數位噴墨印花技術應用於透濕防水薄膜織品之研究

(1)

٥ܿמೌᏢଣ

ᠼᆢᆶ׷਑ᔈҔౢ཰ࣴวᅺγ஑੤

ᅺγፕЎ

ኧՏቔᏀӑ޸מೌᔈҔܭ೸ᔸٛНᖓጢᙃࠔ

ϐࣴز

The Study of Applying Digital Printing Technology

to Breathable Waterproof Membrane

ࣴ ز ғǺҖስम

ࡰᏤ௲௤Ǻ໳पӄ

(2)

ġ ĮġŊġĮġ

ᄔ

ा

ҁࣴزࢂᔈҔኧՏቔᏀӑ޸מೌஒН܄ᚑ਑ᏀНϷᕉߥࠠեྋᏊᚑ ਑ᏀНჹᒃНࠠ PU ᖓጢϷ༾ӭϾࠠ PU ᖓጢ຾ՉቔᏀӑ޸Ǵฅࡕӆஒς ቔᏀӑ޸ϐᖓጢϩձᆶ 15 D Ϸ 20 D ᖓϏѭ೸ܴѲ຾ՉຠӝуπǶ٠௖૸ ኧՏቔᏀӑ޸מೌᔈҔܭ೸ᔸٛНᖓጢᙃࠔϐ೸ᔸࡋǵऐНᓸϷऐነᔔ ࢉՅ୲آࡋǵऐНࢱࢉՅ୲آࡋϷऐӀࢉՅ୲آࡋ฻੝܄Ƕ ่݀ᡉҢǴᕉߥࠠեྋᏊᚑ਑ᏀНቔᏀӑ޸ܭ༾ӭϾ PU ᖓጢϐ֎Ꮐ ܄٫ǵమධࡋଯǵՅ࣬ϷՅறႫکࡋ֡ᓬܭН܄ᚑ਑ᏀНǴԿܭᖓጢނ ܄ຑ՗Бय़Ǵٿޣ࣬՟ǹऐНᓸ(JIS L1092 5.1.2 B ݤ) ɧ10000 mm H2O а΢ǴଳነᔔࢉՅ୲آࡋ 4-5 ભǵᔸነᔔࢉՅ୲آࡋ 3 ભ(AATCC 8-2005 ݤ)ǴऐНࢱࢉՅ୲آࡋ 4-5 ભ(AATCC 61-˨A 2006 ݤ)ǹऐӀࢉՅ୲آ ࡋ 4-5 ભ(AATCC 16-3-2004 20 λਔ)Ƕோ೸ᔸࡋ(JIS L1099 A1 ݤ)Ԗ܌ৡ ౦ǴН܄ᚑ਑ᏀНࣁ 5100~5500 g/m2 /dayǴᕉߥࠠեྋᏊᚑ਑ᏀНࣁǺ 7000~8000 g/m2/dayǶԿܭǴຠӝܭ 15 D Ϸ 20 D ᖓϏѭѲޑኧՏቔᏀӑ ޸೸ᔸٛНᖓጢᙃࠔǴځ೸ᔸࡋΠफ़Կ 3500~5000 g/m2 /dayǴځдނ܄߾ คܴᡉৡ౦Ƕ ҁࣴزว౜ԜᜪᖓϏѭѲޑኧՏቔᏀӑ޸೸ᔸٛНᖓጢᙃࠔǴځނ ܄ёߥ࡭ᆶ΋૓೸ᔸٛНᙃࠔεऊ࣬ӕǹᗨฅ೸ᔸࡋӢຠӝϐ዗ᅙጤό ڀ೸ᔸ܄Ǵ٬೸ᔸࡋԖ٤Πफ़ǶՠԜБԄό཮ౢғࢉ᏾ቲНԦࢉϷቲక ނ฻ୢᚒǶЪՅ࣬ᆒஏϷՅآࡋᓬǴՅறკਢΨёӭኬϯǴ٠ڀԖ࿯࣪ ૈྍϷቸ܄ଛӝ྽ۑࢬՉკਢޑ੝፦Ƕ҂ٰǴё໒วᔈҔܭঋڀᖓǵᇸǵ ՅறᗲᢛᆶࢬՉ܄ޑଯભતᙃࠔǶ ᜢᗖӷǺኧՏቔᏀӑ޸ǵᒃНࠠ PU ᖓጢǵ༾ӭϾࠠ PU ᖓጢǵ ຠӝуπǵ೸ᔸٛН

