• 沒有找到結果。

第五章 結論與建議

5.2 建議

1.針對氣膠法所合成之中孔洞顆粒(MSP)之吸附應用適用性測試,進行室內不同 種類之有機微污染物吸附測試,研究應用領域將以半導體無塵室環境中之空降 有機污染物質(AMCs)為主要目標,目前有機物種除了高揮發性的丙酮外,另亦 可針對低揮發性有機物種進行吸附測試。進而對最適孔洞結構、有機微污染物 之相關性與影響因素做一歸納分析。

2.本研究合成之中孔洞吸附劑係為純矽氧吸附材料,在吸附 VOCs 文獻提及吸附 劑對於親水性與疏水性揮發性有機物有吸附選擇性,目前仍未進一步探討中孔 洞吸附劑對親/疏水性揮發性有機物之吸附選擇性行為,因此建議可進行相關吸 附測試,釐清其相關性。

3.本研究合成之鋁金屬化中孔洞顆粒係為將具有高比表面積及高均勻中孔特性 之中孔洞矽質微粒金屬化,建議未來可嘗試製備不同化學狀態之金屬化中孔洞 顆粒或是多金屬複合中孔洞顆粒,進行觸媒催化能力與環境污染物控制應用測 試,以瞭解其各化學催化作用及應用範圍。亦可嘗試直接以氣膠法合成中孔洞 金屬微粒的可行性進行評估。

4.本研究目前對於鋁金屬化中孔洞顆粒中鋁配位狀態係以 27Al NMR 分析結果 加以推估判斷其配位組成及可能的鋁金屬樣式,雖然有文獻支持上述結果,但 對於酸基種類,酸基樣式,以及酸基數量則無直接的證據輔佐。建議未來後續 研究可針對上述三種因素進行XPS,TPR,TPD 以及大角度 XRD(WAXRD)分 析,以釐清其鋁樣式所造成之酸基樣式數量變化對吸附及觸媒能力的影響。

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