第五章 結論與建議
5.2 建議事項
1. TiO2/CNTs 複合觸媒於本研究中，僅限於照射近紫外光之 MtBE 光催化 反應，未來可將其改質(如: CNTs 官能基之改質、改善複合方法)，應 用於可見光光源之分解實驗，以使光催化技術實行更具實用性。
2. 奈米碳管添加為本研究中複合觸媒促使光催化效能提升因素之一，但 主要反應機制目前僅能利用反應之中間產物推測，後續利用表面特性 鑑定(如：UV via、FTIR 等)，或是自由基之量測，加以確認 CNTs 於 光催化反應中所扮演之角色。
3. MtBE 光催化反應雖已初步鑑定中間產物，然而完整之分解產物之鑑定 與量化，及分解路徑，仍須更進一步加以確認。
4. 利用動力模式分析之方式，探討水氣濃度、溫度於光催化反應下之影 響，以建議後續研究的重點。
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附錄 A
MtBE 反應物與各產物之檢量線
Peak area
2.0e+4 4.0e+4 6.0e+4 8.0e+4 1.0e+5 1.2e+5 1.4e+5 1.6e+5 1.8e+5 2.0e+5 2.2e+5
MT BE conc entr at ion ( % )
0 5 10 15 20 25 30
y = 0.001x + 2.3542 R
2= 0.9995
圖A.1 MtBE 檢量線
Peak area
0 2e+4 4e+4 6e+4 8e+4 1e+5
A c etone concentrat ion (% )
0 5 10 15 20 25 30
y = 0.0027x + 4.6758
R
2= 0.9996
Peak area
10000 20000 30000 40000 50000 60000 70000
T B A concentr ation (%)
0 5 10 15 20 25 30
y = 0.0035x - 1.5635 R
2= 0.9984
圖A.3 TBA 檢量線
Peak area
0 10000 20000 30000 40000 50000 60000
TB F concentration (% )
0 5 10 15 20 25 30
y = 0.0004x + 0.3151
R
2= 0.9997
附錄 B
MtBE 與中間產物之圖譜
圖 B.1 MtBE 與中間產物之圖譜
附錄 C
各操作條件下之實驗值
附表 C.1 密閉實驗測試
附表 C.2 反應系統吸附實驗
Time Concentration(μM) (TiO2/CNTs=20)
Concentration (μM) Pure TiO2
表C.3 各操作條件下之光催化實驗結果
Time (min) Concentration(μM) Time(min) Concentration(μM)
Test 1 Test 2
Test 11 Test 12
Test 23 Test 24
附表C.4 產物分析
附表C.5 光催化分解產物選擇性
Acetone TBA Time(min) Pure TiO2 TiO2/CNTs=100 TiO2/CNTs=20 Time(min) Pure TiO2 TiO2/CNTs=100 TiO2/CNTs=20
0 0.000 0.000 0.000 0 0.000 0.000 0.000