(3)

ġ ĮġŊŊġĮġ

Abstract

The aim of this research is to apply the water-based pigment ink and

eco-solvent pigment ink into the hydrophilic PU membrane and micro porous PU membrane using digital printing technology. Further on to laminate the digital printed membrane to 15 D and 20 D thin denier fabrics individually, this research also discusses the characteristics of the moisture permeability, hydrostatic pressure, friction fastness, water resistant fastness, light fastness and so on of these digital printed breathable waterproof membrane fabrics. The result showed that the micro porous PU membrane with the eco-solvent pigment ink has higher ink receptivity, excelled clarity, better hue and color saturation than that of the water-based pigment ink. Other properties, however, reflect similar results. These properties are the hydrostatic pressure (JIS

L1092 5.1.2 B ) above 10000 mm H2O, the dry friction fastness of dyeing 4-5

levels, the wet friction fastness of dyeing 3 levels (the AATCC 8-2005 ), water resistant fastness of dyeing 4-5 levels (AATCC 61-ɛA 2006 ) and light fastness of dyeing 4-5 levels (AATCC 16-3-2004 20 hours). Other than the above, moisture permeability (JIS L1099 A1 ) shows the difference, the water-based pigment ink printed membrane is 5100~5500 g/m2/day, the eco-solvent pigment ink printed membrane is 7000~8000 g/m2/day. And, the moisture permeability drops to 3500~5000 g/m2/day of the laminated 15 D and 20 D thin denier fabrics with digital printed membrane, the other properties show little differences.

The properties of laminated 15 D and 20 D thin denier breathable fabrics with digital printed membrane and general breathable waterproof fabrics are

similar except moisture permeability. But this technology contributes to less water pollution and creates non-solid waste. Furthermore, the products have higher ink receptivity, clarity, color degree, and better hue and color saturation. In the future, this technology can be applied to thin, light, bright color and fashionable high-quality textiles.

Key wordsǺhydrophilic PU membrane, micro porous PU membrane, digital printing, laminate, breathable waterproof

(4)

ġ ĮġŊŊŊġĮġ

ठ

ᖴ

ૈ୼Ԗᐒ཮ܭౢ཰ᅺγ஑੤ӆ຾অǴࡕᏢགᖴᙍ൑΢ම࿶ගឫᆶڐշޑ ᆫતϦљӕϘǴӵጰဠ٣ߏࣿ໢๏ϒคज़ޑวචޜ໔Ǵ٠ගٮࡌ೛܄ᆶ ᓬ౦ϐᇻـǴ኏Κှ،ࣴزჴᡍ΢ޑୢᚒǴᗋाགᖴϦљӕ٣஭⏎࣑ǵ ݅྆◖ǵᗛ܃޹฻Ǵӧ଺ࣴزޑၡำ΢ፏӭշΚǴ׳གᐟࡰᏤ௲௤໳प ӄԴৣፌፌ௲ᇧǴܭ஑཰ሦୱ΢໺ၰǵ௤཰ǵှൽǴӧᏢғဉ࢏ࡘᆃϐ ሞǴਔਔࠀᓰᏢғόा਻ᎨǴ୲࡭ډനࡕǴϷܴ݅ۘ௲௤ऐЈࡰᏤᆶ஑ ཰ϐࡰ҅Ǵᆶշ౛৪ਦ໦ܭՉࡹ٣୍ǴόჇځྠޑᖄ๎ଛӝǴ๏ϒനε ϐቨ৒ࡋǴаϷᏢ׌ॺ׵܍ਜǵ໳଻㧌ǵ೾ᡉܴܭჴᡍ຾Չය໔឴࣊Ҷ ໕ਔ໔Ǵᇴ଺ჴᡍ຾ࡋǴᗋԖતᙃౢ཰ᆕӝࣴز܌ጰ൑ߏᖃЎǵࢫ჏౉ǵ ࢙݅ⷺܭ΢ᐒჴ୍ᏹբਔǴ๏ϒӄΚЍජǴठ΢ന၈ኑޑᖴཀᆶགᐟǶ ฅౢᅺ੤ޑӕᏢکᒋ࣬ೀǴΨቚబΑόϿӧᏢය໔ޑ៿኷ਔӀǼ! !!!!നࡕाགᖴჹךғڮύቹៜԿుޑࢂғػᎦػךޑР҆ᒃǴӵ݀ؒ ԖдॺǴόٌࣙधᆶคدޑбрǴ൩ؒԖϞϺيЈ଼ӄޑךǴᙣаԜፕ Ў᝘๏Р҆ᒃǴᖴᖴдॺค࡜ค৷ჹךޑਭ୻ᆶбрǴЀځРᒃӧεᆲ ڙ໾໒ΘǴۘ҂ֹӄࡠൺཀ᛽፴ޮੰᄯϐਔǴϝόבჹךѕᓲᆶ౐௠ౢ ᅺ੤ᅿᅿ٣୍<׆ఈϞВ৾ډᅺγᏢՏޑךǴ׳ૈᡣРᒃ໒ЈǴόाӆࣁ ך౐ဉ௠غǴךςפډԾρޑ۩ᅽǼ! !!!!Ꮲғӣ२ᡏ৴ၸ۳ޑҒᆶधǴᅈЈགৱຼᎁ܌ԖޑΓǴᡣךޑΓ ғნၶӵԜӭߍᙦ൤Ǵ҂ٰஒ׳ЈᚶགᐟಒಒӦوၸ೭кᅈు௃ϐၡǼ! ! ! ! !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!Ꮲғ!Җስम!!ᙣᇞ! !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!ύ๮҇୯ 211 ԃ 3 Д!

