九十八學年第二學期「化學實驗二」課程綱要

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一、課程編號：203-11510-01, 02

二、教科書：國立台灣大學化學系，「化學實驗一暨化學實驗二」，第三版，

國立台灣大學出版中心，台北，2009.

Department of Chemistry, National Taiwan, University Experiments in General Chemistry, NTU Press: Taipei, 2009.

教學網頁：http://www.ch.ntu.edu.tw/~genchem99/index.htm https://ceiba.ntu.edu.tw/921edtech

三、成績評量方式：

實驗精神（態度）：40％預習報告：10％實驗紀錄：10%

實驗結果報告：20％實驗期末考：20％

四、預修課程：先修或併修「普通化學一二」。

五、課程進度：

第二學期化學實驗二

週實驗名稱配合普化課程內容

1 C0 報到分組、安全簡介

2 C15 水溶液中銅的電解重量測定法電化學

3 C17 高溫超導體之製備氧高溫超導體、固態反應法

4 C19-1 碘鐘實驗－反應級數及活化能之測定初期反應速率法

5 C19-2~4 碘鐘實驗－反應級數及活化能之測定積分作圖法、活化能與催化劑

6 C20 從廢鋁罐製備明礬兩性化合物、錯合物及結晶

7 C21 直接甲醇燃料電池氧化還原反應、能源、電化

學

8 C22 溫度計之校正及可溶性物質分子量之測定依數性質、凝固點下降

9 C28 金奈米粒子合成及吸收光譜鑑定奈米材料、表面電漿共振波

帶、氧化還原反應

10 C23 蒸餾有機化學

11 C24 分餾有機化學

12 C25 萃取及有機酸在水與有機溶劑間之分佈酸鹼、滴定、有機

13 C26 再結晶與熔點測定溶液、共熔點

14 C27 層析法薄層及管柱層析

期末考 99 年 6 月 18 日週五

12:20-13:10 第一學期化學實驗一

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週實驗名稱配合普化課程內容

1 C0 實驗室安全簡介

2 C1 氮氣之莫耳體積計量化學、理想氣體、分

壓定律

3 C2 化合物化學式的決定計量化學、氧還反應

4 C3 酸鹼指示劑與 pH 值測定 C4 溶解度法則

pH 值、酸、鹼、鹽溶解度法則

5 C5 第一組陽離子定性分析酸、鹼、平衡、沉澱反應

6 C6 第二組陽離子定性分析酸、鹼、平衡、沉澱反應

7 C7 容器體積的校準參考(1)

8 C8 中和滴定當量點、酸、鹼、平衡

9 C9 電位法之應用當量點、酸、鹼、平衡

10 C10-1 緩衝溶液當量點、酸、鹼、平衡

11 C11 反應熱之測定熱化學、卡計、黑斯定律

12 C12 維生素 C 之定量氧還反應、滴定

13 C13 溶解度積之測定計量化學、溶解度積

14 C14 高錳酸鉀的氧化還原滴定氧還反應

15 C16 分光光譜法之應用－微量鈷離子定量錯離子、光譜化學

參考書：Harris, D. C. Quantitative Chemical Analysis, 5^th ed., 1999, W. H.

Freeman and Co.: New York.

Chemistry Lab. (I) (II) (2009-2010)

Textbook: Department of Chemistry, National Taiwan University, Chemistry Laboratory (I), (II), 3rd ed., Taipei, 2009.

Website: http://www.ch.ntu.edu.tw/~genchem99/index.htm https://ceiba.ntu.edu.tw/921edtech

Objective:

Chemistry Laboratory (I) and (II) are Integrated Laboratory courses to fulfill the requirements of Chemistry-majored students. The objectives are to demonstrate the principles of chemistry, teach the students various techniques used by chemists, and train the students to familiar with scientific methods.

Course descriptions:

The contents of Chemistry Laboratory (I) and (II) includes: stoichiometry,

thermochemistry, acid-base, equilibrium, buffer solution, titration, electrochemistry,

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chemical kinetics, coordination compounds, spectrophotometry, materials science, and basic organic chemistry skills.

Course requirements:

Review the experiment before class. Follow the safety guidelines of Lab. Be familiar with Lab skills. Hand in reports on time. Attend the final exam at the end of semester.

Grading: Attitude: 40%; Report: 40%; Final exam: 20%

Contents:

Chemistry Lab. (II)

1 Laboratory safety and work instructions 2 C15. Electrogravimetric analysis of copper 3 C17. Synthesis of Y-Ba-Cu superconductor

4, 5 C19. Iodine clock - the study of chemical kinetics (I), (II) 6 C20. Preparation of alum from aluminum can

7 C21. Direct methanol fuel cell

8 C22. Molecular weight determination by freezing point depression 9 C28. Synthesis and characterizations of gold nanoparticles

10 C23. Simple distillation 11 C24. Fractional distillation 12 C25. Extraction

13 C26. Recrystallization and melting point determination 14 C27. Chromatography

Chemistry Lab. (I) Week Experiments

1 Laboratory safety and work instructions 2 C1. Molar volume of nitrogen gas

3 C2. Determination of the empirical formula of cupric oxide 4 C3. Acid-base indicators and pH determination

C4. Solubility Rules

5 C5. Qualitative analysis of cation group 1 6 C6. Qualitative analysis of cation group 2 7 C7. Calibration of volumetric glassware 8 C8. Preparing standard acid and base

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9 C9. Using a pH-meter for an acid-base titration 10 C10. The buffer solutions

11 C11. Heat of reaction

12 C12. Quantitative analysis of vitamin C

13 C13. Determination of solubility product constant of silver acetate 14 C14. Oxidation/reduction titrations with potassium permanganate 15 C16. Spectrophotometric analysis of cobaltous ions