本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
生質化學品技術發展 生質化學品技術發展 生質化學品技術發展 生質化學品技術發展
張 張 張 張 張 張
張 張 光 光 光 光 光 光 光 光 偉 偉 偉 偉 偉 偉 偉 偉 Guang
Guang - - Way (Bill) Jang Way (Bill) Jang
886 886 - - 3 3 - - 5732854 5732854 [email protected] [email protected]
Material and Chemical Research Laboratories Material and Chemical Research Laboratories
Industrial Technology Research Institute Industrial Technology Research Institute
2012.10.04
2012.10.04
內容 內容 內容 內容 內容 內容 內容 內容
1. Megatrends
2. New Bio-based Chemicals
3. Replacement of Petrochemicals
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
3
Global Megatrends Global Megatrends
如何提昇 如何提昇 如何提昇
如何提昇能源 能源 能源 能源/材料供應同時又能降低 材料供應同時又能降低 材料供應同時又能降低CO 材料供應同時又能降低 CO CO CO 22 2 2 排放 排放 排放 排放? ?? ? 1.
1. 1.
1. increase in process efficiency increase in process efficiency increase in process efficiency increase in process efficiency 2.
2. 2.
2. use of renewable energy/materials use of renewable energy/materials use of renewable energy/materials use of renewable energy/materials 3.
3. 3.
3. …… …… …… ……. .. .
• 人口增加 人口增加 人口增加 人口增加
• 能源 能源 能源 能源/材料需求成長 材料需求成長 材料需求成長 材料需求成長
• 環境暖化 環境暖化 環境暖化 環境暖化/污染 污染 污染 污染
G. Jager Bayer MaterialScience 2012.05
Why Now?
Why Now?
R el at iv e fe ed st o c k p ri c in g
NNFCC 2011.02
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
5
Why Biomass Why Biomass
biomass is the only source - no viable alternative sources of carbon
NNFCC 2011.02
Energy for Producing Bulk Materials Energy for Producing Bulk Materials
*Examples:
HDPE: 77 LDPE: 78 LLDPE: 73 PP: 73
PET: 81 PS: 86 PVC: 56
PA: 120 - 140
Universiteit Utrecht
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
7
Approaches Approaches
Biomass
Bio-based Building Blocks
Bio-based Chemicals, Polymers
3R, incineration
& landfill Bio-based
Chemical Industry Biorefinery
Renewable Resources
Reduced CO 2 Emissions
Process Improvement High Performance drop-in
G. Jager Bayer MaterialScience 2012.05
Carbon Cycle Carbon Cycle
K. Srirangan etc. Apply Energy 2012
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
9
Resources for Bio
Resources for Bio - - based Chemicals based Chemicals
G. Jager Bayer MaterialScience 2012.05
DOE DOE ’ ’ s s Top 12 Bio Top 12 Bio - - derived Building Blocks (2004) derived Building Blocks (2004)
NNFCC 2011.02
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
11
Growth Potential of Bio
Growth Potential of Bio - - based Chemicals based Chemicals
and ethanol
NNFCC 2011.02
Petrochemicals
Petrochemicals
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
13
Synthesis of HMF Synthesis of HMF
The Royal Society of Chemistry 2011
Oxidation and Hydrogenation of HMF Oxidation and Hydrogenation of HMF
The Royal Society of Chemistry 2011
PTA
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
15
Avantium
Avantium YXY Technology YXY Technology
http://avantium.com/yxy/YXY-technology/YXY-process-technology.html
Furanic
Furanic biofuel/2006 DAF Trucks and Volkswagen biofuel/2006 DAF Trucks and Volkswagen
Synthesis and Applications of HMF Synthesis and Applications of HMF
Catalyst Glucose
Dehydration
Separation Purification Oxidation/
Esterification
聚合驗證 聚合驗證 聚合驗證 聚合驗證
HMF產率 產率 產率 產率 83mol %
產率 產率 產率
產率 91 wt%
FDCA
單體純度 單體純度 單體純度
單體純度 99.8 % 透光率 透光率
透光率 透光率88.95 % Tg~78℃ ℃ ℃ ℃,
Tm~210℃ ℃ ℃, ℃
Catalyst HMF
PEF
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
17
Synthesis of
Synthesis of Itaconic Itaconic Acid (IA) Acid (IA)
MICROBES
Glucose Starch
Itaconate (IA) current market
其它用途 10%
化學纖維 27%
黏著劑與 塗料 53%
水處理 10%
Food Scale up
Glycerol
Crude Glycerol
by product from bio-diesel
Dupont’s Hytrel®-like Elastomer
IA derivative market
TCA IA
* 2011-2012年中國衣康酸市場價格調查與走勢分析
*
Super Absorbent polymers
Production of
Production of Itaconic Itaconic Acid (IA) Acid (IA)
Yield
Titer (concentration)
Productivity (rate)
60 % 70 %
70 g/L
1 g/L/h 1.5 g/L/h
Commercial ITRI process
Commercial vs ITRI
Scale (fermenter size,m 3 )
20
200
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
19
HO O H
O
O
RO OR
O
O CH 3
Itaconic acid ROH Catalyst
Dialkyl 2-methyl succinate (DM2MS)
2-methyl BDO (2m-BDO)
3-methyl THF (3m-THF)
H O O
O CH
3CH
3O H CH
3n
HO OH
CH 3
O H 3 C
Poly(3mTHF)
RO OR
O
O
H 2
H 2
2, or 3-methyl GBL (2/3m-THF)
O O H 3 C
O O
H 3 C
+ NR
O H 3 C
NR O
H 3 C + + RNH
22, or 3-methyl Pyrrolidone (2/3m-PYD)
Thermoplastic Elastomers (like Dupot Hytrel TPE)
O
O O
O O
O
O O
C H3 O
O C H3
O O
n
m
類似 類似 類似
類似THF高 高 高 高極性 極性 極性溶劑 極性 溶劑 溶劑, 溶劑 但不溶於
但不溶於 但不溶於 但不溶於H 2 O
可能應用於半導體製程溶劑 可能應用於半導體製程溶劑 可能應用於半導體製程溶劑 可能應用於半導體製程溶劑 NMP,及鋰電池電解液 及鋰電池電解液 及鋰電池電解液 及鋰電池電解液
IA Derivatives Prepared at ITRI
IA Derivatives Prepared at ITRI
Lignin Extraction Lignin Extraction
Alkali Kraft
Dilute Acid Organosolv
Lignosulfonates
Alkali Lignin
Hydrolysis Lignin Organosolv Lignin Black Liq.