(5)

ġ ĮġŊŗġĮġ

Ҟ

ᒵ

ᄔ ा --- ˧ Abstract --- ˨ ठ ᖴ --- ˩ Ҟ ᒵ --- ˪ კ Ҟ ᒵ --- ˫ ߄ Ҟ ᒵ --- ˮ ಃ΋ക ᆣፕ --- 01 1-1 ߻ق --- 01 1-2 Ў᝘ӣ៝ --- 15 1-3 ౛ፕ --- 23 1-4 ࣴز୏ᐒ --- 31 1-5 ࣴزҞޑ --- 34 ಃΒക ჴᡍ --- 35 2-1 ࣴزೕჄࢎᄬ --- 35 2-2 ჴᡍ׷਑ϷᏔ׷ --- 36 2-3 ჴᡍБݤ --- 40 2-4 ኧՏቔᏀӑ޸ϐ೸ᔸٛН܄፦ෳۓ --- 52 ಃΟക ่݀ᆶ૸ፕ --- 55 3-1 ୷ҁ܄፦ --- 55 3-2 Eco-solvent ink ቔӑ PU ጢ׷ϐՅآࡋෳ၂(ຠӝ߻)--- 56 3-3 Eco-solvent ink ቔӑ PU ጢ׷ϐՅآࡋෳ၂(ຠӝࡕ)--- 58 3-4 όӕᏀНჹόӕᖓጢϐϩ݋--- 60 ಃѤക ่ፕ--- 65 ୖԵЎ᝘ --- 66

(6)

ġ ĮġŗġĮġ

კ Ҟ ᒵ

კ 1-1 നಖᇙࠔሡ؃ϩ݋ --- 03 კ 1-2 ቔᏀӑ޸೛ीԵໆख़ᗺ --- 04 კ 1-3 ౢ཰೸ᔸٛНуπמೌϷ SEM კ --- 09 კ 1-4 ӄౚኧՏϡӑ޸ࣁறՅኧՏϡᆶቔᏀϐሡ؃ໆᖿ༈კ --- 15

კ 1-5 Increase in shipping time from China --- 16

კ 1-6 Digital Textile Forecast Segmentation --- 16

კ 1-7 Roll-to-Roll and Flatbed/DTG Printers Vendor--- 17

კ 1-8 Roll-to-Roll and Flatbed /DTG Printers Unit Sales--- 17

კ 1-9 Roll-to-Roll and Flatbed /DTG Printers Value of Sales--- 18

კ 1-10 Roll-to-Roll and Flatbed /DTG Printers Installed Base - 18 კ 1-11 Roll-to-Roll and Flatbed /DTG Printers Ink Liters --- 19

