1. 可嘗試不同水質參數對 MNP-Tu 吸附貴金屬的影響，例如:水中離子強 度。
2. 本研究以 Cu(Ⅱ)作為競爭吸附的代表金屬，但含貴金屬的廢液其金屬 組成相當多種，可嘗試多種過度金屬混和與貴金屬進行選擇性實驗，
以模擬實際回收可能的狀況。
3. 本研究使用批次的方式進行實驗，未來可改成以管柱的方式進行實驗，
探討應用於實場回收貴金屬的效果。
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附錄一 實驗數據
2.水中 pH 質對吸附之影響
擬一階動力模式分析
15.00 0.535332 0.459371 0.578704 30.00 1.031873 0.87108 1.12782 45.00 1.523702 1.255113 1.668314 60.00 2.02977 1.654412 2.214022 90.00 2.923977 2.48025 3.31451 120.00 3.847798 3.299725 4.27249 240.00 7.558262 6.595823 8.187401 360.00 11.22895 9.866618 11.97605 480.00 14.55133 13.14348 15.60468
顆粒內部擴散模式分析
50 mg/L
0.15 g MNP-Tu/0.1 L, pH=2
Pd2+ Au3+ Pt4+
Time (min) ln(t) ln(qt) ln(qt) ln(qt) 15.00 2.70805 3.33292 3.4859469 3.25501 30.00 3.4012 3.36982 3.5392187 3.28091 45.00 3.80666 3.38552 3.5794365 3.29485 60.00 4.09434 3.38642 3.590899 3.29953 90.00 4.49981 3.42687 3.5914504 3.3015 120.00 4.78749 3.43999 3.5936526 3.33529 240.00 5.48064 3.458 3.5942024 3.37804 360.00 5.8861 3.46761 3.5969469 3.4032 480.00 6.17379 3.4961 3.5978601 3.42622
4.等溫吸附實驗
Pt4+ 15 0.00347 9.20719423 10.634 8.6692572 25 0.00336 9.36441539 10.8506 9.182639 35 0.00325 9.74504852 11.4589 11.234207 45 0.00314 10.179425 12.8894 11.395783
6.競爭吸附和選擇性實驗
多質金屬競爭吸附實驗-相同初濃度
7.再利用實驗
附錄二 意見回覆
準，以方便後續數據的
哪一種。 過 物 理 性 吸 附 的 範 pH<4 時 Pt、Au、Pd 主要是以和 Cl-形成的