thermally stable TiN nanocrystals as charge trapping sites for nonvolatile memory device applications,” Appl. Phys. Lett., vol. 86, no.12, p. 123110, 2005.

[42] Y. J. Ahn, J. -D. Choe, J. J. Lee, D. Choi, E. S. Cho, B. Y. Choi, S. -H. Lee, S. K.

Sung, C. -H. Lee, S. H. Cheong, D. K. Lee, S. B. Kim, D. Park and B. I. Ryu,

“Trap Layer Engineered FinFET NAND Flash with Enhanced Memory Window,” in VLSI Symp. Tech. Dig., 2006, pp. 88-89.

[43] K. Yanagidaira, M. Saitoh, and T. Hiramoto, “Enhancement of Charge Storage Performance in Double-Gate Silicon Nanocrystal Memories With Ultrathin Body Structure,” IEEE Electron Devices Lett., vol. 26, no. 7, pp. 473-475, 2005.

[44] C.-P. Lu, C.-K. Luo, B.-Y. Tsui, C.-H. Lin, P.-J. Tzeng, C.-C. Wang, and M.-J.

Tsai, “Nanoscale Multigate TiN Metal Nanocrystal Memory Using High-k Blocking Dielectric and High-Work-Function Gate Electrode Integrated on

Silcon-on-Insulator Substrate,” Jap. J. Appl. Phys., vol. 48, p. 04C059, 2009.

[45] P. Xuan, M. She, B. Harteneck, A. Liddle, J. Bokor, and T.-J. King, “FinFET SONOS Flash Memory for Embedded Applications,” in IEDM Tech. Dig., 2003, pp. 609-612.

[46] M. Specht, U. Dorda, L. Dreeskornfeld, J. Kretz, F. Hofmann, M. Städele, R. J.

Luyken, W. Rösner, H. Reisinger, E. Landgraf, T. Schulz, J. Hartwich, R.

Kömmling, and L. Risch, “20 nm tri-gate SONOS memory cells with multi-level operation,” in IEDM Tech. Dig., 2004, pp. 1083-1085.

[47] M. Specht, R. Kömmling, F. Hofmann, V. Klandzievski, L. Dreeskornfeld, W.

Weber, J. Kretz, E. Landgraf, T. Schulz, J. Hartwich, W. Rösner, M. Städele, R.

J. Luyken, H. Reisinger, A. Graham, E. Hartmann, and L. Risch, “Novel Dual Bit Tri-Gate Charge Trapping Memory Devices,” IEEE Electron Devices Lett., vol. 25, no. 12, pp. 810-812, 2004.

[48] E. S. Cho, C.-H. Lee, T.-Y. Kim, S.-K. Sung, B. K. Cho, C. Lee, H. J. Cho, Y.

Roh, D. Park, K. Kim and B.-I. Ryu, “Hf-silicate Inter-Poly Dielectric Technology for sub 70nm Body Tied FinFET Flash Memory,” in VLSI Symp.

Tech. Dig., 2005, pp.208-209.

[49] T.-H. Hsu, H. T. Lue, Y.-C. King, J.-Y. Hsieh, E.-K. Lai, K.-Y. Hsieh, R. Liu, and C.-Y. Lu, “A High-Performance Body-Tied FinFET Bandgap Engineered SONOS (BE-SONOS) for NAND-Type Flash Memory,” IEEE Electron Devices Lett., vol. 28, no. 5, pp. 443-445, 2007.

[50] F. Hofmann, M. Specht, U. Dorda, R. Kömmling, L. Dreskorndeld, J. Kretz, M.

Städele, W. Rösner, and L. Risch, “NVM based on FinFET device structures,”

Solid-State Electron., vol. 49, no. 11, pp. 1799-1804, 2005.

(a)

Si Substrate

Gate

Source Drain

(b)

Si Substrate

Gate

Buried Oxide

Source Drain

Channel

Fig. 1-1 Schematic cross-section views of (a) planar MOSFET, and (b) planar UTB SOI FET.

(a)

(b)

Fig. 1-2 Schematic structures of the FinFETs on SOI substrate, (a) double-gate FinFETs, and (b) tri-gate FinFETs.

Buried Oxide Si

Gate

Buried Oxide Si

Gate

(a)

Si Substrate

Tunneling Oxide Control Gate

Source Drain

Floating Gate Blocking Oxide

(b)

Si Substrate

Tunneling Oxide Control Gate

Source Drain

Nitride Blocking Oxide ONO

stack {

(c)

Si Substrate

Tunneling Oxide Control Gate

Source Drain

Blocking Oxide

nanocrystals

Fig. 1-3 Basic structure of (a) FG flash memory device, (b) SONOS flash memory device, and (c) nanocrystal flash memory device.

Chapter 2

Current Transportation Mechanisms of Schottky Barrier (SB) MOSFETs and Modified

Schottky Barrier (MSB) MOSFETs

2.1 Introduction

From the prediction of ITRS Roadmap, it mentions that the metal gate electrode, high dielectric constant gate dielectric layer, and metal source/drain would be utilized to enhance the device performance and promote further scaling. The metal source/drain is normally achieved by using metal silicide which is easily formed by the thermal reaction of the metal and the Si layers at source/drain regions and thus the Schottky barriers (SB) were created at the interface between silicide and Si-channel.

Hence, metal source/drain MOSFETs are usually called SB source/drain MOSFETs.

Recently, SB source/drain MOSFETs have been proposed for future nano-scale devices because of easy processing, low thermal budget, small external resistance of source/drain, good drain-induced barrier lowing and better short channel effect. [1-4].

However, the SB MOSFETs still have some drawbacks. The first drawback of the SB MOSFETs is the smaller on-state driving current (Ion) than that of the conventional pn junction MOSFETs due to the existed SB between the silicide and the inverted channel. The existed SB not only affects the driving capability but also degrades the