კ 1-12 Roll-to-Roll and Flatbed /DTG Printers Revenue --- 19

კ 1-13 Roll-to-Roll and Flatbed /DTG Retail Value of Printed Output --- 20

კ 1-14 Roll-to-Roll and Flatbed /DTG Printers Media Revenue --- 21

კ 1-15 ೱុԄቔӑ(Continuous Drop Production) --- 23

კ 1-16 ᓸႝቔ৔Ԅ(Piezo electric Transducer) --- 24

კ 1-17 ؓݰቔ৔Ԅ(Bubble- Jet)--- 24 კ 1-18 ೸ᔸٛН༾ӭϾ೸ᔸচ౛--- 28 კ 1-19 ༾ӭϾ༡թࢬำკ --- 29 კ 1-20 คϾ፦ᒃН܄Ҝጢ೸ᔸޑচ౛ --- 29 კ 1-21 คϾ፦ᒃН܄༡թࢬำკ --- 30 კ 1-22 ᙑԄቔᏀӑ޸ᔈҔኳԄ--- 32 კ 1-23 ཥԄቔᏀӑ޸ᔈҔኳԄ --- 33

(7)

ġ ĮġŗŊġĮġ კ 1-24 ໺಍ӑ޸ᆶኧՏӑ޸ᇙำКၨ--- 33 კ 2-1 ࣴزೕჄाӢϩ݋კ --- 35 კ 2-2 PU ᔸԄፄӝ׷਑΢ጤᐒ --- 37 კ 2-3 ଳԄፄӝ׷਑΢ጤᐒ --- 37 კ 2-4 ྒྷ਻ϸᔈࠠຠӝᐒ --- 38 კ 2-5 ፄӝ׷਑ٛН೸਻ጢຠӝᐒ --- 38 კ 2-6 ೬፦গᚆᐒ --- 39 კ 2-7 ႝတϯଯਏ౗ۓࠠᐒ --- 39 კ 2-8 ࣴزБݤ೛ीࢬำკ --- 40 კ 2-9 ႝတس಍֖Ьᐒ --- 41 კ 2-10 ᑻჿǵբ཰೬ᡏ --- 41 კ 2-11 ӚࠠԄቔӑᐒ--- 42 კ 2-12 ቔӑှ݋ࡋ 360dpi(0304) --- 43 კ 2-13 ቔӑှ݋ࡋ 720dpi(0309) --- 43 კ 2-14 ቔӑှ݋ࡋ 720dpi(0318) --- 43 კ 2-15 ቔӑှ݋ࡋ 720dpi(0323) --- 44 კ 2-16 ቔӑှ݋ࡋ 360dpi(0330) ---44 კ 2-17 ቔӑෳ၂ Glossy CMYK ቹႽ --- 45 კ 2-18 ቔӑෳ၂ Plain CMYK ቹႽ --- 45 კ 2-19 ቔӑෳ၂ Original file --- 46 კ 2-20 ቔӑෳ၂ Color munki--- 46 კ 2-21 A ಔቔӑෳ၂ --- 47

(8)

ġ ĮġŗŊŊġĮġ კ 2-22 B ಔቔӑෳ၂ --- 47 კ 2-23 ЛԳკਢቔӑෳ၂---48 კ 2-24 றՅጕచᅌቫკਢቔӑෳ၂---48 კ 2-25 Ύಔკᔞቔӑෳ၂ኬ---49 კ 2-26 Ύಔკᔞቔӑࡕуπ፾Ҕ܄၂ኬ---50 კ 2-27 Οკࣁ຾Չ୷ҁՅᏀໆፓ᏾ෳ၂่݀---50 კ 2-28 ٬Ҕ Eco-solvent ink ຾Չ PU ጢ׷ቔӑෳ၂ ---51 კ 2-29 ऐНᓸ၂ᡍᐒѠ --- 52 კ 2-30 ೸ᔸࡋෳ၂ᐒѠ--- 54 კ 3-1 ऐВӀෳ၂ኬ --- 57 კ 3-2 ऐНࢱෳ၂ኬ ---57 კ 3-3 ऐଳᔸᑃᔔෳ၂ኬ --- 57 კ 3-4 ऐНᓸෳ၂ኬ --- 57