Fermentation
Bio-EtOH
Cellulose
Wood
Borregaard
MCL
Russia Borregaard
MCL MCL
Na 2 SO 3
NaOH
Cost: NT$ 20~50/kg
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
21
Green Epoxy Adhesion Green Epoxy Adhesion
Lignin-based Epoxide
OCH3
OH O
OH
O HO
OH O R
O
OH HO
HO O OCH3
O OH OH
OCH3
O
O H3CO
HO R
OCH3
R R
R R
R
R = H, OCH3 R
Phenolic Lignin
Phenolic Lignin hardener
HO OH O
O
OH HO O OCH3
O OH
OCH3 O
H3CO O O
OCH3 O O
O
Lignin-based Epoxide
ICT / Substrate
* Patented Technology
FPC application/
Lignin: 35%
Tg: 181 o C (TMA)
CTE: 63 ppm (40~100 o C) Peel strength: 5.22 lb/in
5.07 lb/in (288 o C 30 Sec)
Adhesive thickness: 21~23 µm
Lignin
Lignin - - based Flame Retardant based Flame Retardant
V0 -
50 wt% Lig-(Phenol)-R1 (2)
DADPM
Hardener Commercial FR UL-94 Lignin FR
No
V0 -
30 wt%Lig-Phenol-R2 (7)
V2 10% DOPO
30 wt% Lig-(Phenol)-R1 (5)
No Lignin FR & Phenolic Hardener (bi-function) Commercial FR UL-94
(1) 40 wt% (Lig / R1= 2/3) - Fail
(3) 50 wt% Lig-(Phenol)-R2 - V0
(4) 50 wt% Lig-SO 3 Na-R1 - V0
(6) 40 wt% Lig-(Phenol)-R1 4% DOPO V0
Lignin FR
Epoxy resin
Bio Bio - - PCB PCB
OH OMe HO
L
R
O
O Epoxy
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
23
Biorenewable
Biorenewable Chemicals & Polymers Chemicals & Polymers
A. Higson/The UK’s National Centre for Biorenewable Energy, Fuels and Materials
Factors Determining Competitiveness of
Factors Determining Competitiveness of Bioproducts Bioproducts
B. Erickson etc. Biotechnol. J. 2012
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
25
Price/Performance of Bio
Price/Performance of Bio - - base Materials base Materials
Can marketers persuade consumers to go green?
Consumers aren't yet willing to make the radical
lifestyle changes needed to roll back climate change, writes Vicky Grinnell-Wright. To change that will
require concerted, well-funded marketing efforts, but
it's unclear whether business leaders have the stomach
for that fight. "[I]t will take a group of very, very brave
brands to commit to a paradigm shift," Grinnell-Wright
writes. The Guardian (London) (7/30)
Fossil vs. Renewable Value Chain Fossil vs. Renewable Value Chain
ChemSusChem 2008, 1, 283-289
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
27
Ethylene Value Chain Ethylene Value Chain
Cl - CH 2 - CH 2 - Cl
NNFCC 2011.02
Drop Drop - - In Replacement In Replacement
First Supply Chain of Bio
First Supply Chain of Bio- -PET PET
Gevo Virent Avantium
PX
PlantBottle PlantBottle
Shifted interest
biofuel→biochemicals
2010.10
Bio-ethylene for Bio-PET
Commercial Scale
(<30% plant based PET)
2011.12 Compete &
Need for 100%
PlantBottle 2012.06
the Plant PET
Technology
Collaborative
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
29
Biobased
Biobased TPA and MEG for Plant PET TPA and MEG for Plant PET
ICIS 2011.06.15
Global PTA and PX prices Global PTA and PX prices
50 m tons/yr
15 m tons/yr bottles
30 m tons/yr
60 m tons/yr 2020
本資料均為機密其所有權暨智慧財產權俱屬工業技術研究院非經許可不得以任何方式翻製或複印