(9)

ġ ĮġŗŊŊŊġĮġ

߄ Ҟ ᒵ

߄ 1-1ǵ୯ϣԖހӑ޸уπԋҁКၨȐႣ՗ȑ--- 02 ߄ 1-2ǵતᙃҔቔӑᏀНᅿᜪᆶ୷ҁՅس--- 04 ߄ 1-3ǵኧՏӑ޸ౢࠔޑၮҔጄൎ--- 12 ߄ 1-4ǵቔᏀӑ޸ᆶᆛހӑ޸ϐᔈҔ੝܄Кၨ--- 13 ߄ 1-5ǵӄౚኧՏϡӑ޸ࣁறՅኧՏϡᆶቔᏀϐӝी--- 15 ߄ 1-6ǵቔᓐ܄ૈКၨ--- 25 ߄ 2-1 ჴᡍᏔ׷΋ំ߄ --- ₃₆ ߄ 2-2 ჴᡍ೛ഢ΋ំ߄ --- 36 ߄ 2-3ǵКၨᏀНቔӑࡕϐՅآࡋࠔ፦--- 43 ߄ 2-4ǵКၨᏀНቔӑࡕϐՅآࡋࠔ፦--- ₄₄ ߄ 2-5ǵEpson КၨᏀНቔӑόӕቹႽϐՅৡॶ(ɆE) --- 45 ߄ 2-6ǵTP ink КၨᏀНቔӑόӕᔞਢϐՅৡॶ(ɆE) --- 46 ߄ 3-1ǵН܄ᚑ਑ቔӑܭᒃН܄ PU ᖓጢჹѲ਑ϐ܄፦ෳ၂ ---- 55 ߄ 3-2 ྋᏊࠠᏀНቔӑܭ༾ӭϾқՅᖓጢჹόӕკਢϐ܄፦ෳ ၂ ---55 ߄ 3-3ǵኧՏቔᏀӑ޸ᔈҔܭ೸ᔸٛНᖓጢჹӑ޸ᚆࠠѲෳ၂- 56 ߄ 3-4ǵᔠෳ Eco-solvent ink ϐቔӑࠔ፦ --- 57 ߄ 3-5ǵኧՏቔᏀӑ޸ᔈҔܭ೸ᔸٛНᖓጢჹӑ޸Ѳෳ၂--- 58 ߄ 3-6ǵEco-solvent ink ቔӑ PU ጢ׷ࡕϐނ܄ෳ၂߄--- 59 ߄ 3-7ǵӚ໨܄፦ෳ၂่݀߄--- ₅₉ ߄ 3-8ǵጢ׷ቔӑ፾Ҕ܄ϩ݋--- ₅₉ ߄ 3-9ǵН܄ᚑ਑ჹᒃНࠠ PU ᖓጢቔᏀӑ޸ຠӝ߻ࡕϐނ܄ ෳ၂ --- 60

(10)

ġ ĮġŊřġĮġ ߄ 3-10ǵН܄ᚑ਑ჹ༾ӭϾ PU ᖓጢቔᏀӑ޸ຠӝ߻ࡕϐނ܄ ෳ၂ --- 61 ߄ 3-11ǵᕉߥࠠեྋᏊᚑ਑ჹᒃНࠠ PU ᖓጢቔᏀӑ޸ຠӝϐ ނ܄ෳ၂ --- 62 ߄ 3-12ǵᕉߥࠠեྋᏊᚑ਑ჹ༾ӭϾ PU ᖓጢቔᏀӑ޸ຠӝϐ ނ܄ෳ၂ --- 62 ߄ 3-13ǵόӕᚑ਑ჹᒃНࠠ PU ᖓጢኧՏቔᏀӑ޸ࡕϐКၨ ₆₃ ߄ 3-14ǵόӕᚑ਑ჹ༾ӭϾࠠ PU ᖓጢኧՏቔᏀӑ޸ࡕϐКၨ ₆₄